Transfix surface member coating
A transfix surface member for use in aqueous ink jet printer comprises a substrate. A conformance layer is disposed on the substrate layer. A surface layer comprising a siloxane polymer network is on the conformance layer. The siloxane polymer network comprises a plurality of diphenylsiloxane moieties and a plurality of polar moieties, the diphenylsiloxane moieties and polar moieties being bonded to the siloxane polymer network by one or more siloxane linkages. An indirect printing apparatus employing the transfix surface member is also disclosed.
1. A transfix surface member for use in an aqueous ink jet printer, comprising:
a substrate;
a conformance layer disposed on the substrate layer; and
a surface layer comprising a siloxane polymer network on the conformance layer, the siloxane polymer network comprising a plurality of diphenylsiloxane moieties and a plurality of polar moieties, the diphenylsiloxane moieties and polar moieties being bonded to the siloxane polymer network by one or more siloxane linkages.
2. The transfix surface member of claim 1 , wherein the diphenylsiloxane moiety is in an amount ranging from about 10% to about 50% by weight relative to the total weight of the polymer network.
3. The transfix surface member of claim 1 , wherein the siloxane polymer network is made by combining one or more polar compounds and a dialkylsiloxane-diphenylsiloxane copolymer to form a coating composition.
4. The transfix surface member of claim 3 , wherein the one or more polar compounds are siloxane units of formulae I or II:
where:
L 1 , L 2 and L 3 are linker groups;
X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently selected from the group consisting of a hydroxyl, a reactive alkoxide functionality and an unreactive aliphatic functionality; and
R 1 and R 2 are independently selected from the group consisting of: a) a substituted or unsubstituted polyether group optionally comprising one or more amide moieties, carbonyl moieties, carboxylic acid ester moieties or amine moieties and b) a polyamine group optionally comprising a saturated hydrocarbon chain moiety.
5. The transfix surface member of claim 4 , wherein the siloxane polymer network composition comprises at least one polar moiety formed from a compound of formula I and at least one polar moiety formed from a compound of formula II.
6. The transfix surface member of claim 4 , wherein L 1 , L 2 and L 3 are independently selected C 1 to C 6 alkyl bridge groups.
7. The transfix surface member of claim 4 , wherein R 1 is a moiety selected from the group consisting of:
and
R 2 is a moiety selected from the group consisting of:
where
a is an integer ranging from 0 to about 30; and
m and n are integers ranging from 0 to 50.
8. The transfix surface member of claim 3 , wherein the siloxane polymer network further comprises a plurality of non-polar moieties formed by combining one or more non-polar compounds with the coating composition.
9. The transfix surface member of claim 8 , wherein the non-polar compounds include one or more siloxane compounds of formulae I or II:
where:
L 1 , L 2 and L 3 are linker groups;
X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently selected from the group consisting of a hydroxyl, a reactive alkoxide functionality and an unreactive aliphatic functionality; and
R 1 and R 2 are independently selected from the group consisting of: a) a linear, branched or cyclic, saturated or unsaturated alkyl group, b) a perfluorinated linear, branched or cyclic carbon chain and c) a group having one or more dialkylsiloxane units.
10. The transfix surface member of claim 9 , wherein L 1 , L 2 and L 3 are independently selected C 1 to C 6 alkyl bridge groups.
11. The transfix surface member of claim 9 , wherein at least one of R 1 and R 2 is a moiety having one or more dialkylsiloxane units.
12. The transfix surface member of claim 11 , wherein R 1 is a moiety of a general formula selected from the group consisting of:
R 2 is a moiety of a general formula:
where:
a and x are integers ranging from 0 to 30; and
n is an integer ranging from 0 to 50.
13. The transfix surface member of claim 9 , wherein R 1 is a moiety of a general formula selected from the group consisting of:
—(CF 2 ) n — and
—(CH 2 ) n —, or
R 2 is a moiety of a general formula selected from the group consisting of:
*—(CH 2 ) n CH 3 , and
—(CF 2 ) n CF 3
where n is an integer ranging from 0 to 50.
14. The transfix surface member of claim 3 , wherein the dialkylsiloxane-diphenylsiloxane copolymer is
where:
R 3 is a linear, branched or cyclic, saturated or unsaturated alkyl group containing from about 1 to 30 carbon atoms;
s is an integer of from 1 to 500; and
t is an integer of from 1 to 300.
15. The transfix surface member of claim 1 , further comprising titanium in an amount ranging from about 0.01% to about 5% by weight relative to the total weight of the polymer network composition.
16. The transfix surface member of claim 1 , wherein the transfix surface member is in the form of a blanket.
17. An aqueous inkjet printer comprising:
a transfix surface member, the transfix surface member comprising:
a substrate;
a conformance layer disposed on the substrate layer; and
a surface layer comprising a siloxane polymer network on the conformance layer, the siloxane polymer network comprising a plurality of diphenylsiloxane moieties and a plurality of polar moieties, the diphenylsiloxane moieties and polar moieties being bonded to the siloxane polymer network by one or more siloxane linkages;
a coating mechanism for forming a sacrificial coating onto the transfer member;
a drying station for drying the sacrificial coating;
at least one ink jet nozzle positioned proximate the transfix surface member and configured for jetting ink droplets onto the sacrificial coating formed on the transfix surface member;
an ink processing station configured to at least partially dry the ink on the sacrificial coating formed on the transfix surface member; and
a print medium supply and handling system for moving a substrate into contact with the transfix surface member.
18. The aqueous inkjet printer of claim 17 , wherein the diphenylsiloxane moieties are in an amount ranging from about 10% to about 50% by weight relative to the total weight of the polymer network.
19. The aqueous inkjet printer of claim 17 , wherein the siloxane polymer network is made by combining one or more polar compounds and a dialkylsiloxane-diphenylsiloxane copolymer to form a coating composition.
20. The aqueous inkjet printer of claim 19 , wherein the one or more polar compounds are siloxane units of formulae I or II:
where:
L 1 , L 2 and L 3 are linker groups;
X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently selected from the group consisting of a hydroxyl, a reactive alkoxide functionality and an unreactive aliphatic functionality; and
R 1 and R 2 are independently selected from the group consisting of: a) a substituted or unsubstituted polyether group optionally comprising one or more amide moieties, carbonyl moieties, carboxylic acid ester moieties or amine moieties and b) a polyamine group optionally comprising a saturated hydrocarbon chain moiety.