Melt polymerization reactor system and method
View Patent ↗A reactor system for producing polycarbonate includes a surface area in contact with a reaction mixture. The reaction mixture comprises a melt transesterification catalyst, a dihydroxy compound, a diaryl carbonate, and an phenolic byproduct. The surface area in contact with the reaction mixture contains one or more welds joining reactor system parts. All welds in contact with the reaction mixture join reactor system parts made from the same type of metal. If a filler metal is contained in the weld, the filler metal is made from the same type of metal as the metal parts joined by the weld.
1. A melt polymerization reactor system for producing polycarbonate, the reactor system comprising a surface area in contact with a reaction mixture, wherein:
(I) the reaction mixture comprises a melt transesterification catalyst, a dihydroxy compound, an ester-substituted diaryl carbonate, and an ester-substituted phenol,
(II) the surface area in contact with the reaction mixture contains a weld joining metal reactor system parts,
(III) all welds in contact with the reaction mixture join reactor system parts made from the same type of metal, and
(IV) a filler metal is contained in the weld, the filler metal is made from the same type of metal as the metal parts joined by the weld.
2. The reactor system of claim 1 , wherein the surface area in contact with the reaction mixture has no welds containing stainless steel.
3. The reactor system of claim 1 , wherein the weld joining two reactor system parts is made from stainless steel, wherein the weld is passivated prior to contact with the reaction mixture.
4. A melt polymerization reactor system for producing polycarbonate, the reactor system comprising a surface area in contact with a reaction mixture, wherein:
(I) the reaction mixture comprises a melt transesterification catalyst, a dihydroxy compound, an ester-substituted diaryl carbonate, and an ester-substituted phenol,
(II) the surface area in contact with the reaction mixture has no welds containing stainless steel.
5. The reactor system of claim 1 , wherein the weld joins two reactor system parts made from nickel.
6. A method of forming polycarbonate comprising:
treating a reaction mixture in a melt polymerization reactor system operating under melt polymerization conditions sufficient to produce polycarbonate, and
forming the polycarbonate;
wherein:
(A) the reaction mixture comprises a melt transesterification catalyst, a dihydroxy compound, an ester-substituted diaryl carbonate, and a an ester-substituted phenol, and
(B) the reactor system comprises a surface area in contact with the reaction mixture, wherein:
(I) the surface area in contact with the reaction mixture contains a weld joining metal reactor system parts,
(II) all welds in contact with the reaction mixture join reactor system parts made from the same type of metal, and
(III) a filler metal is contained in the weld, the filler metal is made from the same type of metal as the metal parts joined by the weld.
7. The method claim 6 , wherein the weld joining two reactor system parts is made from stainless steel, wherein the weld is passivated prior to contact with the reaction mixture.
8. The method of claim 6 , wherein the weld joins two reactor system parts made from nickel.
9. The method of claim 6 , wherein the surface area in contact with the reaction mixture has no welds containing stainless steel.
10. The method of claim 6 , wherein the treating of the reaction mixture in a melt polymerization reactor system operating under melt polymerization conditions, is performed at a temperature of 100° C. to 400° C.
11. The method of claim 6 , wherein the dihydroxy compound comprises a dihydric phenol having the following structure:
wherein R 1 is independently at each occurrence a hydrogen atom, halogen atom, nitro group, cyano group, C 1 -C 20 alkyl radical, C 4 -C 20 cycloalkyl radical, or C 6 -C 20 aryl radical, and a is an integer from 0 to 4.
12. The method of claim 11 , wherein the dihydric phenol comprises hydroquinone, resorcinol, methylhydroquinone, butylhydroquinone, tertiary butyl hydroquinone, phenylhydroquinone, 4-phenylresorcinol, 4-methylresorcinol, or a combination comprising at least one of the foregoing.
13. The method of claim 11 , wherein the ester-substituted diaryl carbonate comprises bismethylsalicylcarbonate and the ester-substituted phenol comprises methyl salicylate, and wherein the dihydric phenol comprises hydroquinone, resorcinol, methylhydroquinone, butylhydroquinone, tertiary butyl hydroquinone, phenylhydroquinone, 4-phenylresorcinol, 4-methylresorcinol, or a combination comprising at least one of the foregoing.
14. The method of claim 6 , wherein the ester-substituted diaryl carbonate comprises bismethylsalicylcarbonate and the ester-substituted phenol comprises methyl salicylate.