Wear resistant lead free alloy bushing and method of making
View Patent ↗A bearing having improved wear resistance has a bearing material of a copper-tin-bismuth alloy which may also include phosphorus which has excellent strength, due to the solid solution of copper, tin and phosphorus (when used), attached to a steel backing shell. The material also has good lubricity as a result of the presence of the bismuth which also promotes tin mobilization and formation of a layer of tin on the bearing surface upon use of the bearing. The addition of small amounts of relatively small hard particles in the copper-tin-matrix, particularly Fe 3 P, MoSi 2 or a mixture thereof, provides a suitable hard surface artifact to improve the wear resistance of the bearing material. The bearing includes a sintered powder compact bearing material of a copper-tin-bismuth alloy powder and a metal compound powder which is bonded to a steel backing shell, wherein the metal compound powder has an average particle size of less than 10 μm.
1. A method of making a bearing comprising the steps of:
applying a mixture of a copper-tin-bismuth alloy powder and a metal compound powder having an average particle size of less than 10 μm to a steel backing shell, the metal compound powder including an Fe 3 P powder and an MoSi 2 powder;
heating the powder mixture and steel backing shell to produce a sintered powder mixture and bond the sintered powder mixture to the steel backing shell; and
rolling the sintered powder mixture and steel backing shell to reduce a porosity of the sintered powder mixture and produce a fully-dense sintered compact bearing material, wherein the copper-tin-bismuth alloy of the sintered powder mixture includes a matrix of copper and tin and including bismuth in the form of islands spaced from one another by the matrix and the compound metal powder is dispersed throughout the matrix.
2. The method of claim 1 , further comprising a step of heating the sintered compact bearing material sufficiently to promote interdiffusion within the bearing material at sites associated with the porosity.
3. The method of claim 2 , further comprising a step of running-in the bearing sufficiently to produce a tin-rich surface layer.
4. The method of claim 1 , wherein said copper-tin-bismuth alloy powder comprises, by weight: 8-12% tin, 1-<5% bismuth, and the balance essentially copper.
5. A method of making a bearing comprising the steps of:
applying a powder mixture of a copper-tin-bismuth alloy powder, an Fe 3 P powder and an MoSi 2 powder to a steel backing shell;
heating the powder mixture and steel backing shell to produce a sintered powder mixture and bond the sintered powder mixture to the steel backing shell; and
rolling the sintered powder mixture and steel backing shell to reduce a porosity of the sintered powder mixture and produce a fully dense sintered compact bearing material.
6. The method of claim 5 , further comprising a step of heating the sintered compact bearing material sufficiently to promote interdiffusion within the bearing material at sites associated with the porosity.
7. The method of claim 6 , further comprising a step of running-in the bearing sufficiently to produce a tin-rich surface layer.
8. The method of claim 5 , wherein said Fe 3 P powder and said MoSi 2 powder together comprise 0.1-10% by volume of said compact.
9. The method of claim 5 , wherein said Fe 3 P powder and said MoSi 2 powder each have an average particle size of less than 10 μm.
10. The method of claim 5 , wherein said copper-tin-bismuth alloy comprises, by weight: 8-12% tin, 1-<5% bismuth and the balance essentially copper.
11. The method of claim 10 , further comprising phosphorus as an alloy constituent of the copper-tin-bismuth alloy powder.
12. The method of claim 11 , wherein the phosphorus comprises, by weight, 0.03-0.8% of the copper-tin-bismuth alloy powder.
13. The method of claim 12 , wherein the MoSi 2 comprises 0.1-0.5% by weight of the powder mixture.
14. The method of claim 11 , wherein the sintered compact bearing material comprises a molybdenum phosphorus compound as a reaction product of said MoSi2 powder and at least one of the F 3 P powder or the phosphorus.