IP Library Granted Patent US 9,273,217
Granted Patent B2
US 9,273,217 · App. 14/230,098 · Granted Mar 1, 2016

Composition that can be screen printed onto polyvinyl butyral

Inventors: Sebastien Wery (Compiegne, FR); Elodie Ducourthial (Compiegne, FR); Angelique Debraine (Grandefresnoy, FR); Benoit Barbier (Jette, BE); Virginie Duclaux (Paris, FR)
Assignee: SAINT-GOBAIN GLASS FRANCE
C09D11/106B32B17/10339Y10T428/24802Y10T428/24868
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Quick Facts
Patent No.
US 9,273,217
App. No.
14/230,098
Granted
Mar 1, 2016
Kind
B2
Abstract

The invention relates to a composition suitable for the black printing, via screen printing, of a sheet of polyvinyl butyral intended to be part of a laminated glazing unit, characterized in that it comprises: 11% to 13% by weight of polyvinyl butyral, 35% to 40% by weight of at least one aliphatic dicarboxylic acid diester, and at least one black pigment in an amount and with a specific surface area that are selected so that the Brookfield viscosity of the composition at 20° C. is between 9 and 13 Pa·s; a process for printing, via screenprinitng, a sheet of polyvinyl butyral intended to be part of a laminated glazing unit, using this composition; a sheet of polyvinyl butyral intended to be part of a laminated glazing unit, and printed, via screen printing, using this composition; and a laminated glazing unit comprising such a sheet of polyvinyl butyral.

Claims (42)

1. A composition suitable for the black printing, via screen printing, of a sheet of polyvinyl butyral, wherein the composition comprises:

from 3% to 5% by weight of cyclohexanone;

from 11% to 13% by weight of polyvinyl butyral;

from 35% to 40% by weight of at least one aliphatic dicarboxylic acid diester;

an effective amount of a surface tension modifier that does not contain silicone; and

at least one black pigment in an amount and with a specific surface area such that the Brookfield viscosity of the composition at 20° C. is between 9 and 13 Pa·s,

wherein the surface tension modifier is a polyacrylate.

2. The composition of claim 1 , wherein the polyvinyl butyral contained in the composition has a molecular weight evaluated by gel permeation chromatography centered about a value at most equal to 90 000 in polystyrene equivalents.

3. The composition of claim 1 , wherein the polyvinyl butyral contained in the composition has a molecular weight evaluated by gel permeation chromatography centered about a value at least equal to 20 000 in polystyrene equivalents.

4. The composition of claim 1 , wherein the [OH] content of the polyvinyl butyral contained in the composition corresponds to a weight percentage of poly(vinyl alcohol) between 17% and 22%.

5. The composition of claim 1 , wherein said at least one aliphatic dicarboxylic acid diester is a succinate, a glutarate, or an adipate.

6. The composition of claim 1 , wherein said at least one black pigment is a mixture of carbon black and black iron oxide.

7. The composition of claim 1 , further comprising:

an effective amount of plasticizer as wetting agent.

8. The composition of claim 1 , wherein said at least one black pigment is a mixture of carbon black and black iron oxide, and the composition comprises:

from 8% to 12% by weight of carbon black; and

from 28% to 32% by weight of black iron oxide.

9. The composition of claim 8 , wherein the aliphatic dicarboxylic acid diester is a mixture of a succinate, a glutarate, and an adipate.

10. A process for printing, via screen printing, a sheet of polyvinyl butyral, the process comprising:

applying the composition of claim 1 to the sheet of polyvinyl butyral, through a screen-printing screen.

11. The process of claim 10 , wherein a thickness of a wet layer of composition applied to the polyvinyl butyral sheet is between 10 and 50 μm.

12. A composition suitable for the black printing, via screen printing, of a sheet of polyvinyl butyral, wherein the composition comprises:

from 5% to 10% by weight of at least one plasticizer selected from group consisting of a benzoate ester, a phthalate, an adipate, a fatty acid ester, a trioctyl trimellitate, a triacetin, a glycerol, a propylene glycol, a sorbitol, and a trimethylpentanediol diisobutyrate;

from 11% to 13% by weight of polyvinyl butyral;

from 35% to 40% by weight of at least one aliphatic dicarboxylic acid diester;

an effective amount of a surface tension modifier that does not contain silicone; and

at least one black pigment in an amount and with a specific surface area such that the Brookfield viscosity of the composition at 20° C. is between 9 and 13 Pa·s,

wherein the surface tension modifier is a polyacrylate.

13. The composition of claim 12 , wherein the plasticizer is dimethylcyclohexyl phthalate.

14. The composition of claim 12 , wherein the polyvinyl butyral contained in the composition has a molecular weight evaluated by gel permeation chromatography centered about a value of a least equal to 20 000 and at most equal to 90 000 in polystyrene equivalents.

15. The composition of claim 12 , wherein the [OH] content of the polyvinyl butyral contained in the composition corresponds to a weight percentage of poly(vinyl alcohol) between 17% and 22%.

16. The composition of claim 12 , wherein said at least one aliphatic dicarboxylic acid diester is a succinate, a glutarate, or an adipate.

17. The composition of claim 12 , wherein said at least one black pigment is a mixture of carbon black and black iron oxide.

18. A composition suitable for the black printing, via screen printing, of a sheet of polyvinyl butyral, wherein the composition consists of:

from 11% to 13% by weight of polyvinyl butyral;

from 5% to 10% by weight of a wetting agent;

from 8% to 12% by weight of carbon black;

from 28% to 32% by weight of black iron oxide;

from 35% to 40% by weight of at least one aliphatic dicarboxylic acid diester;

from 3% to 5% by weight of cyclohexanone;

from 0.5% to 2% by weight of a surface tension modifier that does not contain silicone, wherein the surface tension modifier is a polyacrylate; and

wherein the composition has a Brookfield viscosity at 20° C. between 9 and 13 Pa·s.

Assignments (2)
NUNC PRO TUNC ASSIGNMENT Recorded May 16, 2025
From: SAINT-GOBAIN GLASS FRANCE
To: SAINT-GOBAIN SEKURIT FRANCE
Reel/Frame 071969/0743 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 20, 2016
From: WERY, SEBASTIEN; DUCOURTHIAL, ELODIE; BARBIER, BENOIT; DUCLAUX, VIRGINIE
To: SAINT-GOBAIN GLASS FRANCE
Reel/Frame 037534/0237 →
Priority Claims (1)
FR 11 53189 · Apr 12, 2011 · national
Continuity (2)
Continuation 14111340
Related Publication 20140212639A1 · Jul 31, 2014