IP Library Granted Patent US 9,366,787
Granted Patent B2
US 9,366,787 · App. 14/198,980 · Granted Jun 14, 2016

Organic light emitting diode with light extracting layer

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Quick Facts
Patent No.
US 9,366,787
App. No.
14/198,980
Granted
Jun 14, 2016
Kind
B2
Abstract

A light extraction substrate includes a glass substrate having a first surface and a second surface. A light extraction layer is formed on at least one of the surfaces. The light extraction layer is a coating, such as a silicon-containing coating, incorporating nanoparticles.

Claims (47)

1. A light extraction substrate, comprising:

a substrate having a first surface and a second surface;

a light extraction layer over at least a portion of the first or second surface, the light extraction layer comprising a coating including nanoparticles,

wherein the light extraction layer has an average surface roughness in the range of 50 nanometers to 500 nanometers, and

wherein the substrate with the light extraction layer has haze in the range of 10% to 50%.

2. The light extraction substrate of claim 1 , wherein the substrate comprises glass.

3. The light extraction substrate of claim 1 , wherein the nanoparticles are selected from the group consisting of silver oxide, alumina, titania, cerium oxide, zinc oxide, tin oxide, silica, fumed silica, zirconia, and combinations thereof.

4. The light extraction substrate of claim 1 , wherein the light extraction layer has a thickness in the range of 100 nm to 4,000 nm.

5. The light extraction substrate of claim 1 , including an anode located on the light extraction layer.

6. The light extraction substrate of claim 5 , wherein the light extraction layer has a refractive index between the refractive index of the anode and refractive index of the substrate.

7. The light extraction substrate of claim 1 , wherein the coating comprises a silicon-containing coating material.

8. The substrate of claim 1 , wherein the coating is a polymeric coating.

9. A light emitting device, comprising:

a glass substrate having a first surface and a second surface;

a light extraction layer spin deposited over at least a portion of the first surface, the light extraction layer comprising a silicon-containing coating including nanoparticles;

an anode over at least a portion of the light extraction layer;

a light emissive layer over at least a portion of the anode; and

a cathode over at least a portion of the light emissive layer,

wherein the light extraction layer has a refractive index between the refractive index of the anode and refractive index of the glass substrate, and

wherein the substrate with the light extraction layer has haze in the range of 10% to 50%.

10. The light emitting device of claim 9 , wherein the light extraction layer is located between the substrate and the emissive layer.

11. The light emitting device of claim 9 , wherein the light extraction layer is located between the substrate and the anode.

12. The light emitting device of claim 9 , wherein the nanoparticles are selected from the group consisting of silver oxide, alumina, titania, cerium oxide, zinc oxide, tin oxide, silica, fumed silica, zirconia, and combinations thereof.

13. The light emitting device of claim 9 , wherein the light extraction layer has a thickness in the range of 100 nm to 4,000 nm.

14. The light emitting device of claim 9 , wherein the light extraction layer has an average surface roughness in the range of 50 nanometers to 500 nanometers.

15. A light emitting device comprising

a glass substrate having a first surface and a second surface;

a light extraction layer spin deposited over at least a portion of the first surface, the light extraction layer comprising a silicon-containing coating including nanoparticles;

an anode over at least a portion of the light extraction layer;

a light emissive layer over at least a portion of the anode; and

a cathode over at least a portion of the light emissive layer,

wherein the light extraction layer has an average surface roughness in the range of 50 nanometers to 500 nanometers, and

wherein the substrate with the light extraction layer has haze in the range of 10% to 50%.

16. A light emitting device comprising

a glass substrate having a first surface and a second surface;

a light extraction layer spin deposited over at least a portion of the first surface,

the light extraction layer comprising a silicon-containing coating including nanoparticles;

an anode over at least a portion of the light extraction layer;

a light emissive layer over at least a portion of the anode; and

a cathode over at least a portion of the light emissive layer,

wherein the coating comprises a polymeric organosilane material.

17. A light extraction substrate, comprising:

a substrate having a first surface and a second surface;

a light extraction layer over at least a portion of the first or second surface, the light extraction layer comprising a coating including nanoparticles; and

an anode located on the light extraction layer,

wherein the light extraction layer has a refractive index between the refractive index of the anode and refractive index of the substrate, and

wherein the substrate with the light extraction layer has haze in the range of 10% to 50%.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2021
From: VITRO, S.A.B. DE C.V.
To: VITRO FLAT GLASS LLC
Reel/Frame 058052/0526 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 11, 2019
From: VITRO, S.A.B. DE C.V.
To: VITRO FLAT GLASS LLC
Reel/Frame 048048/0177 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL: 040473 FRAME: 0455. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 3, 2017
From: PPG INDUSTRIES OHIO, INC.
To: VITRO, S.A.B. DE C.V.
Reel/Frame 042393/0520 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2016
From: PPG INDUSTRIES OHIO, INC.
To: VITRO, S.A.B. DE C.V.
Reel/Frame 040473/0455 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 9, 2014
From: LU, SONGWEI
To: PPG INDUSTRIES OHIO, INC.
Reel/Frame 032861/0361 →