The present invention provides novel cathodes having a reduced resistivity and other improved electrical properties. Furthermore, this invention also presents methods of manufacturing novel electrochemical cells and novel cathodes. These novel cathodes comprise a silver material that is doped with a trivalent species.
1. A battery comprising
a cathode comprising a silver material that is doped with a trivalent dopant;
an anode comprising zinc; and
an electrolyte;
wherein the trivalent dopant comprises indium, gallium, boron ytterbium, or any combination thereof, and the dopant is present in a concentration of from about 0.25 wt % to about 10 wt % by weight of the cathode.
2. The battery of claim 1 , wherein the silver material comprises a powder.
3. The battery of claim 2 , wherein the powder has a mean particle diameter of about 20 μm or less.
4. The battery of claim 3 , wherein the powder has a mean particle diameter of about 5 μm or less.
5. The battery of claim 2 , wherein the cathode, the anode, or both comprise a binder.
6. The battery of claim 5 , wherein the cathode further comprises a binder.
7. The battery of claim 6 , wherein the binder comprises PTFE or PVDF.
8. The battery of claim 5 , wherein the anode further comprises a binder.
9. The battery of claim 8 , wherein the binder comprises PTFE or PVDF.
10. The battery of claim 1 , wherein the electrolyte comprises NaOH, KOH, or a combination thereof.
11. The battery of claim 1 , wherein the silver material comprises Ag, AgO, Ag 2 O, Ag 2 O 3 , AgOH, AgOOH, AgONa,AgCuO 2 , AgFeO 2 , AgMnO 2 , Ag(OH) 2 , or any combination thereof.
12. The battery of claim 1 , wherein the trivalent dopant comprises indium, gallium, boron, or any combination thereof.