Battery separator, and battery separator manufacturing method
View Patent ↗A battery separator includes a porous membrane A with a thickness of less than 10 μm including a polypropylene resin, and a porous membrane B laminated thereon including a heat resistant resin and inorganic particles or cross-linked polymer particles, wherein the porous membrane A satisfies a specific range of thickness, average pore size, and porosity, and the entire battery separator satisfies a specific range of thickness, peeling strength at the interface between the porous membrane A and the porous membrane B, and difference in air resistance between the entire battery separator and the porous membrane A.
1. A battery separator comprising: a porous membrane A comprising a polypropylene resin, and a porous membrane B laminated thereon comprising a heat resistant resin and inorganic particles or cross-linked polymer particles, wherein the porous membrane A satisfies expressions (a) to (c), the battery separator satisfies expressions (d) to (f), and the heat resistant resin comprises a vinylidene fluoride homopolymer:
t ( A )<10 μm (a)
wherein t (A) is a thickness of the porous membrane A;
0.01 μm≦ R ( A )≦1.0 μm (b)
wherein R (A) is an average pore size of the porous membrane A;
30%≦ V ( A )≦70% (c)
wherein V (A) is a porosity of the porous membrane A:
t ( T )≦13 μm (d)
wherein t (T) is a thickness of the entire battery separator;
F ( A/B )≧1.0 N/25 mm (e)
wherein F (A/B) is a peeling strength at an interface between the porous membrane A and the porous membrane B; and
20 ≦Y−X≦ 100 (f)
wherein X is an air resistance (sec/100 cc Air) of the porous membrane A, and
Y is an air resistance (sec/100 cc Air) of the battery separator.
2. The battery separator according to claim 1 , wherein the battery separator has an air resistance of 50 to 600 sec/100 cc Air.
3. A process of producing the battery separator according to claim 1 , comprising steps (i) and (ii):
(i): applying a varnish comprising the heat resistant resin, which comprises the vinylidene fluoride homopolymer, and inorganic particles or cross-linked polymer particles to the porous membrane A comprising the polypropylene resin, and then passing the porous membrane A through a low humidity zone at an absolute humidity of not less than 0.5 g/m 3 and less than 6.0 g/m 3 and a high humidity zone at an absolute humidity of not less than 7.0 g/m 3 and less than 25.0 g/m 3 to form a heat resistant resin membrane on the porous membrane A; and
(ii): immersing the composite membrane obtained in step (i), in which the heat resistant resin membrane is laminated, in a coagulation bath to convert the heat resistant resin membrane into the porous membrane B, and washing and drying the porous membrane B to obtain the battery separator.
4. A process of producing the battery separator according to claim 2 , comprising steps (i) and (ii):
(i): applying a varnish comprising the heat resistant resin which comprises the vinylidene fluoride homopolymer and inorganic particles or cross-linked polymer particles to the porous membrane A comprising the polypropylene resin, and then passing the porous membrane A through a low humidity zone at an absolute humidity of not less than 0.5 g/m 3 and less than 6.0 g/m 3 and a high humidity zone at an absolute humidity of not less than 7.0 g/m 3 and less than 25.0 g/m 3 to form a heat resistant resin membrane on the porous membrane A; and
(ii): immersing the composite membrane obtained in step (i), in which the heat resistant resin membrane is laminated, in a coagulation bath to convert the heat resistant resin membrane into the porous membrane B, and washing and drying the porous membrane B to obtain the battery separator.
5. A battery separator obtained by a process comprising (i) and (ii):
(i): applying a varnish comprising a heat resistant resin which comprises a fluororesin vinylidene fluoride homopolymer and inorganic particles or cross-linked polymer particles to a porous membrane A comprising a polypropylene resin, and passing the porous membrane A through a low humidity zone at an absolute humidity of not less than 0.5 g/m 3 and less than 6.0 g/m 3 and a high humidity zone at an absolute humidity of not less than 7.0 g/m 3 and less than 25.0 g/m 3 to form a heat resistant resin membrane on the porous membrane A; and
(ii): immersing the composite membrane obtained in (i), in which the heat resistant resin membrane is laminated, converting the heat resistant resin membrane into a porous membrane B in a coagulation bath, and washing and drying the porous membrane B to obtain the battery separator, wherein the battery separator comprises the porous membrane A comprising the polypropylene resin, and the porous membrane B laminated thereon comprising the heat resistant resin and inorganic particles or cross-linked polymer particles, wherein the porous membrane A satisfies expressions (a) to (c), the battery separator satisfies expressions (d) to (f), and the heat resistant resin comprises the vinylidene fluoride homopolymer:
t ( A )<10 μm (a)
wherein t (A) is a thickness of the porous membrane A;
0.01 μm≦ R ( A )≦10 μm (b)
wherein R (A) is an average pore size of the porous membrane A;
30%≦ V ( A )≦70% (c)
wherein V (A) is a porosity of the porous membrane A:
t ( T )≦13 μm (d)
wherein t (T) is a thickness of the entire battery separator;
F ( A/B )≧1.0 N/25 mm (e)
wherein F (A/B) is a peeling strength at the interface between the porous membrane A and the porous membrane B; and
20≦ Y−X≧ 100 (f)
wherein X is an air resistance (sec/100 cc Air) of the porous membrane A, and
Y is an air resistance (sec/100 cc Air) of the battery separator.