Method for increasing the advantages of strength aids in the production of paper and paperboard
The invention relates to a method for manufacturing paper, paperboard or cardboard comprising the steps of (a) pulping an aqueous cellulosic material containing a starch; (b) preventing at least a portion of the starch from being microbially degraded by treating the aqueous cellulosic material containing the starch with one or more biocides; and (h) adding a dry and/or wet strength polymer to the cellulosic material.
1. A method for manufacturing paper, paperboard or cardboard comprising the steps of
(a) pulping an aqueous cellulosic material containing a starch;
(b) preventing at least a portion of the starch from being microbially degraded by treating the aqueous cellulosic material containing the starch with one or more biocides, which are at least partially added to the cellulosic material in the thick stock area, where the cellulosic material has a stock consistency of at least 2.0%; and
(h) adding a dry and/or wet strength polymer to the cellulosic material; and
wherein the one or more biocides are continuously or discontinuously added to the cellulosic material in quantities so that after 1 month of treatment on a continuously operating papermaking plant,
the electrical conductivity of the aqueous cellulosic material has been decreased by at least 5%, compared to the electrical conductivity that was measured at the same location of the papermaking machine immediately before biocide was added for the first time; and/or
pH value of the aqueous phase of the cellulosic material has been increased by at least 0.2 pH units, compared to the pH value that was measured at the same location of the papermaking machine immediately before biocide was added for the first time.
2. The method of claim 1 , wherein the one or more biocides are dosed in an amount of at least 5.0 g/ metric ton, based on the total amount of the composition containing the cellulosic material and the starch.
3. The method of claim 1 , wherein the one or more biocides are oxidative and/or comprise two components.
4. The method of claim 1 , wherein the one or more biocides comprise an inorganic ammonium salt in combination with a halogen source.
5. The method of claim 1 wherein a further biocide is added to the cellulosic material which differs from the one or more biocides added in step (b).
6. The method of claim 5 , wherein the further biocide is added in at least one of section (I) or (II); and is optionally added in section (III) and/or (IV) of a papermaking plant comprising a papermaking machine, wherein section (I) includes measures taking place before pulping; section (II) includes measures associated with pulping; section (III) includes measures taking place after pulping but still outside the papermaking machine; and section (IV) includes measures taking place inside the papermaking machine.
7. The method of claim 5 , wherein the further biocide is non-oxidizing.
8. The method of claim 5 , wherein the further biocide is an organic biocide selected from the group consisting of quaternary ammonium compounds, benzyl-C 12-16 -alkyldimethyl chlorides (ADBAC), polyhexamethylenebiguanide (biguanide), 1,2-benzisothiazol-3(2H)-one (BIT), bronopol (BNPD), bis(trichloro-methyl)sulfone, diiodomethyl-p-tolylsulfone, bronopol/quaternary ammonium compounds, benzyl-C 12-16 -alkyldimethyl chlorides (BNPD/ADBAC), bronopol/didecyl-dimethylammonium chloride (BNPD/DDAC), bronopol/5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (BNPD/Iso), NABAM/sodium dimethyldithio-carbamate, sodiumdimethyldithiocarbamate-N,N-dithiocarbamate (NABAM), sodium-methyldithiocarbamate, sodium dimethyldithiocarbamate, 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT), 2,2-dibromo-2-cyanoacetamide (DBNPA), DBNPA/bronopol/iso (DBNPA/BNPD/Iso), 4,5-dichloro-2-n-octyl-3-isothiazolin-3-one (DCOIT), didecyl-dimethylammonium chloride (DDAC), didecyldimethylammoniumchloride, alkyl-dimethylbenzylammoniumchloride (DDAC/ADBAC), dodecylguanidine monohydro-chloride/quaternary ammonium compounds, benzyl-C 12-16 -alkyldimethyl chlorides (DGH/ADBAC), dodecylguanidine monohydrochloride/methylene dithiocyanate (DGH/MBT), gluteraldehyde (Glut), gluteraldehyde/quaternary ammonium compounds/benzylcoco alkyldimethyl chlorides (Glut/coco), gluteraldehyde/didecyldimethyl-ammonium chloride (Glut/DDAC), gluteraldehyde/5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (Glut/Iso), gluteraldehyde/methylene dithiocyanate (Glut/MBT), 5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (Iso), methylene dithiocyanate (MBT), 2-methyl-4-isothiazolin-3-one (MIT), methamine oxirane(methamine oxirane), sodium bromide (NaBr), nitromethylidynetrimethanol, 2-n-octyl-3-isothiazolin-3-one (OIT), bis(trichloromethyl) sulphone/quaternary ammonium compounds, benzyl-C 12-16 -alkyldimethyl chlorides (sulphone/ADBAC), symclosene, terbuthylazine, dazomet (thione), tetrakis(hydroxymethyl)phosphonium sulphate(2:1) (THPS) and p-[(diiodomethyl)sulphonyl]toluene (tolyl sulphone), and mixtures thereof.
