Method for producing silicone step-growth elastomers from dual functional siloxanes
View Patent ↗A convenient, practical method for forming elastomers from dual functional siloxanes that cure by a step-growth mechanism is provided. The method involves preparing a first mixture containing a first telechelic siloxane and a hydrosilylation catalyst; preparing a second mixture containing a second telechelic siloxane and a dual functional siloxane having two different polymer termini; and reacting the first mixture with the second mixture to produce the siloxane elastomer. The first and second mixtures may be stored separately until time of use.
1. A method for producing a linear, step-growth siloxane elastomer comprising:
(a) preparing a first mixture comprising a first monodisperse telechelic siloxane and a hydrosilylation catalyst;
(b) preparing a second mixture comprising a second monodisperse telechelic siloxane and a dual functional linear, monodisperse siloxane having two different polymer termini; and
(c) reacting the first mixture with the second mixture to produce the linear, step-growth siloxane elastomer having a substantially 1:1 ratio of end groups.
2. The method according to claim 1 , wherein the hydrosilylation catalyst is based on Pt(0).
3. The method according to claim 2 , wherein the hydrosilylation catalyst is Karstedt's catalyst.
4. The method according to claim 1 , wherein the second mixture further comprises a filler or a reinforcing agent.
5. The method according to claim 4 , wherein the second mixture further comprises fumed silica.
6. The method according to claim 1 , wherein a weight ratio of the first mixture to the second mixture is about 1:1 to about 1:200.
7. The method according to claim 1 , wherein the dual functional siloxane has one monohydride group terminus and one unsaturated group terminus.
8. The method according to claim 7 , wherein the unsaturated group terminus is selected from the group consisting of vinyl, styryl, allyl, methallyl, hexenyl, and octenyl.
9. The method according to claim 1 , wherein the dual functional siloxane has one monohydride group terminus and one monovinyl group terminus.
10. The method according to claim 1 , wherein the first telechelic siloxane contains two identical unsaturated functional groups selected from the group consisting of vinyl, styryl, allyl, methallyl, hexenyl, and octenyl.
11. The method according to claim 10 , wherein the first telechelic siloxane contains two vinyl functional groups.
12. The method according to claim 1 , wherein the second telechelic siloxane contains two hydride functional groups.
13. The method according to claim 1 , wherein the first telechelic siloxane has a backbone selected from the group consisting of dimethylsiloxane, ethylmethylsiloxane, diethylsiloxane, dimethylsilylethylsiloxane, trifluoropropylmethylsiloxane, diphenylsiloxane and phenylmethylsiloxane.
14. The method according to claim 1 , wherein the second telechelic siloxane has a backbone selected from the group consisting of dimethylsiloxane, ethylmethylsiloxane, diethylsiloxane, dimethylsilylethylsiloxane, trifluoropropylmethylsiloxane, diphenylsiloxane and phenylmethylsiloxane.
15. The method according to claim 1 , wherein the dual functional siloxane has a backbone selected from the group consisting of dimethylsiloxane, ethylmethylsiloxane, diethylsiloxane, dimethylsilylethylsiloxane, trifluoropropylmethylsiloxane, diphenylsiloxane and phenylmethylsiloxane.
16. The method according to claim 1 , wherein the first and the second mixtures are stored separately for a period of up to about five years prior to performing step (c).
17. The method according to claim 1 , wherein step (c) is performed at room temperature to about 120° C.
18. The method according to claim 1 , wherein step (c) comprises combining the first and the second mixtures in an appropriate ratio to achieve equal molar amounts of the first and the second telechelic siloxanes.