Multi-layer magnetic nanoparticles for magnetic recording
View Patent ↗According to one embodiment, a multi-layer magnetic nanoparticle includes a core; a first magnetic layer deposited on a surface of the core; and a second magnetic layer deposited on a surface of the first magnetic layer, where the core, the first magnetic layer and the second magnetic layer comprise different magnetic anisotropies and/or saturation magnetizations.
1. A multi-layer magnetic nanoparticle, comprising:
a core comprising NdFeB;
a first magnetic layer deposited on a surface of the core;
a second magnetic layer deposited on a surface of the first magnetic layer, wherein the second magnetic layer is a soft magnetic layer, wherein the soft magnetic layer as deposited on the surface of the first magnetic layer is chemically inert; and
a third magnetic layer deposited on a surface of the second magnetic layer,
wherein the core, the first magnetic layer, the second magnetic layer, and the third magnetic layer comprise different magnetic anisotropies and/or saturation magnetizations.
2. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the core has a diameter between about 3 to about 13 nm.
3. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the first magnetic layer has a diameter between about 0.5 nm and about 15 nm.
4. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the first magnetic layer comprises an intermetallic material selected from a group consisting of: Fe, Co, a Fe alloy, a Co alloy, and combinations thereof.
5. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the second magnetic layer comprises a magnetic oxide.
6. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the second magnetic layer comprises at least one of Fe 3 O 4 , and CoFe 2 O 4 .
7. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the magnetic anisotropy of the core is higher than the magnetic anisotropy of the first magnetic layer and the magnetic anisotropy of the second magnetic layer.
8. The multi-layer magnetic nanoparticle as recited in claim 7 , wherein the magnetic anisotropy of the first magnetic layer is higher than the magnetic anisotropy of the second magnetic layer.
9. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the magnetic anisotropy of the core is between about 1e 6 erg/cc and 1e 8 erg/cc.
10. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the magnetic anisotropy of the first magnetic layer and/or the magnetic anisotropy of the second magnetic layer is less than 1e 6 erg/cc.
11. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the first magnetic layer and the second magnetic layer each has substantially no magnetic anisotropy.
12. The multi-layer magnetic nanoparticle as recited in claim 1 , wherein the saturation magnetization of the first magnetic layer and/or the second magnetic layer is between about 200 emu/cc and about 2400 emu/cc.
13. The multi-layer magnetic nanoparticle as recited in claim 1 , further comprising one or more additional layers deposited above a surface of the second magnetic layer, wherein the one or more additional layer have a magnetic anisotropy that is lower than the magnetic anisotropy of the core, the first magnetic layer and/or the second magnetic layer.
14. A product, comprising:
a magnetic recording medium having a substrate and a magnetic recording layer deposited above the substrate, the magnetic recording layer comprising a layer of magnetic nanoparticles, wherein each of the magnetic nanoparticles comprises:
a core;
a first magnetic layer deposited on a surface of the core;
a second magnetic layer deposited on a surface of the first magnetic layer, the second layer being ferrimagnetic; and
a third magnetic layer deposited on a surface of the second magnetic layer,
wherein the core, the first magnetic layer, the second magnetic layer, and the third magnetic layer comprise different magnetic anisotropies and/or saturation magnetizations.
15. The product as recited in claim 14 , wherein the magnetic nanoparticles are dispersed in a binder.
16. The product as recited in claim 14 , wherein the magnetic nanoparticles have a substantially uniform diameter between about 5 nm to about 20 nm, wherein a spacing between the magnetic nanoparticles in the layer of magnetic nanoparticles is uniform.
17. The product as recited in claim 14 , wherein the magnetic anisotropy of the core is higher than the magnetic anisotropy of the first magnetic layer, the magnetic anisotropy of the first magnetic layer is higher than the magnetic anisotropy of the second magnetic layer, and the magnetic anisotropy of the second magnetic layer is higher than the magnetic anisotropy of the third magnetic layer.
18. The product as recited in claim 14 , wherein the magnetic anisotropy of the core is between about 1e 6 erg/cc and 1e 8 erg/cc, wherein the magnetic anisotropy of the first magnetic layer and/or the magnetic anisotropy of the second magnetic layer and/or the magnetic anisotropy of the third magnetic layer is less than 1e 6 erg/cc.
19. The product as recited in claim 14 , wherein the second magnetic layer has substantially no magnetic anisotropy.
20. A product, comprising:
a magnetic recording medium having a substrate and a magnetic recording layer deposited above the substrate, the magnetic recording layer comprising a layer of magnetic nanoparticles, wherein each of the magnetic nanoparticles comprises:
a core;
a first magnetic layer deposited on a surface of the core; and
a second magnetic layer deposited on a surface of the first magnetic layer,
wherein the core, the first magnetic layer and the second magnetic layer comprise different magnetic anisotropies and/or saturation magnetizations,
wherein the first magnetic layer and the second magnetic layer each has substantially no magnetic anisotropy.