Stablized polycarbonate blend with post consumer recycled plastics
View Patent ↗In various aspects, the invention relates to blended thermoplastic polymer compositions (e.g., polycarbonate or polycarbonate-polysiloxane copolymer compositions) comprising recycled acrylonitrile-butadiene-styrene (ABS) polymer or recycled polystyrene polymer which contain at least one impurity and an acid melt flow stabilizer. The presence of the acid melt flow stabilizer improves the thermal stability of the polymer blend. In various further aspects, blended compositions further comprise a flame retardant. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
1. A thermoplastic polymer blend composition, comprising:
a) from about 65 to about 80 parts by weight of at least one bisphenol A polycarbonate polymer component;
b) from about 15 to about 35 parts by weight of at least one recycled polymer, wherein the at least one recycled polymer comprises one or more of a recycled acrylonitrile-butadiene-styrene (ABS) polymer, a recycled polystyrene (PS) polymer, or a combination thereof, wherein the recycled polymer comprises at least one impurity selected from iron, aluminum, copper, magnesium, calcium and polyurethane particle in an amount in the range from at least about 10 ppm to about 10,000 ppm; and
c) from greater than 0 to about 0.1 parts by weight of an acid melt flow stabilizer per 100 parts by weight of the thermoplastic blend composition;
wherein the thermoplastic polymer blend composition exhibits a melt flow rate measured at 260° C./2.16 kgf measured according to ASTM D1238 that is lower than that of an identical reference polymer blend composition in the absence of the acid melt flow stabilizer.
2. The thermoplastic polymer blend composition of claim 1 , wherein the polycarbonate polymer component comprises a bisphenol A polycarbonate polymer.
3. The thermoplastic polymer blend composition of claim 2 , wherein the polycarbonate polymer component further comprises a polycarbonate-polysiloxane copolymer.
4. The thermoplastic polymer blend composition of claim 1 , further comprising from greater than 0 to about 30 parts by weight of a flame retardant.
5. The thermoplastic polymer blend composition of claim 1 , wherein the acid melt flow stabilizer comprises an organic acid.
6. The thermoplastic polymer blend composition of claim 5 , wherein the organic acid comprises citric acid.
7. The thermoplastic polymer blend composition of claim 1 , wherein the acid melt flow stabilizer comprises an inorganic acid.
8. The thermoplastic polymer blend composition of claim 7 , wherein the inorganic acid comprises phosphoric acid, phosphorous acid, or a combination thereof.
9. The thermoplastic polymer blend composition of claim 1 , wherein the acid melt flow stabilizer is present in an amount from greater than 0 to about 0.05 parts by weight per 100 parts by weight of the thermoplastic polymer blend composition.
10. The thermoplastic polymer blend composition of claim 1 , wherein a molded article formed from the thermoplastic polymer blend composition exhibits a notched Izod impact that is greater than that of an identical reference polymer blend composition in the absence of the acid melt flow stabilizer.
11. The thermoplastic polymer blend composition of claim 1 , comprising:
a) from about 65 to about 80 parts by weight of the at least one bisphenol A polycarbonate polymer;
b) from about 15 to about 35 parts by weight of the at least one recycled polymer;
c) from greater than 0 to about 0.1 parts by weight of the acid melt flow stabilizer; and
d) from about 5 to about 20 parts by weight of a flame retardant,
wherein total amounts of (a) through (d) are 100 parts by weight.
12. A thermoplastic polymer blend composition, comprising:
a) from about 65 to about 80 parts by weight of a polycarbonate polymer component;
b) from about 15 to about 35 parts by weight of at least one recycled polymer comprising one or more of a recycled acrylonitrile-butadiene-styrene (ABS) polymer, a recycled polystyrene (PS) polymer, or a combination thereof, wherein the recycled polymer comprises at least one impurity not present in an identical virgin polymer; and
c) from greater than 0 to about 0.1 parts by weight of an acid melt flow stabilizer, wherein the acid melt flow stabilizer does not comprise a carboxylic acid;
wherein the thermoplastic polymer blend composition exhibits a melt flow rate measured at 260° C./2.16 kgf measured according to ASTM D1238 that is lower than that of an identical reference polymer blend composition in the absence of the acid melt flow stabilizer.
13. The thermoplastic polymer blend composition of claim 12 , wherein the polycarbonate polymer component comprises a bisphenol A polycarbonate polymer.
14. The thermoplastic polymer blend composition of claim 13 , wherein the polycarbonate polymer component further comprises a polycarbonate-polysiloxane copolymer.
15. The thermoplastic polymer blend composition of claim 12 , wherein a molded article formed from the thermoplastic polymer blend composition exhibits a notched Izod impact that is greater than that of an identical reference polymer blend composition in the absence of the acid melt flow stabilizer.
16. A molded article formed from the composition of claim 1 .