Alumina-zirconia ceramic implants and related materials, apparatus, and methods
View Patent ↗Embodiments of apparatus, systems, and methods relating to biomedical implants and other devices made up of unique and improved alumina-zirconia ceramic materials. In an example of a method according to an implementation of the invention, a slurry is prepared, compressed, and fired to obtain a fired ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide. Some embodiments and implementations may comprise selected concentrations of one or more such compounds to yield certain preferred results.
1. A method for manufacturing a ceramic biomedical implant, the method comprising the steps of:
preparing a first feedstock by mixing ingredients comprising at least aluminum oxide and strontium carbonate or ingredients selected to yield aluminum oxide and strontium carbonate;
preparing a second feedstock by mixing ingredients comprising at least aluminum oxide and calcium carbonate or ingredients selected to yield aluminum oxide and calcium carbonate;
preparing a slurry comprising materials from the first feedstock, materials from the second feedstock, and further comprising additional ingredients configured to yield at least a portion of a ceramic biomedical implant comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide;
forming a compact derived from the slurry;
firing the compact to obtain a fired piece;
after the step of firing the slurry, compressing the fired piece; and
reoxidizing the fired piece, wherein, following the step of reoxidizing the fired piece, the fired piece comprises at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide, and wherein the fired piece comprises a combination of aluminum oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide in a concentration of at least about 84% by volume.
2. The method of claim 1 , wherein the fired piece comprises aluminum oxide in a concentration of at least about 74% by weight.
3. The method of claim 1 , wherein the fired piece comprises aluminum oxide in a concentration of at least about 74.6% by weight.
4. The method of claim 1 , wherein the fired piece comprises yttrium oxide in a concentration of between about 0.8% and about 1.5% by mole of the total molar amounts of zirconium dioxide, yttrium oxide, and cerium oxide in the fired piece.
5. The method of claim 1 , wherein the fired piece comprises cerium oxide in a concentration of between about 1.75% and about 4.0% by mole of the total molar amounts of zirconium dioxide, yttrium oxide, and cerium oxide in the fired piece.
6. The method of claim 1 , wherein the fired piece comprises strontium oxide in a concentration of between about 0.8% and about 1.2% by weight.
7. The method of claim 6 , wherein the fired piece comprises strontium oxide in a concentration of about 0.8% by weight.
8. The method of claim 1 , wherein the step of forming the compact derived from the slurry comprises forming the compact from the slurry.
9. The method of claim 1 , wherein the step of forming the compact derived from the slurry comprises:
drying the slurry to form a powder; and
compressing the powder to form the compact.
10. A method for manufacturing a ceramic piece, the method comprising the steps of:
preparing a slurry comprising ingredients configured to yield a ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide;
forming a compact derived from the slurry; and
firing the compact to obtain a fired ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide, wherein the fired ceramic piece comprises strontium oxide in a concentration of between about 0.8% and about 1.2% by weight.
11. The method of claim 10 , wherein the fired ceramic piece comprises aluminum oxide in a concentration of at least about 74.6% by weight.
12. The method of claim 10 , wherein the fired ceramic piece comprises a combination of aluminum oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide in a concentration of at least about 84% by volume.
13. The method of claim 10 , wherein the fired ceramic piece comprises yttrium oxide in a concentration of between about 0.8% and about 1.5% by mole of the total molar amounts of zirconium dioxide, yttrium oxide, and cerium oxide in the fired ceramic piece.
14. The method of claim 10 , wherein the fired ceramic piece comprises cerium oxide in a concentration of between about 1.75% and about 4.0% by mole of the total molar amounts of zirconium dioxide, yttrium oxide, and cerium oxide in the fired ceramic piece.
15. The method of claim 10 , wherein the fired ceramic piece comprises strontium oxide in a concentration of about 0.8% by weight.
16. The method of claim 10 , wherein the fired ceramic piece comprises magnesium oxide in a concentration of about 0.05% by weight.
17. The method of claim 10 , wherein the fired ceramic piece comprises titanium dioxide in a concentration of about 0.10% by weight.
18. The method of claim 10 , wherein the fired ceramic piece comprises calcium oxide in a concentration of about 0.15% by weight.
19. The method of claim 10 , wherein the fired ceramic piece comprises magnesium oxide, titanium dioxide, and calcium oxide in a combined concentration of no more than about 0.3% by weight.
20. A method for manufacturing a ceramic biomedical implant, the method comprising the steps of:
preparing a slurry comprising ingredients configured to yield a ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide;
forming a compact derived from the slurry; and
firing the compact to obtain a fired ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide,
wherein the fired ceramic piece comprises aluminum oxide in a concentration of at least about 74.6% by weight,
wherein the fired ceramic piece comprises a combination of aluminum oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide in a concentration of at least about 84% by volume,
wherein the fired ceramic piece comprises yttrium oxide in a concentration of between about 0.8% and about 1.5% by mole of the total molar amounts of zirconium dioxide, yttrium oxide, and cerium oxide in the fired ceramic piece,
wherein the fired ceramic piece comprises cerium oxide in a concentration of between about 1.75% and about 4.0% by mole of the total molar amounts of zirconium dioxide, yttrium oxide, and cerium oxide in the fired ceramic piece,
wherein the fired ceramic piece comprises strontium oxide in a concentration of between about 0.8% and about 1.2% by weight,
wherein the fired ceramic piece comprises strontium oxide in a concentration of about 0.8% by weight, and
wherein the fired ceramic piece comprises magnesium oxide, titanium dioxide, and calcium oxide in a combined concentration of no more than about 0.3% by weight.
21. A method for manufacturing a ceramic biomedical implant, the method comprising the steps of:
preparing a first feedstock by mixing ingredients comprising at least aluminum oxide and strontium carbonate or ingredients selected to yield aluminum oxide and strontium carbonate;
preparing a second feedstock by mixing ingredients comprising at least aluminum oxide and calcium carbonate or ingredients selected to yield aluminum oxide and calcium carbonate;
preparing a slurry comprising materials from the first feedstock, materials from the second feedstock, and further comprising additional ingredients configured to yield at least a portion of a ceramic biomedical implant comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide;
forming a compact derived from the slurry;
firing the compact to obtain a fired piece;
after the step of firing the slurry, compressing the fired piece; and
reoxidizing the fired piece, wherein, following the step of reoxidizing the fired piece, the fired piece comprises at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide, and wherein the fired piece comprises strontium oxide in a concentration of between about 0.8% and about 1.2% by weight.
22. A method for manufacturing a ceramic piece, the method comprising the steps of:
preparing a slurry comprising ingredients configured to yield a ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide;
forming a compact derived from the slurry; and
firing the compact to obtain a fired ceramic piece comprising at least aluminum oxide, zirconium dioxide, yttrium oxide, cerium oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide, wherein the fired ceramic piece comprises a combination of aluminum oxide, strontium oxide, magnesium oxide, titanium dioxide, and calcium oxide in a concentration of at least about 84% by volume.