Process for the creation of uniform grain size in hot worked spinodal alloy
Processes for producing a uniform grain hot worked spinodal alloy are disclosed. The processes generate a uniform grain spinodal alloy without cracking and without the need for a homogenization step. The processes include providing an as-cast spinodal alloy, heating the as-cast spinodal alloy between 1200 and 1300° F. for approximately 12 hours and hot working, allowing the spinodal alloy to cool, performing a second hot work on the as-cast spinodal alloy after it has been heated to 1700° F. for a defined time period, exposing the alloy to a third temperature, performing a second hot work reduction, and cooling the alloy again.
1. A process for producing an article comprising, in sequence:
heating a casting to a first temperature of from about 1100° F. to about 1400° F. for a first time period of from about 10 hours to about 14 hours, the casting comprising a spinodal alloy;
performing a first hot work reduction of the casting;
air cooling the casting to a first ambient temperature;
heating the casting to a second temperature of at least 1600° F. for a second time period;
exposing the casting to a third temperature for a third time period;
performing a second hot work reduction of the casting; and
air cooling the casting to a final ambient temperature to produce the article.
2. The process of claim 1 , wherein the third temperature is least about 50° F. greater than the second temperature, and the third time period is from about 2 hours to about 6 hours.
3. The process of claim 1 , wherein the third temperature is least about 50° F. lower than the second temperature, and the third time period is from about 2 hours to about 6 hours, and the casting is furnace cooled from the second temperature down to the third temperature.
4. The process of claim 1 , wherein the second temperature is from 1600° F. to about 1800° F.
5. The process of claim 1 , wherein the second time period is from about 12 hours to about 48 hours.
6. The process of claim 1 , wherein the third temperature is from about 1600° F. to about 1750° F.
7. The process of claim 1 , wherein the third time period is about 4 hours.
8. The process of claim 1 , wherein the process does not include a homogenization step.
9. The process of claim 1 , wherein the first ambient temperature and the second ambient temperature are room temperature.
10. The process of claim 1 , wherein the as-cast spinodal alloy is a copper-nickel-tin alloy.
11. The process of claim 10 , wherein the copper-nickel-tin alloy comprises from about 8 to about 20 wt % nickel and from about 5 to about 11 wt % tin, with the balance being copper.
12. The process of claim 11 , wherein the copper-nickel-tin as-cast spinodal alloy comprises from about 8 to about 10 wt % nickel and from about 5 to about 8 wt % tin.
13. The process of claim 1 , wherein the first hot work reduction reduces the area of the casting by at least 30%.
14. The process of claim 1 , wherein the second first hot work reduction reduces the area of the casting by at least 30%.
15. The process of claim 1 , wherein the first temperature is from about 1200° F. to about 1350° F.
16. The process of claim 1 , wherein the second temperature is from about 1650° F. to about 1750° F.
17. The process of claim 1 , wherein the first time period is about 12 hours; and the first temperature is about 1350° F.
18. The process of claim 1 , wherein the second time period is about 24 hours; and the second temperature is about 1700° F.
19. A process (S 100 ) for producing a spinodal alloy with uniform grain size, comprising:
heating an as-cast spinodal alloy between 1300° F. and 1400° F. for approximately 12 hours and then hot work reducing the alloy;
air cooling the spinodal alloy;
heating the spinodal alloy to about 1700° F. for a time period of about 12 hours to about 48 hours;
heating the spinodal alloy to about 1750° F. for about 4 hours;
performing a hot work reduction; and
air cooling the spinodal alloy to produce the spinodal alloy with uniform grain size.
20. A process (S 200 ) for producing a spinodal alloy with uniform grain size, comprising:
heating an as-cast spinodal alloy between 1300° F. and 1400° F. for approximately 12 hours and then hot work reducing the alloy;
air cooling the spinodal alloy;
heating the spinodal alloy to about 1700° F. for a time period of about 12 hours to about 48 hours;
furnace cooling the spinodal alloy to about 1600° F. and heating for about 4 hours;
performing a hot work reduction; and
air cooling the spinodal alloy to produce the spinodal alloy with uniform grain size.