Low phosphorus chabazites
View Patent ↗A catalyst composition is provided having a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO 2 and Al 2 O 3 in a mole ratio of about 5 to about 40. The catalyst composition is capable of NOx conversion at elevated temperatures. A catalytically active washcoat includes such catalyst compositions and one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article. Methods of reducing NOx employing the catalyst compositions are also provided.
1. A composition comprising a crystalline structure, wherein at least a portion of the crystalline structure is a molecular sieve having a chabazite framework consisting of thirty-six T-atoms selected from the group consisting of silicon, aluminum, and phosphorus;
wherein said molecular sieve comprises about 0.05 to about 5.0 mole percent of framework phosphorus based on the total moles of framework silicon, aluminum, and phosphorus in said molecular sieve; and
wherein said molecular sieve has a silica-to-alumina mole ratio of at least about 10.
2. The composition of claim 1 wherein said molecular sieve comprises about 0.05 to about 1.0 mole percent of framework phosphorus based on the total moles of framework silicon, aluminum, and phosphorus in said molecular sieve.
3. The composition of claim 1 wherein said molecular sieve comprises about 80 to about 90 mole percent of said framework Si and about 10 to about 20 combined mole percent of said framework Al and P, based on the total moles of said framework Si, Al, and P in said molecular sieve.
4. The composition of claim 1 wherein said framework phosphorus is present as —PO 2 moieties, said framework silicon in present as —SiO 2 moieties, and framework aluminum is present as —AlO 2 moieties.
5. The composition of claim 1 wherein said molecular sieve material further comprises about 0.025 to about 5 w/w % of extra-framework copper on an anhydrous molecular sieve basis.
6. The composition of claim 1 wherein said molecular sieve material further comprises about 0.025 to about 5 w/w % of extra-framework iron on an anhydrous molecular sieve basis.
7. A method for reducing NOx in an exhaust gas comprising contacting the gas with a catalyst for a time and temperature sufficient to reduce the level of NOx compounds in the gas, wherein the catalyst is a catalyst comprising a composition according to claim 1 .
8. A composition comprising a molecular sieve material having a CHA framework, wherein the framework consists of periodic building units having 36 interlinked T-atoms selected from the group consisting of aluminum, silicon, and phosphorus, and wherein said molecular sieve material has a mean phosphorus concentration of about 0.5 to about 1.5 atoms per periodic building unit.
9. The composition of claim 8 wherein said mean phosphorus concentration is about 1.0 to about 1.5 atoms per periodic building unit.
10. The composition of claim 8 wherein said molecular sieve material has a silica-to-alumina ratio of at least about 10.
11. The composition of claim 8 wherein said molecular sieve material has a silica-to-alumina ratio of at least about 10 and an Al:P ratio of greater than about 1.
12. The composition of claim 8 wherein said molecular sieve material has a silica-to-alumina ratio of at least about 10 and an Al:P ratio of greater than about 10.
13. The composition of claim 8 wherein said molecular sieve material has a silica-to-alumina ratio of at least about 10 and an Al:P ratio of greater than about 100.
14. The composition of claim 8 wherein said phosphorus is connected to at least a portion of said aluminum via oxygen bridges.
15. The composition of claim 8 wherein said molecular sieve material further comprises a non-aluminum base metal.
16. The composition of claim 15 wherein said non-aluminum base metal is ion-exchanged.
17. The composition of claim 16 wherein said non-aluminum base metal is copper.
18. The composition of claim 16 wherein said non-aluminum base metal is iron.