High-strength galvanized steel sheet excellent in bendability and manufacturing method thereof
View Patent ↗The present invention provides a high-strength galvanized steel sheet with maximum tensile strength of 900 MPa or more. The high-strength galvanized steel sheet has an alloyed galvanized layer formed on a surface of a base steel sheet containing predetermined amounts of C, Si, Mn, P, S, Al, N, O with a balance being constituted of iron and inevitable impurities, in which in a structure of the base steel sheet, retained austenite is limited to 8% or less in volume fraction, kurtosis K* of the hardness distribution between 2% hardness and 98% hardness is −0.30 or less, a ratio between Vickers hardness of surface layer of the base steel sheet and Vickers hardness of ¼ thickness of the base steel sheet is 0.35 to 0.70, and a content of iron in the alloyed galvanized layer is 8 to 12% in mass %.
1. A high-strength galvanized steel sheet excellent in bendability with maximum tensile strength of 900 MPa or more, comprising an alloyed galvanized layer formed on a surface of a base steel sheet containing, in mass %,
C: 0.075 to 0.300%,
Si: 0.30 to 2.50%,
Mn: 1.30 to 3.50%,
P: 0.001 to 0.050%,
S: 0.0001 to 0.0100%,
Al: 0.005 to 1.500%,
N: 0.0001 to 0.0100%, and
O: 0.0001 to 0.0100% with a balance being constituted of iron and inevitable impurities, wherein:
retained austenite is limited to 8% or less in volume fraction in a range of ⅛ thickness to ⅜ thickness of the base steel sheet;
when plural measurement regions with a diameter of 1 μm or less are set in the range of ⅛ thickness to ⅜ thickness of the base steel sheet, measurement values of hardness in the plural measurement regions are arranged in an ascending order to obtain a hardness distribution, an integer N0.02 is obtained, which is a number obtained by multiplying a total number of measurement values of hardness by 0.02 and rounding up this number when this number includes a fraction, hardness of a measurement value which is N0.02-th largest from a measurement value of minimum hardness is taken as 2% hardness, an integer N0.98 is obtained, which is a number obtained by multiplying a total number of measurement values of hardness by 0.98 and rounding down this number when this number includes a fraction, and hardness of a measurement value which is N0.98-th largest from a measurement value of minimum hardness is taken as 98% hardness, kurtosis K* of the hardness distribution between the 2% hardness and the 98% hardness is −0.30 or less;
a ratio between Vickers hardness of surface layer of the base steel sheet and Vickers hardness of ¼ thickness of the base steel sheet is 0.35 to 0.70; and
a content of iron in the alloyed galvanized layer is 8 to 12% in mass %.
2. The high-strength galvanized steel sheet excellent in bendability according to claim 1 , wherein the structure of the base steel sheet contains, in volume fraction, 10 to 75% ferrite, 10 to 50% in total of either or both of bainitic ferrite and bainite, 10 to 50% tempered martensite in the range of ⅛ thickness to ⅜ thickness of the base steel sheet, the fresh martensite is limited to 15% or less in volume fraction, and perlite is limited to 5% or less in volume fraction.
3. The high-strength galvanized steel sheet excellent in bendability according to claim 1 , wherein the base steel sheet further contains, in mass %, one or more of
Ti: 0.005 to 0.150%,
Nb: 0.005 to 0.150%,
B: 0.0001 to 0.0100%,
Cr: 0.01 to 2.00%,
Ni: 0.01 to 2.00%,
Cu: 0.01 to 2.00%,
Mo: 0.01 to 1.00%,
W: 0.01 to 1.00%, and
V: 0.005 to 0.150%, and/or
0.0001 to 0.5000 mass % in total of one or more selected from the group consisting of Ca, Ce, Mg, Zr, Hf, and an element other than Ce belonging to the lanthanoid series.
4. The high-strength galvanized steel sheet excellent in bendability according to claim 1 , wherein either or both of a coating film constituted of a phosphorus oxide and a coating film constituted of a composite oxide containing phosphorus is or are formed on a surface of the alloyed galvanized layer.