Enzymatically active high-flux selectively gas-permeable membranes
An ultra-thin, catalyzed liquid transport medium-based membrane structure fabricated with a porous supporting substrate may be used for separating an object species such as a carbon dioxide object species. Carbon dioxide flux through this membrane structures may be several orders of magnitude higher than traditional polymer membranes with a high selectivity to carbon dioxide. Other gases such as molecular oxygen, molecular hydrogen, and other species including non-gaseous species, for example ionic materials, may be separated using variations to the membrane discussed.
1. A membrane structure for moving an object species from a first region having an object species first concentration, through the membrane structure, to a second region having a object species second concentration different from the first concentration, wherein the object species is a gaseous molecule or non-gas species to be selectively transported from the first region to the second region, the membrane structure comprising:
a supporting substrate comprising a plurality of pores therethrough;
a nanoporous layer within the plurality of pores, the nanoporous layer being thinner than the supporting substrate, wherein the nanoporous layer comprises:
a hydrophilic layer having a thickness of 50 nm or less; and
a hydrophobic layer; and
a liquid transport medium within the hydrophilic layer, wherein the liquid transport medium comprises:
a liquideous permeation medium; and
at least one catalyst within the liquideous permeation medium.
2. The membrane structure of claim 1 , wherein:
the plurality of pores have a first portion having a first average diameter at a first side of the supporting substrate adjacent to the first region;
the plurality of pores have a second portion having a second average diameter at a second side of the supporting substrate adjacent to the second region, wherein the first average diameter is smaller than the second average diameter; and
the nanoporous layer is within the first portion of the plurality of pores.
3. The membrane structure of claim 2 , wherein the second portion of the plurality of pores is free from the nanoporous layer.
4. The membrane structure of claim 2 , wherein:
the first average diameter is between about 2 nanometers (nm) and about 1000 nm; and
the second average diameter is between 0.5 μm and about 10 millimeters.
5. The membrane structure of claim 1 , wherein the supporting substrate comprises at least one of anodized porous alumina, silica, ceramic, a polymer, a metal, a metal alloy, a metallic composite material, and combinations of two or more of these.
6. The membrane structure of claim 1 , wherein the nanoporous layer comprises at least one of silica, silicate, a metal oxide, or a combination thereof.
7. The membrane structure of claim 1 , wherein the liquideous permeation medium comprises water and the catalyst is an enzyme comprising carbonic anhydrase.
8. The membrane structure of claim 7 , wherein the membrane structure is configured to move an object species comprising carbon dioxide.
9. The membrane structure of claim 1 , wherein the nanoporous layer has a thickness of between about 5 nanometers and about 100 micrometers and the hydrophilic layer has a thickness of about 2 nanometers to about 10 nanometers.
10. The membrane structure of claim 8 , wherein the supporting substrate has a thickness of between about 10 micrometers and about 200 micrometers.
11. The membrane structure of claim 1 , further comprising:
the plurality of pores have a first portion having a first average diameter at a first side of the supporting substrate;
the supporting substrate comprises at least one of anodized porous alumina, silica, ceramic, a polymer, a metal, a metal alloy, a metallic composite material, and combinations of two or more of these;
the plurality of pores have a second portion having a second average diameter at a second side of the supporting substrate, wherein the first average diameter is smaller than the second average diameter;
the nanoporous layer comprises at least one of a silica, silicate, metal oxide, or a combination thereof and is within the first portion of the plurality of pores;
the second portion of the plurality of pores is free from the nanoporous layer; and
the liquideous permeation medium comprises water and the catalyst is an enzyme comprising carbonic anhydrase.
12. A membrane structure for moving an object species from a first region having an object species first concentration, through the membrane structure, to a second region having an object species second concentration different from the first concentration, wherein the object species is a gaseous molecule or non-gas species to be selectively transported from the first region to the second region, the membrane structure comprising:
a supporting substrate comprising a plurality of pores therethrough;
a nanoporous layer within the plurality of pores, the nanoporous layer being thinner than the supporting substrate, wherein the nanoporous layer comprises:
a hydrophilic layer having a thickness of 50 nm or less and being configured to allow a liquid transport medium to be positioned within the first layer; and
a hydrophobic layer.
13. The membrane structure of claim 12 , wherein the supporting substrate comprises at least one of anodized porous alumina, silica, ceramic, a polymer, a metal, a metal alloy, a metallic composite material, and combinations of two or more of these.
14. The membrane structure of claim 13 , wherein the nanoporous layer comprises at least one of nanoporous silica, mesoporous silica, nanoporous polymeric material, nanoporous organic-inorganic composite, silicates, oxides, metals, metal alloys, carbon, sulfides and composites thereof.
15. The membrane structure of claim 12 , wherein the supporting substrate comprises at least one of anodized porous alumina, ceramic, a polymer, a metal, a metal alloy, a metallic composite material, and combinations of two or more of these.
16. The membrane structure of claim 15 , wherein the nanoporous layer comprises at least one of nanoporous silica, mesoporous silica, silicate, a metal oxide, or a combination thereof.
17. The membrane structure of claim 12 , wherein the nanoporous layer comprises nanoporous silica or mesoporous silica.
18. The membrane structure of claim 15 , wherein the supporting substrate comprises anodized porous alumina.
19. The membrane structure of claim 15 , wherein the supporting substrate comprises a polymer.
20. The membrane structure of claim 12 , wherein the hydrophilic layer has a thickness of about 2 nanometers to about 10 nanometers.