Temporary adhesion of chemically similar substrates
A temporary adhesive for reversibly bonding a silicon wafer to a silicon support contains a crosslinkable organopolysiloxanes composition and a fatty acid or salt thereof or fatty acid ester as a release regulator having a density different from the crosslinkable organopolysiloxanes composition of at least 0.1 g/cm 3 , which upon parting of the wafer from the substrate, the adhesive remains substantially adhered to the substrate.
1. A process for the temporary adhesive bonding of a silicon wafer to a silicon support, comprising applying an adhesive to the support, wherein
the adhesive is a crosslinkable silicone composition comprising at least 0.01 to 10 wt % of at least one release agent selected from the group consisting of fatty acids and their metal salts, fatty acid esters of saturated or unsaturated fatty acids, and combinations thereof, and bonding the silicon wafer to the support by the adhesive,
wherein the release agent has at least a density difference of 0.10 g/cm 3 as compared with the density of the silicone composition and as a result the adhesive force between the cured adhesive and the silicon support is greater by at least 0.5 N/mm than the adhesive force between the cured adhesive and the silicon wafer, measured according to DIN ISO 813, and the cured adhesive can be parted adhesively from at least 80% of the area of the silicon wafer on parting of a bond between the silicon wafer and the silicon support.
2. The process of claim 1 , wherein the crosslinkable silicone composition is selected from the group consisting of condensation-crosslinking, addition-crosslinking, and peroxidically crosslinking silicone compositions.
3. A method for the temporary adhesive bonding of a silicon wafer to a silicon support, comprising:
a) applying an adhesive to a silicon wafer, wherein the adhesive is a crosslinkable silicone composition comprising at least 0.01 to 10 wt % of at least one release agent selected from the group consisting of fatty acids and their metal salts, fatty acid esters of saturated or unsaturated fatty acids, and combinations thereof,
wherein the release agent has at least a density difference of 0.10 g/cm 3 as compared with the density of the silicone composition and as a result the adhesive force between the cured adhesive and the silicon support is greater by at least 0.5 N/mm than the adhesive force between the cured adhesive and the silicon wafer, measured according to DIN ISO 813, and the cured adhesive can be parted adhesively from at least 80% of the area of the silicon wafer on parting of a bond between the silicon wafer and the silicon support,
b) observing a waiting time of 10 seconds to 120 minutes wherein any solvent present is removed during the waiting time,
d) contacting the silicon support with the adhesive,
e) curing the adhesive,
f) implementing further working steps on the silicon wafer and/or the silicon support,
g) separating the silicon wafer and silicon support, with the cured adhesive remaining on the silicon support.
4. A method for the temporary adhesive bonding of a silicon wafer to a silicon support, comprising:
a) applying an adhesive to a silicon wafer, wherein the adhesive is a crosslinkable silicone composition comprising at least 0.01 to 10 wt % of at least one release agent selected from the group consisting of fatty acids and their metal salts, fatty acid esters of saturated or unsaturated fatty acids, and combinations thereof,
wherein the release agent has at least a density difference of 0.10 g/cm 3 as compared with the density of the silicone composition and as a result the adhesive force between the cured adhesive and the silicon support is greater by at least 0.5 N/mm than the adhesive force between the cured adhesive and the silicon wafer, measured according to DIN ISO 813, and the cured adhesive can be parted adhesively from at least 80% of the area of the silicon wafer on parting of a bond between the silicon wafer and the silicon support,
b) observing a waiting time of 10 seconds to 120 minutes wherein any solvent present is removed during the waiting time,
d) contacting the silicon support with the adhesive,
e) curing the adhesive,
f) implementing further working steps on the silicon wafer and/or the silicon support,
g) separating the silicon wafer and silicon support, with the cured adhesive remaining on the silicon support,
wherein the crosslinkable silicone composition is selected from the group consisting of condensation-crosslinking, addition-crosslinking, and peroxidically crosslinking silicone compositions.