IP Library Granted Patent US 9,196,496
Granted Patent B2
US 9,196,496 · App. 14/201,456 · Granted Nov 24, 2015

Method of integrating a charge-trapping gate stack into a CMOS flow

Inventor: Krishnaswamy Ramkumar (San Jose, CA)
Assignee: CYPRESS SEMICONDUCTOR CORPORATION
H01L21/28282H01L27/11573H01L21/823462
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Quick Facts
Patent No.
US 9,196,496
App. No.
14/201,456
Granted
Nov 24, 2015
Kind
B2
Abstract

A method of fabricating a memory device is described. Generally, the method includes: forming on a surface of a substrate a dielectric stack including a tunneling dielectric and a charge-trapping layer overlying the tunneling dielectric; forming a cap layer overlying the dielectric stack, wherein the cap layer comprises a multi-layer cap layer including at least a first cap layer overlying the charge-trapping layer, and a second cap layer overlying the first cap layer; patterning the cap layer and the dielectric stack to form a gate stack of a memory device; removing the second cap layer; and performing an oxidation process to oxidize the first cap layer to form a blocking oxide overlying the charge-trapping layer, wherein the oxidation process consumes the first cap layer. Other embodiments are also described.

Claims (36)

1. A method comprising:

forming a dielectric stack on a surface of a substrate, the dielectric stack including a tunneling dielectric overlying the surface of the substrate and a charge-trapping layer overlying the tunneling dielectric;

forming a cap layer overlying the dielectric stack, wherein the cap layer comprises a multi-layer cap layer including at least a first cap layer overlying the charge-trapping layer, and a second cap layer overlying the first cap layer;

patterning the cap layer and the dielectric stack to form a gate stack of a memory device;

removing the second cap layer; and

performing an oxidation process to oxidize the first cap layer to form a blocking oxide overlying the charge-trapping layer, wherein the oxidation process consumes the first cap layer.

2. The method of claim 1 , wherein the first cap layer and the second cap layer comprise a material comprising nitride.

3. The method of claim 1 , wherein the oxidation process consumes a portion of the charge-trapping layer.

4. The method of claim 1 , wherein the oxidation process does not consume substantially any of the charge-trapping layer.

5. The method of claim 1 , wherein the charge-trapping layer comprises a multi-layer charge-trapping layer including at least a first charge-trapping layer closer to the tunneling dielectric, and an second charge-trapping layer that is oxygen-lean relative to the first charge-trapping layer and comprises a majority of a charge traps distributed in multi-layer charge-trapping layer.

6. The method of claim 5 , wherein the second charge-trapping layer and the cap layer comprise the same material.

7. The method of claim 1 , wherein the first cap layer and the second cap layer comprise silicon nitride or silicon oxynitride.

8. A method comprising:

forming a dielectric stack on a surface of a substrate, the dielectric stack including a tunneling dielectric overlying the surface of the substrate and a charge-trapping layer on the tunneling dielectric;

forming a cap layer on the charge-trapping layer;

patterning the cap layer and the dielectric stack to form a gate stack of a memory device in a first region of the substrate and to remove the cap layer and the charge-trapping layer from a second region of the substrate; and

removing at least a portion of the cap layer in the first region of the substrate;

performing an oxidation process to form a gate oxide overlying the surface of the substrate in the second region while concurrently oxidizing a remaining portion of the cap layer to form a blocking oxide on the charge-trapping layer.

9. The method of claim 8 , wherein the oxidation process consumes substantially all of the remaining portion of the cap layer.

10. The method of claim 8 , wherein the oxidation process consumes a portion of the charge-trapping layer.

11. The method of claim 8 , wherein the charge-trapping layer comprises a multi-layer charge-trapping layer including at least a first charge-trapping layer closer to the tunneling dielectric, and an second charge-trapping layer that is oxygen-lean relative to the first charge-trapping layer and comprises a majority of a charge traps distributed in multi-layer charge-trapping layer.

12. The method of claim 11 , wherein the second charge-trapping layer and the cap layer comprise the same material.

13. The method of claim 8 , wherein the cap layer comprises silicon nitride or silicon oxynitride.

14. A method comprising:

forming a dielectric stack in a first region and over a pad oxide in a second region of a substrate, the dielectric stack including a tunneling dielectric overlying a surface of the substrate and a charge-trapping layer on the tunneling dielectric;

forming a cap layer overlying the dielectric stack;

forming a sacrificial oxide over the cap layer;

patterning the sacrificial oxide, cap layer and dielectric stack to form a gate stack in the first region of the substrate, and to remove the sacrificial oxide, cap layer and dielectric stack from the second region of the substrate;

removing the sacrificial oxide from the gate stack while removing the pad oxide from the second region; and

forming a gate oxide overlying the surface of the substrate in the second region using an oxidation process while concurrently oxidizing at least a portion of the cap layer to form a blocking oxide overlying the charge-trapping layer.

15. The method of claim 14 , wherein the oxidation process consumes substantially all of the cap layer.

16. The method of claim 15 , wherein the oxidation process consumes a portion of the charge-trapping layer.

17. The method of claim 15 , wherein the oxidation process does not consume substantially any of the charge-trapping layer.

18. The method of claim 14 , wherein the charge-trapping layer comprises a multi-layer charge-trapping layer including at least a first charge-trapping layer closer to the tunneling dielectric, and an second charge-trapping layer that is oxygen-lean relative to the first charge-trapping layer and comprises a majority of a charge traps distributed in multi-layer charge-trapping layer.

19. The method of claim 18 , wherein the second charge-trapping layer and the cap layer comprise the same material.

20. The method of claim 14 , wherein the first cap layer and the second cap layer comprise silicon nitride or silicon oxynitride.

Assignments (5)
CORRECTIVE ASSIGNMENT TO CORRECT THE 8647899 PREVIOUSLY RECORDED ON REEL 035240 FRAME 0429. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTERST. Recorded Nov 3, 2020
From: CYPRESS SEMICONDUCTOR CORPORATION; SPANSION LLC
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 058002/0470 →
RELEASE OF SECURITY INTEREST Recorded May 7, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: CYPRESS SEMICONDUCTOR CORPORATION; SPANSION LLC
Reel/Frame 049109/0573 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2019
From: CYPRESS SEMICONDUCTOR CORPORATION
To: LONGITUDE FLASH MEMORY SOLUTIONS LTD.
Reel/Frame 049086/0803 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2015
From: RAMKUMAR, KRISHNASWAMY
To: CYPRESS SEMICONDUCTOR CORPORATION
Reel/Frame 036661/0968 →
SECURITY INTEREST Recorded Mar 21, 2015
From: CYPRESS SEMICONDUCTOR CORPORATION; SPANSION LLC
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 035240/0429 →
Continuity (3)
Continuation 13428201 · Mar 23, 2012
Provisional Application 61599258 · Feb 15, 2012
Related Publication 20140235046A1 · Aug 21, 2014