Granted Patent B2

US 9,036,242 · App. 14/222,860 · Granted May 19, 2015

Abstract

Claims (32)

1. An electrochromic device comprising a first substrate, a first electrically conductive layer, a first electrode layer, a second electrically conductive layer and a second substrate, the first and second substrates being glass or plastic, the first and second electrically conductive layers each having a sheet resistance, R s , to the flow of electrical current through the first and second electrically conductive layers that varies as a function of position in the first and second electrically conductive layers, respectively, wherein the ratio of the value of maximum sheet resistance, R max , to the value of minimum sheet resistance, R min , in the first electrically conductive layer is at least about 10 and the ratio of the value of maximum sheet resistance, R max , to the value of minimum sheet resistance, R min , in the second electrically conductive layer is at least about 10, the first substrate and the first electrically conductive layer being transmissive to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet, wherein (i) the first electrically conductive layer has a spatially varying sheet resistance R s , that varies as a function of position in the first electrically conductive layer, (ii) a contour map of the sheet resistance R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and (iii) a projection of a line segment having a length of at least 1 cm of one of the gradient lines onto the second electrically conductive layer defines a complementary line segment in the second electrically conductive layer wherein (a) the average value of the slope of the sheet resistance of the first electrically conductive layer over the gradient line segment, S 1 avg , is a positive or negative value, and (b) the average value of the slope of the sheet resistance of the second electrically conductive layer over the complementary line segment S 2 avg , is zero or is opposite in sign to S 1 avg .

2. The electrochromic device of 1 wherein (i) the ratio of the average sheet resistance in a first region of the first electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the first electrically conductive layer circumscribed by a second convex polygon is at least 5, the first and second regions of the first electrically conductive layer each comprising at least 25% of the surface area of the first electrically conductive layer and (ii) the ratio of the average sheet resistance in a first region of the second electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the second electrically conductive layer circumscribed by a second convex polygon is at least 5, the first and second regions of the second electrically conductive layer each comprising at least 25% of the surface area of the second electrically conductive layer.

3. The multi-layer device of claim 2 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, a second electrode layer, the second electrically conductive layer and the second substrate, and wherein the first electrode layer comprises an electrochromic material and the second electrode layer comprises an electrochromic material.

4. The electrochromic device of claim 1 wherein the first electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the first electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.

5. The electrochromic device of claim 4 wherein the second electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the second electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the second electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.

6. The multi-layer device of claim 5 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, a second electrode layer, the second electrically conductive layer and the second substrate, and wherein the first and second electrode layers comprise an electrochromic material.

7. The electrochromic device of claim 5 wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the first electrically conductive layer circumscribed by a second convex polygon is at least 5, the first and second regions circumscribed by the first and second convex polygons, respectively, each comprising at least 25% of the surface area of the first electrically conductive layer.

8. The electrochromic device of claim 5 wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer, R 1 avg , to the average sheet resistance in a second region of the first electrically conductive layer, R 2 avg , is at least 1.25, the ratio of the average sheet resistance in the second region of the first electrically conductive layer, R 2 avg , to the average sheet resistance in a third region of the first electrically conductive layer, R 3 avg , is at least 1.25, the ratio of the average sheet resistance in the third region of the first electrically conductive layer, R 3 avg , to the average sheet resistance in a fourth region of the first electrically conductive layer, R 4 avg , is at least 1.25, wherein the first region is contiguous with the second region, the second region is contiguous with the third region, the third region is contiguous with the fourth region, each of the regions is circumscribed by a convex polygon, and each comprises at least 10% of the surface area of the first electrically conductive layer.

9. The electrochromic device of claim 8 wherein the ratio of the average sheet resistance in a first region of the second electrically conductive layer, R 1 avg , to the average sheet resistance in a second region of the second electrically conductive layer, R 2 avg , is at least 1.25, the ratio of the average sheet resistance in the second region of the second electrically conductive layer, R 2 avg , to the average sheet resistance in a third region of the second electrically conductive layer, R 3 avg , is at least 1.25, the ratio of the average sheet resistance in the third region of the second electrically conductive layer, R 3 avg , to the average sheet resistance in a fourth region of the second electrically conductive layer, R 4 avg , is at least 1.25, wherein the first region is contiguous with the second region, the second region is contiguous with the third region, the third region is contiguous with the fourth region, each of the regions is circumscribed by a convex polygon, and each comprises at least 10% of the surface area of the second electrically conductive layer.

10. The electrochromic device of claim 1 wherein the second substrate and the second electrically conductive layer are transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.

11. The multi-layer device of claim 10 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, a second electrode layer, the second electrically conductive layer and the second substrate, and wherein the first and second electrode layers comprise an electrochromic material.

12. The multi-layer device of claim 1 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, a second electrode layer, the second electrically conductive layer and the second substrate.

13. The electrochromic device of claim 12 wherein the first electrode layer comprises an electrochromic material.

14. The electrochromic device of claim 12 wherein the first electrode layer comprises an electrochromic material and the second electrode layer comprises an electrochromic material.

