Hydrogenated block copolymer, resin composition, film and container
View Patent ↗The present invention provides a hydrogenated block copolymer which has an excellent balance in a transparency, optical property, flexibility, mechanical property, moldability, heat resistance, gas barrier property, low moisture absorbency and non-adsorptive property of chemical. Also, the present invention has an object to provide a resin composition containing the hydrogenated block copolymer as a resin component, and a film and container containing the composition. The present invention relates to a hydrogenated block copolymer containing a Block A of a hydrogenated vinyl aromatic polymer and a Block B of a polymer containing isobutylene.
1. A hydrogenated block copolymer comprising:
(A) a hydrogenated vinyl aromatic polymer block; and
(B) a polymer block mainly comprising isobutylene,
wherein the polymer block (B) comprises 70% by mass or more of isobutylene as a monomer component.
2. The hydrogenated block copolymer as claimed in claim 1 , wherein the hydrogenated block copolymer has a weight average molecular weight of 10,000 or more and 200,000 or less.
3. The hydrogenated block copolymer as claimed in claim 1 , wherein the hydrogenated vinyl aromatic polymer block (A) is a hydrogenated polystyrene block in which the aromatic ring is hydrogenated.
4. The hydrogenated block copolymer as claimed in claim 1 , wherein the hydrogenation rate of the aromatic ring of the hydrogenated vinyl aromatic polymer block (A) is 50% by mol or more.
5. The hydrogenated block copolymer as claimed in claim 1 , wherein the hydrogenated block copolymer comprises two blocks of the hydrogenated vinyl aromatic polymer block (A) and one block of the polymer block (B).
6. The hydrogenated block copolymer as claimed in claim 1 , wherein the content ratio of the hydrogenated vinyl aromatic polymer block (A) based on the total mass of the hydrogenated block copolymer is 40% by mass or less.
7. A resin composition comprising the hydrogenated block copolymer described in claim 1 .
8. The resin composition as claimed in claim 7 , which further comprises a polyolefin containing propylene, the propylene being a main component of the polyolefin.
9. The resin composition as claimed in claim 8 , wherein the polyolefin containing propylene is a copolymer of propylene and at least one of ethylene and an olefin having 4 to 8 carbon atoms.
10. The resin composition as claimed in claim 8 , wherein the content of the hydrogenated block copolymer is 10 to 90% by mass and the content of the polyolefin containing propylene is 90 to 10% by mass.
11. The resin composition as claimed in claim 7 , further comprising at least one amorphous polyolefin selected from a copolymer of ethylene and a cyclic olefin and a hydrogen additive of a ring-opened polymer of a cyclic olefin.
12. The resin composition as claimed in claim 11 , wherein the content of the hydrogenated block copolymer is 5 to 90% by mass and the content of the at least one amorphous polyolefin is 95 to 10% by mass.
13. The resin composition as claimed in claim 7 , which further comprises at least one polymer selected from a hydrogenated vinyl aromatic polymer and a block copolymer having a hydrogenated vinyl aromatic polymer block and a block of a polymer mainly containing a hydrogenated conjugate diene.
14. The resin composition as claimed in claim 13 , wherein the content of the hydrogenated block copolymer is 5 to 90% by mass and the content of the at least one polymer is 95 to 10% by mass.
15. A film comprising the resin composition described in claim 7 .
16. A container comprising the resin composition described in claim 7 .