Organic electroluminescence element, illumination device and display device
View Patent ↗Provided are an organic electroluminescence element, an illumination device, and a display device having lower driving voltage and excellent luminous efficiency. An organic electroluminescence element has a supporting substrate; and a cathode, a light emitting layer and an adjacent layer provided on the supporting substrate, wherein the adjacent layer is arranged adjacent to the outer side of the cathode (i.e., the side opposite to the light emitting layer), wherein the cathode is a transparent layer containing a metal and having a film thickness of 2 nm or more but less than 10 nm; and wherein the adjacent layer has a refractive index of between 1.6 and 1.95, a film thickness of between 15 nm and 180 nm, and contains no light scattering particle.
1. An organic electroluminescence element comprising:
a supporting substrate; and
a cathode, a light emitting layer and an adjacent layer provided on the supporting substrate, wherein the adjacent layer is arranged adjacent to the outer side of the cathode (i.e., the side opposite to the light emitting layer),
wherein the cathode is a transparent layer containing a metal and having a film thickness of 2 nm or more but less than 10 nm; and
wherein the adjacent layer has a refractive index of between 1.6 and 1.95, a film thickness of between 15 nm and 180 nm, and contains no light scattering particle.
2. The organic electroluminescence element according to claim 1 , wherein the adjacent layer contains a metal complex compound having a quinoline derivative as its ligand.
3. The organic electroluminescence element according to claim 1 , wherein the adjacent layer contains a compound represented by the following general formula (1):
(Ar1) n 1-Y1 General Formula (1)
where n1 represents an integer of 1 or more; Y1 represents either a substituent if n1 is one, or a bond or an n1-valent linking group if n1 is 2 or more; Ar1 represents a group represented by the following general formula (A); and, if n1 is or more, a plurality of Ar1 may be either identical to or different from each other; wherein the compound represented by General Formula (1) has at least two condensed aromatic heterocycles in the molecule, each formed by condensing three or more rings,
where X represents —N(R)—, —O—, —S— or —Si(R)(R′)—, and E1 to E8 each represent —C(R1)= or —N═, wherein R, R′ and R1 each represent a hydrogen atom, a substituent or a linking site with Y1; * represents a linking site with Y1; Y2 represents a bond or a divalent linking group; Y3 and Y4 each represent a group derived from a 5-membered or 6-membered aromatic ring, wherein at least one of Y3 and Y4 represents a group derived from an aromatic heterocycle containing a nitrogen atom as a ring constituent atom; and n2 represents an integer of 1 to 4.
4. The organic electroluminescence element according to claim 3 , wherein the compound represented by the general formula (1) is a compound represented by the following general formula (2):
where Y5 represents a divalent linking group which is an arylene group, a heteroarylene group or a combination of the arylene group and the heteroarylene group; E51 to E66 each represent —C(R3)= or —N═, wherein R3 represents a hydrogen atom or a substituent; Y6 to Y9 each represent a group derived from an aromatic hydrocarbon ring or a group derived from an aromatic heterocycle, wherein at least one of Y6 and Y7 and at least one of Y8 and Y9 each represent a group derived from an aromatic heterocycle containing an N atom; and n3 and n4 each represent an integer of 0 to 4, wherein the sum of n3 and n4 is 2 or more.
5. The organic electroluminescence element according to claim 4 , wherein the compound represented by the general formula (2) is a compound represented by the following general formula (3):
where Y5 represents a divalent linking group which is an arylene group, a heteroarylene group or a combination of the arylene group and the heteroarylene group; E51 to E66 and E71 to E88 each represent —C(R3)= or —N═, wherein R3 represents a hydrogen atom or a substituent, and wherein at least one of E71 to E79 and at least one of E80 to E88 each represent —N═; and n3 and n4 each represent an integer of 0 to 4, wherein the sum of n3 and n4 is 2 or more.
6. The organic electroluminescence element according to claim 1 , wherein the main component of the cathode is silver.
7. The organic electroluminescence element according to claim 1 , further comprising:
an electron transporting layer arranged between the cathode and the light emitting layer,
wherein the electron transporting layer contains an alkali metal or an alkali metal compound.
8. The organic electroluminescence element according to claim 7 , wherein the alkali metal or the alkali metal compound is kalium or a kalium compound.
9. The organic electroluminescence element according to claim 7 , wherein the electron transporting layer contains a compound represented by one of general formulas (1) to (3).
10. The organic electroluminescence element according to claim 1 , wherein the light emitting layer contains a compound represented by the following general formula (4):
where P and Q each represent a carbon atom or a nitrogen atom; A1 represents an atom group which forms an aromatic hydrocarbon ring or an aromatic heterocycle with P—C; A2 represents an atom group which forms an aromatic heterocycle with Q-N; P1-L1-P2 represents a bidentate ligand, wherein P1 and P2 each independently represent a carbon atom, a nitrogen atom or an oxygen atom, and L1 represents an atom group which forms the bidentate ligand with P1 and P2; j1 represents an integer of 1 to 3, and j2 represents an integer of 0 to 2, wherein the sum of j1 and j2 is 2 or 3; and M1 represents a transition metal element of groups 8 to 10 in the periodic table of elements.
11. The organic electroluminescence element according to claim 10 , wherein the compound represented by the general formula (4) is a compound represented by the following general formula (5):
where Z represents a hydrocarbon ring group or a heterocyclic group; P and Q each represent a carbon atom or a nitrogen atom; A1 represents an atom group which forms an aromatic hydrocarbon ring or an aromatic heterocycle with P—C; A3 represents —C(R01)=C(R02)-, —N═C(R02)-, —C(R01)=N— or ═N—N—, wherein R01 and R02 each represent a hydrogen atom or a substituent; P1-L1-P2 represents a bidentate ligand, wherein P1 and P2 each independently represent a carbon atom, a nitrogen atom or an oxygen atom, and L1 represents an atom group which forms the bidentate ligand with P1 and P2; j1 represents an integer of 1 to 3, and j2 represents an integer of 0 to 2, wherein the sum of j1 and j2 is 2 or 3; and M1 represents a transition metal element of groups 8 to 10 in the periodic table of elements.
12. The organic electroluminescence element according to claim 10 , wherein M1 represents iridium.
13. The organic electroluminescence element according to claim 1 , further comprising:
an auxiliary electrode arranged between the cathode and the adjacent layer.
14. The organic electroluminescence element according to claim 1 , wherein the organic electroluminescence element is a dual emission type organic electroluminescence element.
15. An illumination device comprising an organic electroluminescence element described in claim 1 .
16. A display device comprising an organic electroluminescence element described in claim 1 .