IP Library Granted Patent US 9,487,648
Granted Patent B2
US 9,487,648 · App. 14/232,209 · Granted Nov 8, 2016

High flow polyolefin composition with low shrinkage and CLTE

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Quick Facts
Patent No.
US 9,487,648
App. No.
14/232,209
Granted
Nov 8, 2016
Kind
B2
Abstract

Polyolefin composition comprising (a) a heterophasic propylene copolymer comprising a polypropylene (PP) having a melt flow rate MFR 2 (230° C.) of 30 to 350 g/10 min, and an elastomeric propylene copolymer (E) having an intrinsic viscosity (IV) in the range of 1.5 to 3.0 dl/g and (b) a polyethylene having a melt flow rate MFR 2 (190° C.) of 15 to 100 g/10 min, wherein (i) the total polyolefin composition has a melt flow rate MFR 2 (230° C.) of more than 15 to 200 g/10 min, and (ii) the weight ratio of elastomeric propylene copolymer to the polyethylene is below 2.0.

Claims (31)

1. Polyolefin composition (PO) comprising:

(a) a heterophasic propylene copolymer (HECO) comprising:

(a1) a polypropylene (PP) having a melt flow rate MFR 2 (230° C.) of 30 to 350 g/10 min, and

(a2) an elastomeric propylene copolymer (E) having an intrinsic viscosity (IV) in the range of 1.5 to 3.0 dl/g measured as the intrinsic viscosity (IV) of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO), and

(b) a polyethylene (PE) having a melt flow rate MFR 2 (190° C.) of 25 to 80 g/10 min, wherein, the polyethylene (PE) is an ethylene homopolymer and has a density of at least 945 kg/m 3 , wherein further:

(i) the total polyolefin composition (PO) has a melt flow rate MFR 2 (230° C.) of more than 15 to 200 g/10min, and

(ii) the weight ratio of the elastomeric propylene copolymer (E) to the polyethylene (PE) is below 2.0.

2. Polyolefin composition (PO) according to claim 1 , wherein:

(a) the amount of the elastomeric propylene copolymer (E) within the heterophasic propylene copolymer (HECO) is 20 to 50 wt. %, and/or

(b) the elastomeric propylene copolymer (E) has a comonomer content of 15to 75 wt. %, the comonomers are ethylene and/or a C 4 to C 12 α-olefin.

3. Polyolefin composition (PO) according to claim 1 , wherein the polypropylene (PP) has:

(a) a melting temperature of at least 135° C., and/or

(b) a comonomer content of equal or below 10 wt. %, the comonomers are ethylene and/or a C 4 to C 12 α-olefin.

4. Polyolefin composition (PO) according to claim 1 , wherein the polypropylene (PP) is a propylene homopolymer (H-PP).

5. Polyolefin composition (PO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has:

(a) a melt flow rate MFR 2 (230° C.) of more than 15 to 300 g/10 min, and/or

(b) a comonomer content in the range of 6.0 to 18 wt. %, the comonomers are ethylene and/or a C 4 to C 12 α-olefin.

6. Polyolefin composition (PO) according to claim 1 , wherein the polyolefin composition (PO) comprises up to 30 wt. % of an inorganic filler.

7. Polyolefin composition (PO) according to claim 6 , wherein the inorganic filler has a cutoff particle size d95 [mass percent] of equal or below 20 μm.

8. Polyolefin composition (PO) according to claim 1 , wherein the polyolefin composition (PO) comprises up to 30 wt. % of a polyethylene (PE2) having:

(a) a density of below 940 kg/m 3 , and/or

(b) a melt flow rate MFR 2 (190° C.) of 0.5 to 30 g/10 min,

with the proviso that the polyethylene (PE2) differs from the polyethylene (PE) in density and/or melt flow rate.

9. Polyolefin composition (PO) according to claim 1 , wherein the polyolefin composition (PO) has:

(a) a tensile modulus of at least 900 MPa, and/or

(b) an impact strength at 23° C. of at least 10 kJ/m 2 , and/or

(c) a coefficient of linear thermal expansion (CLTE) performed in a temperature range from −30 to +80° C. of not more than 100 μm/mK.

10. Automotive article comprising the polyolefin composition (PO) according to claim 1 .

11. Automotive article according to claim 10 , wherein the automotive article is an exterior automotive article.

12. Process for the preparation of the polyolefin composition (PO) according to claim 1 , comprising extruding the heterophasic propylene copolymer (HECO), the polyethylene (PE), and optionally the inorganic filler (F) and the polyethylene (PE2), in an extruder.

13. Process according to claim 12 , wherein the heterophasic propylene copolymer (HECO) is obtained by producing the polypropylene (PP) in one reactor, transferring said polypropylene (PP) in a subsequent reactor, where in the presence of the polypropylene (PP) the elastomeric propylene copolymer (E) is produced.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 7, 2014
From: GAHLEITNER, MARKUS; GRESTENBERGER, GEORG; GREIN, CHRISTELLE; TRANNINGER, CORNELIA
To: BOREALIS AG
Reel/Frame 032619/0611 →