9. The method of claim 8 , wherein the further biocide is an organic biocide selected from the group consisting of quaternary ammonium compounds, 1,2-benzisothiazol-3(2H)-one (BIT), bronopol/5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (BNPD/Iso), 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT), DBNPA/bronopol/iso (DBNPA/BNPD/Iso), 4,5-dichloro-2-n-octyl-3-isothiazolin-3-one (DCOIT), gluteraldehyde/5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (Glut/Iso), 5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (Iso), 2-methyl-4-isothiazolin-3-one (MIT), 2-n-octyl-3-isothiazolin-3-one (OIT), and mixtures thereof.
10. The method of claim 8 , wherein the further biocide is an organic biocide selected from the group consisting gluteraldehyde (Glut), gluteraldehyde/quaternary ammonium compounds/benzylcoco alkyldimethyl chlorides (Glut/coco),gluteraldehyde/ didecyldimethyl-ammonium chloride (Glut/DDAC), gluteraldehyde/5-chloro-2-methyl-2H-isothiazol-3-one/2-methyl-2H-isothiazol-3-one (Glut/Iso), gluteraldehyde/methylene dithiocyanate (Glut/MBT), and mixtures thereof.
11. The method of claim 1 , wherein the dry and/or wet strength polymer comprises non-ionic, anionic, cationic or amphoteric cellulose reactive polymers capable of forming covalent inter-polymer cross-linkages with cellulose through aldehyde functional groups and/or 3-hydroxy-azetidinium functional groups of the dry and/or wet strength polymer.
12. The method according to claim 11 , wherein the non-ionic, anionic, cationic or amphoteric cellulose reactive polymers are reaction products of ionic or nonionic homo- or copolymers comprising monomer units derived from vinylamides, which are optionally fully or partially hydrolyzed, and/or from (meth)acrylamides with epichlorohydrin or with cellulose reactive agents comprising at least one aldehyde functional group; or of polysaccharides with epichlorohydrin or with cellulose reactive agents comprising at least one aldehyde functional group.
13. The method of claim 12 , wherein the cellulose reactive agents comprise at least two aldehyde functional groups selected from the group consisting of glyoxal, glutaraldehyde, succinaldehyde, furan dialdehyde, 2-hyroxyadipaldehyde, dialdehyde starch, and combinations thereof.
14. The method of claim 1 , wherein the dry and/or wet strength polymer comprises a natural or synthetic non-ionic, anionic, cationic or amphoteric polymer.
15. The method of claim 14 , wherein the natural or synthetic non-ionic, anionic, cationic or amphoteric polymers are selected from the group consisting of a) native or chemically modified polysaccharides; b) anionic homo- or copolymers comprising anionic monomer units derived from (meth)acrylic acid; optionally in combination with non-ionic monomer units derived from (meth)acrylamide; c) cationic homo- or copolymers comprising cationic monomer units derived from vinylamine, polydiallyldimethylammonium chloride, 2-acryloylethyltrimethylammonium chloride, and/or ethyleneimine; optionally in combination with non-ionic monomer units derived from vinylamide and/or (meth)acrylamide; d) amphoteric polymers; e) substantially nonionic water-soluble polymers; and f) water-insoluble latexes.
16. The method of claim 14 , wherein the natural or synthetic non-ionic, anionic, cationic or amphoteric polymers comprise anionic homo- or copolymers comprising anionic monomer units derived from (meth)acrylic acid.
17. The method of claim 14 , wherein the natural or synthetic non-ionic, anionic, cationic or amphoteric polymers comprise cationic homo- or copolymers comprising cationic monomer units derived from at least one monomer selected from vinylamine, polydiallyldimethylammonium chloride, 2-acryloylethyltrimethylammonium chloride, and ethyleneimine.
18. The method of claim 1 , which is performed on a continuously operating papermaking plant, further comprising the steps:
(A) measuring a property of the aqueous cellulosic material selected from the group consisting of electrical conductivity, redox potential, pH value, concentration of ATP, and concentration of free starch; at said location of the papermaking machine;
(B) manufacturing paper, paperboard or cardboard by the method of claim 1 comprising steps (a), (b), and (h);
(C) measuring the same property as measured in step (A) at the same location as step (A), after time, delta T, wherein delta T is at least 1 and comparing the value measured in step (C) with the value measured in step (A); and
(D) regulating the dosage of biocide added in step (b) and/or the dosage of dry and/or wet strength polymer added in step (h) in dependence of the result of the comparison made in step (C).