Golf ball with soft feel
View Patent ↗A golf ball comprising: (a) a core; (b) an inner mantle layer; (c) an intermediate mantle layer; (d) an outer mantle layer; and (e) at least one cover layer; wherein the core has a PGA compression of less than 70, and the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of at least 30.
1. A golf ball comprising:
(a) a core;
(b) an inner mantle layer comprising a polyalkenamer;
(c) an intermediate mantle layer;
(d) an outer mantle layer; and
(e) at least one cover layer;
wherein the core has a PGA compression of less than 70, and the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of at least 30.
2. The golf ball of claim 1 , wherein the core has a PGA compression of less than 60.
3. The golf ball of claim 1 , wherein the core has a PGA compression of less than 40.
4. The golf ball of claim 1 , wherein each of the mantle layers each have a thickness of less than 0.080 in.
5. The golf ball of claim 1 , wherein the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of at least 40.
6. The golf ball of claim 1 , wherein the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of at least 50.
7. The golf ball of claim 1 , wherein the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of 30 to 70.
8. The golf ball of claim 1 , wherein the intermediate mantle layer, and the outer mantle layer each individually comprises a unimodal ionomer; a bimodal ionomer; a modified unimodal ionomer; a modified bimodal ionomer; a thermoset polyurethane; a polyester elastomer; a copolymer comprising at least one first co-monomer selected from butadiene, isoprene, ethylene or butylene and at least one second co-monomer selected from a (meth)acrylate or a vinyl arylene; a polyalkenamer; or any and all combinations or mixtures thereof.
9. The golf ball of claim 1 , wherein the outer mantle layer has a material Shore D hardness of at least 55 and a material flexural modulus of at least 35 kpsi.
10. The golf ball of claim 1 , wherein each of (a), (b), (c) and (d) have a Shore D hardness and the Shore D hardness of each of (a), (b), (c) and (d) increases from the core to the outer mantle layer.
11. The golf ball of claim 1 , wherein the cover layer comprises a polyurethane, a polyurea, or a combination or mixture thereof.
12. A golf ball comprising:
(a) a core material having a PGA compression of less than 70 and a material flexural modulus of less than 20 kpsi;
(b) an inner mantle layer material comprising a polyalkenamer;
(c) an intermediate mantle layer material;
(d) an outer mantle layer material; and
(e) at least one cover layer material;
wherein the material of each of (a), (b), (c) and (d) have a material flexural modulus and the material flexural modulus of each of (a), (b), (c) and (d) increases from the core material to the outer mantle layer material such that each successive layer between the core material and the outer mantle layer material has a flexural modulus that is greater relative to the immediately adjacent inner layer material and wherein the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of at least 30.
13. The golf ball of claim 12 , wherein the core has a PGA compression of less than 40.
14. The golf ball of claim 12 , wherein each of the mantle layers each have a thickness of less than 0.075 in.
15. The golf ball of claim 12 , wherein the inner mantle layer has a material flexural modulus of 2 to 35 kpsi.
16. The golf ball of claim 15 , wherein the intermediate mantle layer has a material flexural modulus of 10 to 50 kpsi.
17. The golf ball of claim 16 , wherein the outer mantle layer has a material flexural modulus of 30 to 110 kpsi.
18. The golf ball of claim 17 , wherein the core material has a flexural modulus of less than 10 kpsi and a PGA compression of less than 40.
19. The golf ball of claim 12 , wherein the cover layer comprises a polyurethane, a polyurea, or a combination or mixture thereof.
20. The golf ball of claim 12 , wherein each successive layer between the core material and the outer mantle layer material has a flexural modulus that is greater by at least 3 kpsi relative to the immediately adjacent inner layer material.
21. A golf ball comprising:
(a) a core having a PGA compression of less than 40;
(b) an inner mantle layer comprising a polyalkenamer;
(c) an intermediate mantle layer;
(d) an outer mantle layer; and
(e) an outer cover layer;
wherein the golf ball has sufficient impact durability and a golf ball frequency of <4000 Hz.
22. The golf ball of claim 21 , wherein the golf ball frequency is less than 3400 Hz.
23. The golf ball of claim 21 , wherein the golf ball has a sound pressure level, S, of less than 81 dB.
24. The golf ball of claim 1 , wherein:
the core comprises polybutadiene;
the intermediate mantle layer comprises a unimodal ionomer; a bimodal ionomer; a modified unimodal ionomer; a modified bimodal ionomer; a thermoset polyurethane; a polyester elastomer; a copolymer comprising at least one first co-monomer selected from butadiene, isoprene, ethylene, propylene or butylene and at least one second co-monomer selected from a (meth)acrylate or a vinyl arylene; a polyalkenamer; or any and all combinations or mixtures thereof;
the outer mantle layer comprises a copolymer of ethylene and (meth)acrylic acid partially neutralized with a metal selected from the group consisting of lithium, sodium, potassium, magnesium, calcium, barium, lead, tin, zinc, aluminum or a combination thereof; or a blend of a polyamide and at least one maleic anhydride grafted polyolefin; and
the outer cover layer comprises a thermoset polyurethane; a thermoset polyurea; a polymer blend composition formed from a copolymer of ethylene and carboxylic acid as Component A, a hydroxyl-modified block copolymer of styrene and isoprene as Component B, and a metal cation as Component C; or a polymer blend composition formed from a copolymer of ethylene and carboxylic acid as Component A, a styrene-(ethylene-butylene)-styrene block copolymer as Component B, and a metal cation as Component C.
25. The golf ball of claim 24 , wherein the polybutadiene of the core is obtained via a lanthanum rare earth catalyst.
26. The golf ball of claim 25 , wherein the polybutadiene of the core further comprises a pyridine peptizer that also includes a chlorine functional group and a thiol functional group.
27. The golf ball of claim 25 , wherein the intermediate mantle layer comprises polyoctenamer; a hydroxyl-modified block copolymer of styrene and isoprene; a high acid content modified ionomers; or a mixture thereof.
28. The golf ball of claim 1 , wherein the core comprises polybutadiene that is obtained via a rare earth catalyst, a nickel catalyst, or a cobalt catalyst.
29. The golf ball of claim 1 , wherein the core comprises polybutadiene that is obtained via a rare earth catalyst.
30. The golf ball of claim 1 , wherein the polyalkenamer of the inner mantle layer comprises a polyoctenamer.
31. The golf ball of claim 29 , wherein the polyalkenamer of the inner mantle layer comprises a polyoctenamer.
32. The golf ball of claim 1 , wherein the core is a unitary core.
33. The golf ball of claim 21 , wherein the core is unitary core.