Methods for treating a metathesis feedstock with metal alkoxides
View Patent ↗Various methods are provided for treating and reacting a metathesis feedstock. In one embodiment, the method includes providing a feedstock comprising a natural oil, chemically treating the feedstock with a metal alkoxide under conditions sufficient to diminish catalyst poisons in the feedstock, and, following the treating, combining a metathesis catalyst with the feedstock under conditions sufficient to metathesize the feedstock.
1. A method of metathesizing a feedstock comprising:
providing a feedstock comprising a natural oil and peroxide poisons;
chemically treating the feedstock with a metal alkoxide to reduce the amount of peroxide poisons in the feedstock through a chemical reaction of the peroxide poisons with the metal alkoxide; and
following the chemically treating, combining a metathesis catalyst with the chemically treated feedstock to metathesize the chemically treated feedstock, wherein the metal alkoxide comprises a metal selected from the group consisting of aluminum, titanium, zirconium, copper, iron, cerium, and silicon.
2. The method of claim 1 , wherein the metal alkoxide comprises an alkoxide selected from the group consisting of methoxide, ethoxide, n-propoxide, isopropoxide, butoxide, 2-methylpropoxide, and tert-butoxide.
3. The method of claim 1 , wherein the metal alkoxide is selected from the group consisting of titanium isopropoxide, aluminum ethoxide, aluminum isopropoxide, zirconium ethoxide, and mixtures thereof.
4. The method of claim 1 , wherein the metal alkoxide is added at a level of between 0.01 wt % and 1 wt % of the feedstock.
5. The method of claim 1 , wherein the chemically treating is conducted at a temperature between 25° C. and 125° C.
6. The method of claim 1 further comprising combining an adsorbent material with the feedstock.
7. The method of claim 6 , comprising combining the adsorbent material with the feedstock in an amount between 0.1 and 3.0 wt % based on the weight of the feedstock.
8. The method of claim 6 , comprising combining the adsorbent material with the feedstock in an amount between 0.2 and 2.0 wt % based on the weight of the feedstock.
9. A method of metathesizing a feedstock comprising:
providing a feedstock comprising a natural oil and peroxide poisons, the feedstock having a starting peroxide value;
chemically treating the feedstock with a metal alkoxide for a time sufficient to reduce the starting peroxide value of the feedstock by approximately 80% or more through a chemical reaction of the peroxide poisons with the metal alkoxide; and
following the chemically treating, combining a metathesis catalyst with the chemically treated feedstock to metathesize the chemically treated feedstock, wherein the metal alkoxide comprises a metal selected from the group consisting of aluminum, titanium, zirconium, copper, iron, cerium, and silicon.
10. The method of claim 9 , wherein the chemically treating decreases the starting peroxide value of the feedstock by approximately 90% or more.
11. The method of claim 9 , wherein the time is between 1 hour and 24 hours.