15. The multi-layer device of claim 1 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, the second electrically conductive layer and the second substrate.

16. The multi-layer device of claim 1 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, the second electrically conductive layer and the second substrate.

17. The electrochromic device of claim 1 wherein (a) the first electrically conductive layer comprises a region A 1 and a region B 1 wherein region A 1 and region B 1 each comprise at least 25% of the surface area of the first electrically conductive layer, are each circumscribed by a convex polygon and are mutually exclusive, (b) a projection of region A 1 onto the second electrically conductive layer defines a region A circumscribed by a convex polygon in the second electrically conductive layer comprising at least 25% of the surface area of the second electrically conductive, (c) a projection of region B 1 onto the second electrically conductive layer defines a region B circumscribed by a convex polygon in the second electrically conductive layer comprising at least 25% of the surface area of the second electrically conductive, (d) the first electrically conductive layer has an average sheet resistance in region A 1 corresponding to R A1 avg and an average sheet resistance in region B 1 corresponding to R B1 avg (e) the second electrically conductive layer has an average sheet resistance in region A corresponding to R A avg and an average sheet resistance in region B corresponding to R B avg , (f) the ratio of R A1 avg to R B1 avg or the ratio of R B avg to R A avg is at least 1.5 and (g) the ratio of (R A1 avg /R A avg ) to (R B1 avg /R B avg ) is at least 1.5.

18. The electrochromic device of claim 17 wherein the first electrode layer comprises an electrochromic material.

19. The electrochromic device of claim 17 wherein the multi-layer device further comprises a second electrode layer and the second electrode layer comprises an electrochromic material.

20. The electrochromic device of claim 1 wherein the first electrically conductive layer is graded in composition or thickness.

21. The electrochromic device of claim 1 wherein the first substrate is transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.

22. The electrochromic device of claim 1 wherein the first electrode layer comprises an electrochromic material.

23. The electrochromic device of claim 22 wherein the second electrode layer comprises an electrochromic material.

24. The electrochromic device of claim 1 , the multi-layer device further comprising an ion conducting layer, the first electrode layer being between the ion conducting layer and the first electrically conductive layer, the ion conducting layer being a dielectric material having an ionic conductivity for carrier ions of at least 10 −7 Siemens/cm at 25° C.

25. The electrochromic device of claim 1 wherein the second electrode layer comprises an electrochromic material.

26. The electrochromic device of claim 1 wherein the second substrate is transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.

27. The electrochromic device of claim 1 wherein the first substrate has an inner surface facing the first electrically conductive layer, the surface area of the inner surface of the first substrate being at least 0.1 meter 2 .

28. A process for the preparation of a multi-layer device comprising forming a multi-layer layer structure comprising an electrochromic layer between and in electrical contact with a first and a second electrically conductive layer, the first and/or the second electrically conductive layer having a spatially varying sheet resistance, R s , to the flow of electrical current through the first and/or the second electrically conductive layer that varies as a function of position in the first and/or the second electrically conductive layer, respectively, wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the first electrically conductive layer circumscribed by a second convex polygon is at least 5, the first and second regions circumscribed by the first and second convex polygons, respectively, each comprising at least 25% of the surface area of the first electrically conductive layer, wherein (i) the first electrically conductive layer has a spatially varying sheet resistance R s , that varies as a function of position in the first electrically conductive layer, (ii) a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and (iii) a projection of a line segment having a length of at least 1 cm of one of the gradient lines onto the second electrically conductive layer defines a complementary line segment in the second electrically conductive layer wherein (a) the average value of the slope of the sheet resistance of the first electrically conductive layer over the gradient line segment, S 1 avg , is a positive or negative value, and (b) the average value of the slope of the sheet resistance of the second electrically conductive layer over the complementary line segment, S 2 avg , is zero or is opposite in sign to S 1 avg .

29. The process of claim 28 wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer, R 1 avg , to the average sheet resistance in a second region of the first electrically conductive layer, R 2 avg , is at least 1.25, the ratio of the average sheet resistance in the second region of the first electrically conductive layer, R 2 avg , to the average sheet resistance in a third region of the first electrically conductive layer, R 3 avg , is at least 1.25, the ratio of the average sheet resistance in the third region of the first electrically conductive layer, R 3 avg , to the average sheet resistance in a fourth region of the first electrically conductive layer, R 4 avg , is at least 1.25, wherein the first region is contiguous with the second region, the second region is contiguous with the third region, the third region is contiguous with the fourth region, each of the regions is circumscribed by a convex polygon, and each comprises at least 10% of the surface area of the first electrically conductive layer.

30. The process of claim 28 wherein the first electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the first electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the sheet resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.

31. The process of claim 28 wherein the process comprises depositing the first electrically conductive layer on a glass or plastic substrate and varying the sheet resistance of the deposited layer as a function of position in the first electrically conductive layer.

32. The process of claim 28 wherein the process comprises depositing a first electrically conductive layer having a composition or thickness that varies as a function of position in the first electrically conductive layer.

Assignments (18)