Polymethacrylic acid anhydride telomers
The present invention provides compositions of phosphorus acid group and methacrylic anhydride group containing telomeric copolymers of methacrylic acid having an as yet never achieved amount of more than 70 wt. %, or, preferably, 72 wt. % or more, and up to 99 wt. %, of methacrylic anhydride groups based on the total weight of polymerized methacrylic acid and/or salt units. The compositions enjoy higher thermal stability than was previously achieved and enable easer processing that does not require the removal of liquids or solvents.
1. A polymer composition comprising at least one phosphorus acid group and methacrylic anhydride group containing telomeric copolymer of methacrylic acid and/or its salts having an average of more than 70 wt. % to 99 wt. % of methacrylic anhydride groups, based on the total weight of methacrylic acid polymerized units in the copolymer, all anhydride percentages as determined by titration, and having a weight average molecular weight (Mw) of from 1,000 to 100,000.
2. The polymer composition as claimed in claim 1 , wherein the weight average molecular weight (Mw) ranges from 2,000 to 40,000.
3. The polymer composition as claimed in claim 1 , wherein the telomeric copolymer of methacrylic anhydride has on average at least one imide group.
4. The polymer composition as claimed in claim 1 comprising 72 wt. % or more of methacrylic anhydride groups, based on the total weight of methacrylic acid polymerized units in the corresponding copolymer.
5. The polymer composition as claimed in claim 1 , wherein the telomeric copolymer is the copolymerization product of from 0.1 to 25 wt. %, based on the total weight of monomers used to make the cotelomer or copolymer, of a vinyl or acrylic comonomer which is resistant to hydrolysis under processing conditions.
6. The polymer composition as claimed in claim 5 , wherein the vinyl or acrylic monomer is chosen from acrylamide, methacrylamide, C 1 to C 6 alkyl methacrylamides, C 1 to C 6 dialkyl methacrylamides, styrene and alpha-methyl styrene, sulfonated styrene, sulfonated acrylamide, isopropylacrylamide, t-butylacrylamide, acrylonitrile, methyl methacrylate, cyanostyrene, hydroxystyrene, ethyl acrylate.
7. The polymer composition as claimed in claim 1 , wherein the telomeric copolymer comprises from 2 to 20 wt. %, of a phosphorus acid compound, based on the total weight of reactants used to make the telomeric copolymer.
8. The polymer composition as claimed in claim 1 , wherein the at least one phosphorus acid group is bound to a carbon atom of the polymer backbone, is a hypophosphite, its salt, an alkyl phosphinate, a dialkyl phosphinate, or a mixture thereof.
9. The polymer composition as claimed in claim 1 which is in the form of a powder, pellet, granule, or a suspension in a non-aqueous carrier.
10. A method of making a phosphorus acid group and methacrylic anhydride group containing telomeric copolymer of methacrylic acid and/or its salts having an average of more than 70 wt. % to 99 wt. % of methacrylic anhydride groups, based on the total weight of methacrylic acid polymerized units in the copolymer, all anhydride percentages as determined by titration, comprising melting under shear the telomeric copolymer of methacrylic acid at a temperature of from 190 to 260° C., all temperatures being that of the telomeric copolymer.