HIGH-ASPECT-RATIO IMPRINTED STRUCTURE METHOD
A method of making a high-aspect-ratio imprinted structure includes providing a substrate, forming a first layer on the substrate, imprinting a plurality of micro-channels in the first layer, and curing the first layer. Each micro-channel has a bottom and walls, the micro-channel bottom having distinct first and second portions. A material is deposited on the first layer and in each micro-channel and anisotropically etched to remove the deposited material from the first layer and the second portion of the micro-channel bottom, leaving the deposited material on the micro-channel walls. A filler material is located in the micro-channels between the deposited materials and on only the second portion of the micro-channel bottom and cured.
1 . A method of making a high-aspect-ratio imprinted structure, comprising:
providing a substrate having a surface;
forming a curable first layer on the surface, imprinting a plurality of micro-channels in the curable first layer, and curing the curable first layer to form a cured first layer having imprinted micro-channels, each with a micro-channel bottom and micro-channel walls, the micro-channel bottom having distinct first and second portions;
depositing a material on the cured first layer and in each micro-channel on the micro-channel walls and on both the first and second portions of the micro-channel bottom;
anisotropically etching the material to remove the deposited material from the cured first layer and the second portion of the micro-channel bottom, leaving the deposited material on the micro-channel walls;
locating a curable filler material in the micro-channels between the deposited materials and on only the second portion of the micro-channel bottom and curing the curable filler material; and
curing the curable filler material.
2 . The method of claim 1 , further including coating the deposited material in the micro-channels with an oxide.
3 . The method of claim 2 , further including anisotropically etching the oxide to remove the oxide from the deposited material on the cured first layer and at least the second portion of the micro-channel bottom, leaving oxide coating the deposited material on the micro-channel walls.
4 . The method of claim 1 further including forming a curable second layer over the cured first layer and curing the curable second layer to form a cured second layer.
5 . The method of claim 1 further including at least partially filling the micro-channels with curable filler material and curing the curable filler material to form a cured filler.
6 . The method of claim 5 further including forming a curable second layer over the cured first layer and at least partially filling the micro-channels in a common step with a common material, removing the curable second layer from the first cured layer but not the imprinted micro-channels, and curing the curable filler material to form a cured filler.
7 . The method of claim 1 further including forming a curable second layer over the cured first layer and at least partially filling the micro-channels in a common step with a common material and then curing the common material to form a cured second layer and a cured filler.
8 . The method of claim 1 further including anisotropically etching the deposited material with a low-pressure plasma etch.
9 . The method of claim 8 further including anisotropically etching the deposited material with a low-pressure plasma etch containing a passivating gas.
10 . The method of claim 8 further including anisotropically etching the deposited material with a low-pressure plasma etch containing a fluorocarbon.
11 . The method of claim 1 further including coating the first cured layer and each imprinted micro-channel with a metal material.
12 . The method of claim 1 further including coating the cured first layer and each imprinted micro-channel using atomic layer deposition (ALD).
13 . The method of claim 1 further including coating the cured first layer and each imprinted micro-channel using evaporation.
14 . The method of claim 1 further including coating the cured first layer and each imprinted micro-channel using sputtering.
15 . The method of claim 1 further including coating the first cured layer and each imprinted micro-channel using a material source.
16 . The method of claim 15 further including orienting the material source so that material from the material source travels from the material source towards the substrate surface at a non-orthogonal angle.
17 . The method of claim 15 further including rotating the material source with respect to the substrate surface at a non-orthogonal angle.
18 . The method of claim 1 further including partially curing the first layer, depositing a second layer over the first layer and the deposited material, and then curing the first layer and the second layer in a common step that cross links the first layer to the second layer.
19 . The method of claim 1 further including depositing filler material in the micro-channels between the deposited material on the micro-channel walls, depositing a second layer over the first layer and then curing the second layer and the filler material in a common step that cross links the second layer to the filler material.
20 . A privacy screen, a wire grid polarizer, a plasmonic device or, a grating made by the method of claim 1 .