Staged combustion of sulfureous combustible effluents with recovery of the sulfur in the claus process
A process for advantageously efficiently treating a sulfureous combustible effluent stream by recovering the sulfur in elemental form comprises a step of combustion of the sulfureous combustible effluent stream with an oxidant gas in excess, and then a step of post-combustion of the effluents from the combustion step with an acidic gas. The stream of the post-combustion effluents, free of chemical compounds that are harmful to the efficacy of the Claus catalysts, is treated in a Claus unit, which performs the recovery of the sulfur in elemental form.
1. A process for treating a sulfureous combustible effluent stream, comprising the successive steps consisting in:
introducing into a combustion chamber the said stream and an oxidant gas in excess, performing the total combustion of the said stream with an excess of the oxidant gas, and withdrawing the gaseous effluent from the combustion chamber;
reacting, in a post-combustion chamber, a mixture consisting of the said gaseous effluent and an acidic gas, the said acidic gas being in an amount sufficient for all of the oxidant compounds to be consumed by reaction with the hydrogen sulfide of the acidic gas, the oxidant compounds being O 2 , SO 3 and NO x , and withdrawing the treated stream, the residence time of all of the gaseous streams in the said post-combustion chamber being at least greater than 0.5 second.
2. The process according to claim 1 , characterized in that the sulfureous combustible effluent stream treated in the process according to the invention is a stream of sulfur polluted with combustible impurities.
3. The process according to claim 1 , characterized in that the sulfureous combustible effluent stream treated in the process according to the invention is a DSO.
4. The process according to claim 1 , characterized in that the temperature of the combustion reaction is between 1300° C. and 1500° C.
5. The process according to claim 1 , the said process also comprising a step consisting in cooling the treated stream withdrawn from the post-combustion chamber.
6. The process according to claim 1 , the said process also comprising a step consisting in removing the sulfur in elemental form from the treated stream withdrawn from the post-combustion chamber.
7. The process according to claim 1 , the said process also comprising a step consisting in introducing the treated stream withdrawn from the post-combustion chamber, optionally cooled and/or optionally partially desulfurized, into the reaction oven of a Claus unit, in addition to a charge of acidic gas and of oxidant gas feeding the burner of the Claus reaction oven.
8. The process according to claim 1 , the said process also comprising a step consisting in introducing the treated stream withdrawn from the post-combustion chamber, optionally cooled and/or optionally partially desulfurized, into one or a series of several Claus catalytic reactors.
9. The process according to claim 1 , the said process also comprising an additional step consisting in recycling into the combustion chamber at least part of a process stream substantially not containing any oxygen, the temperature of which is less than 300° C.
10. The process according to claim 9 , characterized in that the stream at least partly recycled into the combustion chamber is the partially desulfurized, cooled treated stream, obtained after a cooling step and a step of condensation of the sulfur formed in the post-combustion stage.