High strength flake graphite cast iron having excellent workability and preparation method thereof
View Patent ↗The present disclosure relates to flake graphite cast iron having high workability and a preparation method thereof, and more particularly, to flake graphite cast iron with a uniform graphite shape, low chill formability, a high strength such as a tensile strength of 350 MPa or more, and excellent workability and fluidity by controlling each of the contents of manganese (Mn) and sulfur (S) and carbon (C) and silicon (Si) included in the cast iron and a carbon equivalent (CE) to predetermined ratios, and a preparation method thereof.
1. A flake graphite cast iron for use with an engine consisting of:
3.05 to 3.25% of carbon (C), 2.1 to 2.4% of silicon (Si), 0.600 to 1.099% of manganese (Mn), 0.09 to 0.13% of sulfur (S), 0.04% or less of phosphorus (P), 0.6 to 0.8% of copper (Cu), 0.2 to 0.4% of molybdenum (Mo), the balance iron (Fe) and other inevitable impurities satisfying 100% as a total weight %, and
simultaneously satisfying a chemical composition wherein a ratio (Mn/S) of the content of manganese (Mn) to the content of sulfur (S) is in a range from 7 to 28,
a ratio ((Mn/S)/(C/Si)) of the content ratio of manganese and sulfur to the content ratio of carbon and silicon is in a range from 5 to 18,
a carbon equivalent (CE) is in a range from 3.8 to 4.0, and
a tensile strength of 350 MPa or more.
2. The flake graphite cast iron of claim 1 , wherein a processing length is 6 m or more when a VBmax is 0.45 during an evaluation of workability of a workability test specimen.
3. The flake graphite cast iron of claim 1 , wherein a wedge test specimen has a chill depth of 3 mm or less.
4. A method for preparing flake graphite cast iron for use with the engine of claim 1 , the method comprising:
(i) preparing a cast iron melt consisting of 3.05 to 3.25% of carbon (C), 2.1 to 2.4% of silicon (Si), 0.600 to 1.099% of manganese (Mn), 0.09 to 0.13% of sulfur (S), 0.04% or less of phosphorus (P), 0.6 to 0.8% of copper (Cu), 0.2 to 0.4% of molybdenum (Mo), the balance iron (Fe) and other inevitable impurities based on a total weight %, wherein a chemical composition of the cast iron melt is adjusted such that a ratio (Mn/S) of a content of manganese (Mn) to a content of sulfur (S) is in a range from 7 to 28, a ratio ((Mn/S)/(C/Si)) of a content ratio of manganese and sulfur to a content ratio of carbon and silicon is in a range from 5 to 18, and a carbon equivalent (CE) is in a range from 3.8 to 4.0; and
(ii) pouring the prepared cast iron melt into a ladle and injecting the cast iron melt into a prepared mold.
5. The method of claim 4 , wherein the cast iron melt in step (i) is prepared by adding the copper (Cu) and the molybdenum (Mo) to the cast iron melt prepared by melting a cast iron material including the carbon (C), the silicon (Si), the manganese (Mn), the sulfur (S), the phosphorus (P) and the iron (Fe).
6. The method of claim 4 , wherein an Fe—Si-based inoculant is added one or more times in step (ii).
7. The method of claim 6 , wherein the Fe—Si-based inoculant is added when the cast iron melt is poured into the ladle, when the cast iron melt is injected into the mold, or in all the steps.