Method for recovering polymer and apparatus therefor
View Patent ↗Process and apparatus for recovering polymer from a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.
1. A process for recovering polymer from a gas phase reactor ( 3 ), the gas phase reactor ( 3 ) having a distribution plate and being connected to an outlet vessel ( 1 ) via a feed pipe ( 2 ) and a return gas line ( 5 ), the outlet vessel ( 1 ) comprising at least one apparatus for the breakup of polymeric agglomerates ( 4 ), whereby the gas phase reactor ( 3 ) and the outlet vessel ( 1 ) are connected by a connecting passage including the feed pipe ( 2 ), wherein the connecting passage allows the transport of agglomerates having a maximum three dimensional diameter of 30 cm and whereby the connecting passage ( 2 ) and the outlet vessel ( 1 ) are not equipped with a sieve,
the process comprising:
continuously discharging polymeric material from the gas phase reactor ( 3 ) via the feed pipe ( 2 ) to the outlet vessel ( 1 ),
passing the polymeric material into the at least one apparatus for breakup of polymeric agglomerates ( 4 ),
recovering polymer from the outlet vessel ( 1 ), whereby
the bed level height in the gas phase reactor ( 3 ) and the flow through the feed pipe ( 2 ) are controlled by controlling the flow rate through the return gas line ( 5 ) from the outlet vessel ( 1 ) to the gas phase reactor ( 3 ), and/or by controlling the outlet rate of polymer product from the outlet vessel ( 1 ).
2. Process according to claim 1 , wherein the average mean residence time of polymeric material in the outlet vessel ( 1 ) is less than 60 seconds, whereby the average mean residence time is V P /Q D , V, being the average volume of the polymer bed in the outlet vessel and Q, being the volumetric exit rate of the polymer.
3. Process according to claim 1 , wherein the polymeric material discharged from the gas phase reactor ( 3 ) comprises polymer powder and polymer agglomerates.
4. Process according to claim 1 , wherein the polymer recovered from the outlet vessel ( 1 ) is a polyethylene and/or polypropylene homo- or copolymers.
5. Process according to claim 1 , whereby the polymer recovered from the outlet vessel ( 1 ) is a polyethylene homo- or copolymer having a density of below 925 kg/m 3 .
6. Process according to claim 4 , whereby the polyethylene(s) have a melt flow rate (21.6 kg load, ISO 1133, 190° C.) of 2 g/10 min or higher and polypropylene homo- or copolymer(s) have a melt flow rate (2.16 kg load, ISO 1133, 230° C.) of 20 g/10 min or higher.
7. An apparatus for recovering polymer, the apparatus comprising:
a gas phase reactor ( 3 ) having a distribution plate,
an outlet vessel ( 1 ) comprising at least one apparatus for the breakup of polymeric agglomerates ( 4 ) and an outlet ( 9 ) for the polymer,
a feed pipe ( 2 ) connecting the gas phase reactor ( 3 ) and the outlet vessel ( 1 )
a return gas line ( 5 ) connecting the gas phase reactor ( 3 ) and the outlet vessel ( 1 ),
means for varying the flow rate ( 12 ) through the return gas line ( 5 ) from the outlet vessel ( 1 ) to the gas phase reactor ( 3 ), and
means for varying the outlet rate ( 13 ) of polymer product from the outlet vessel ( 1 ),
wherein the gas phase reactor ( 3 ) and the outlet vessel ( 1 ) are connected by a connecting passage including the feed pipe ( 2 ), wherein the connecting passage ( 2 ) allows the transport of agglomerates having a maximum three dimensional diameter of 30 cm and wherein the connecting passage ( 2 ) and the outlet vessel ( 1 ) do not contain a sieve.
8. The apparatus according to claim 7 , wherein the feed pipe ( 2 ) is connected to the gas phase reactor ( 3 ) above the distribution plate in a height less than ¼ of the effective diameter of the distribution plate measured from the upper edge of the distribution plate in vertical direction.
9. Apparatus according to claim 7 , whereby the inner diameter of the feed pipe ( 2 ) is 30 cm or less and/or whereby the inner diameter of the feed pipe ( 2 ) is at least 10 cm.
10. Method for the production of polyethylene and/or polypropylene homo- or copolymer(s) with an apparatus according to claim 7 .
11. Method according to claim 10 for the production of polyethylene homo- or copolymer(s) having a density of below 925 kg/m 3 .
12. Method according to claim 10 , whereby the polyethylene(s) have a melt flow rate (21.6 kg load, ISO 1133, 190° C.) of 2 g/10 min or higher and the polypropylene homo- or copolymer(s) have a melt flow rate (2.16 kg load, ISO 1133, 230° C.) of 20 g/10 min or higher.