Low temperature chemical processing of graphite-clad nuclear fuels
View Patent ↗A reduced-temperature method for treatment of a fuel element is described. The method includes molten salt treatment of a fuel element with a nitrate salt. The nitrate salt can oxidize the outer graphite matrix of a fuel element. The method can also include reduced temperature degradation of the carbide layer of a fuel element and low temperature solubilization of the fuel in a kernel of a fuel element.
1. A method for processing a graphite-encapsulated nuclear fuel element comprising:
contacting a nuclear fuel element with a first nitrate salt at a temperature of from about 400° C. to about 700° C., the nuclear fuel element including a fuel particle and a graphite matrix external to the fuel particle, the fuel particle comprising a fuel kernel that includes a fissile or a fertile material, the first nitrate salt reacting with the graphite of the graphite matrix to oxidize the graphite to carbon dioxide.
2. The method according to claim 1 , the fuel particle further comprising a layer surrounding the fuel kernel that includes a carbide, the method further comprising contacting the carbide with an alkali metal hydroxide and a second nitrate salt, the carbide reacting with the alkali metal hydroxide and the second nitrate salt to oxidize the carbide.
3. The method according to claim 2 , wherein the alkali metal hydroxide is sodium hydroxide.
4. The method according to claim 2 , wherein the first nitrate salt and the second nitrate salt are the same.
5. The method according to claim 2 , the fuel particle further comprising a carbon layer that is interior to the carbide layer, the second nitrate salt reacting with the carbon layer to oxidize the carbon of the interior carbon layer.
6. The method according to claim 2 , wherein the carbide is silicon carbide or zirconium carbide.
7. The method according to claim 1 , wherein the method is a single-step method.
8. The method according to claim 1 , wherein the method is a multi-step method.
9. The method according to claim 1 , further comprising contacting the fuel kernel with a metal superoxide or peroxide to solubilize the fissile or fertile material of the fuel kernel.
10. The method according to claim 9 , wherein the metal superoxide or peroxide is sodium peroxide.
11. The method according to claim 1 , further comprising contacting the fuel kernel with nitric acid to solubilize the fissile or fertile material of the fuel kernel.
12. The method according to claim 1 , wherein the first nitrate salt is an alkaline metal nitrate salt, the first nitrate salt reacting with the graphite to oxidize the graphite and produce a carbonate salt of the alkaline metal.
13. The method according to claim 1 , further comprising regenerating the first nitrate salt following the oxidation reaction.
14. The method according to claim 1 , wherein the first nitrate salt is sodium nitrate.
15. The method according to claim 1 , wherein the first nitrate salt is nitric acid.
16. The method according to claim 1 , the fuel particle further comprising an external carbon layer, the first nitrate salt reacting with the carbon of the external carbon layer to oxidize the carbon.
17. The method according to claim 1 , further comprising pre-treating the fuel element.
18. The method according to claim 1 , wherein the first nitrate salt is contacted with the fuel element at a controlled rate during the course of the degradation reaction.
19. The method according to claim 1 , wherein the fuel element is a spherical fuel element.