Organic electroluminescent element
View Patent ↗Provided is an organic electroluminescent device (organic EL device) which has improved luminous efficiency and a simple configuration, while ensuring sufficient driving stability. This organic electroluminescent device includes a light-emitting layer between an anode and a cathode that are laminated on a substrate. The light-emitting layer contains a phosphorescent light-emitting dopant, and a carbazole compound represented by the following formula (1) as a host material. In the formula (1), E represents oxygen or sulfur, and R 1 to R 6 each represent hydrogen, an alkyl group, a cycloalkyl group, or an aromatic group represented by the formula (2). In the formula (2), X represents CR 9 or nitrogen.
1. An organic electroluminescent device, comprising:
a substrate;
an anode;
an organic layer; and
a cathode,
the anode, the organic layer, and the cathode being laminated on the substrate,
wherein the organic layer comprises at least one layer selected from the group consisting of a light-emitting layer, a hole-transporting layer, an electron-transporting layer, a hole-blocking layer, and an electron-blocking layer, the at least one layer containing a carbazole compound represented by the general formula (1):
in the general formula (1), R 1 to R 6 each independently represent hydrogen, an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 11 carbon atoms, or an aromatic group represented by the general formula (2), and at least one of R 1 to R 6 represents an aromatic group represented by the general formula (2), X's each independently represent CR 9 or nitrogen, R 7 to R 9 each independently represent hydrogen, an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 11 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or an aromatic heterocyclic group having 3 to 17 carbon atoms, and the aromatic hydrocarbon group and the aromatic heterocyclic group may each have a substituent, and E represents oxygen or sulfur.
2. An organic electroluminescent device according to claim 1 , wherein R 2 in the general formula (1) represents an aromatic group represented by the general formula (2).
3. An organic electroluminescent device according to claim 1 , wherein the carbazole compound comprises a carbazole compound represented by the general formula (3):
in the general formula (3), X, R 7 , R 8 , and E are identical in meaning to X, R 7 , R 8 , and E in the general formulae (1) and (2).
4. An organic electroluminescent device according to claim 3 , wherein the carbazole compound comprises a carbazole compound represented by the general formula (4):
in the general formula (4), R 7 , R 8 , and E are identical in meaning to R 7 , R 8 , and E in the general formula (3), and R 9 is identical in meaning to R 7 and a plurality of R 9 's may be identical to or different from one another.
5. An organic electroluminescent device according to claim 4 , wherein R 7 to R 9 in the general formula (4) each independently represent hydrogen, an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 11 carbon atoms, an unsubstituted aromatic hydrocarbon group having 6 to 18 carbon atoms, an unsubstituted aromatic heterocyclic group having 3 to 17 carbon atoms, or a substituted aromatic hydrocarbon group or a substituted aromatic heterocyclic group obtained by providing the unsubstituted aromatic hydrocarbon group or the unsubstituted aromatic heterocyclic group with a substituent, and the substituent comprises one kind selected from an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an acyl group having 2 to 7 carbon atoms, an aromatic hydrocarbon group having 6 to 12 carbon atoms, and a diarylamino group having 12 to 24 carbon atoms.
6. An organic electroluminescent device according to claim 1 , wherein the layer containing the carbazole compound comprises a light-emitting layer containing a phosphorescent light-emitting dopant.
7. An organic electroluminescent device according to claim 3 , wherein the layer containing the carbazole compound comprises a light-emitting layer containing a phosphorescent light-emitting dopant.