Method for producing light ceramic materials
View Patent ↗The present invention relates to a novel process for producing ceramic materials, in particular refractory materials having a reduced relative density. In particular, the invention relates to a process for producing light, refractory materials having non-contiguous pores based on shaped and unshaped materials. These materials can be used as working lining in high-temperature applications. The process is based on the production of spherical, closed and isolated pores in the microstructure of the material. The pores having a pore diameter which can be set in a targeted manner are generated by use of polymer particles, in particular polymethacrylates, in particular polymers or copolymers prepared by means of suspension polymerization, as pore formers which can be burnt out. The polymers or copolymers are present in the form of small spheres having a defined diameter. The introduction of isolated spherical pores allows the production of ceramic materials having a sometimes significantly reduced relative density and improved corrosion resistance and better mechanical strength compared to the prior art. The specific, closed pore system at the same time contributes to reducing the thermal conductivity of the ceramic materials. In addition, the novel process has the advantage that there is no risk of formation of undesirable black cores, even in the production of thick-walled ceramic products.
1. A process for producing a ceramic material, the process comprising:
mixing a ceramic raw composition with from 0.5 to 90% by weight of spherical polymer particles having a diameter of from 5 μm to 3 mm, based on a sum of the ceramic raw composition and the spherical polymer particles, thereby forming a mixed mixture,
pressing the mixture to form the ceramic material,
subsequently drying the mixture,
optionally conditioning the mixture,
firing the mixture,
wherein the ceramic raw composition comprises more than 10% by weight of ceramic particles which are larger than 0.6 mm, the process further comprising:
baking the mixture at a temperature of at least 100° C. above a ceiling temperature,
wherein the spherical polymer particles are composed of a polymer having the ceiling temperature of less than 280° C.
2. The process according to claim 1 ,
wherein the spherical polymer particles have a monomodal particle size distribution.
3. The process according to claim 1 ,
wherein the polymer is a polymethacrylate, polyoxymethylene or poly-α-methylstyrene and
the spherical polymer particles have a diameter of from 10 μm and 200 μm.
4. The process according to claim 3 ,
wherein the polymethacrylate has an oxygen content of at least 25% by weight.
5. The process according to claim 4 ,
wherein the polymer is a polymethacrylate having a methyl methacrylate content of at least 80% by weight.
6. The process according to claim 1 ,
wherein a proportion of spherical polymer particles added to the ceramic raw composition is from 40 to 70% by weight.
7. The process according to claim 1 ,
wherein the spherical polymer particles are thermoplastic suspension polymers.
8. The process according to claim 1 ,
wherein the spherical polymer particles have a particle size distribution from 0.5 to 2.0.
9. The process according to claim 1 , wherein at list one of the following stage is performed:
conditioning the mixture.