Granted Patent B2

US 10,047,477 · App. 14/243,046 · Granted Aug 14, 2018

Abstract

Claims (42)

1. A textile coating composition comprising an aqueous emulsion of a midblock sulfonated styrenic block copolymer and a poly(vinyl alcohol);

wherein the midblock sulfonated styrenic block copolymer comprises at least two non-sulfonated styrenic polymer end blocks A, at least one interior styrenic polymer block B carrying sulfonyl groups and/or derivates thereof, and one or more interior polymer blocks D that have a glass transition temperature of less than 20° C.;

wherein the coating composition has a solids content, defined by the amount of midblock sulfonated styrenic block copolymer and poly(vinyl alcohol) in the coating composition by weight, in the range of 5 to 70 wt. %; and

wherein a ratio of the poly(vinyl alcohol) versus the midblock sulfonated styrenic block copolymer by weight is in the range of 1:1 to 1:200.

2. The coating composition of claim 1 , wherein the midblock sulfonated styrenic block copolymer is a mixture of midblock sulfonated styrenic block copolymers.

3. The coating composition of claim 1 , comprising a midblock sulfonated styrenic block copolymer of the general configuration A-D-B-D-A, A-B-D-B-A, (A-DB) n X, (A-B-D) n X or a mixture thereof, where n is an integer from 2 to about 30, X is coupling agent residue.

4. The coating composition of claim 1 , comprising a midblock sulfonated styrenic block copolymer of the general configuration (A-D-B) n X, where n is 2 or n is an integer from 3 to 6, and X, A, B and D have the defined meaning.

5. The coating composition of claim 4 , comprising a midblock sulfonated styrenic block copolymer wherein:

a) each A block independently is a polymer block having an apparent number average molar mass between 1,000 and 60,000 g/mol; and/or

b) each D block, if present, independently is a polymer block having an apparent number average molar mass between 1,000 and 60,000 g/mol, and/or

c) each B block independently is a polymer block having an apparent number average molar mass between 10,000 and 300,000 g/mol,

wherein the term “molar mass” refers to polystyrene equivalent or apparent molar mass of the polymer or block of the copolymer, measured with gel permeation chromatography (GPC) using polystyrene calibration standards, according to ASTMD5296-11, and wherein the molar mass expressed herein is measured at the peak of the GPC trace.

6. The coating composition of claim 5 , comprising a midblock sulfonated styrenic block copolymer wherein:

a) each A block independently is a polymer block having an apparent number average molar mass between 5,000 and 40,000 g/mol; and/or

b) each D block, if present, independently is a polymer block having an apparent number average molar mass between 2,000 and 40,000 g/mol, and/or

c) each B block independently is a polymer block having an apparent number average molar mass between 15,000 and 200,000 g/mol.

7. The coating composition of claim 6 , comprising a midblock sulfonated styrenic block copolymer wherein:

a) each A block independently is a polymer block having an apparent number average molar mass between 7,000 and 20,000 g/mol; and/or

b) each D block, if present, independently is a polymer block having an apparent number average molar mass between 5,000 and 20,000 g/mol, and/or

c) each B block independently is a polymer block having an apparent number average molar mass between 19,000 and 100,000 g/mol.

8. The coating composition of claim 3 , comprising a midblock sulfonated styrenic block copolymer having a B block content in the range of 10 to 85% m calculated on the mass of the sulfonated block copolymer.

9. The coating composition of claim 8 , comprising a midblock sulfonated styrenic block copolymer having a B block content in the range of 20 to 60% m calculated on the mass of the sulfonated block copolymer.

10. The coating composition of claim 1 , comprising a midblock sulfonated styrenic block copolymer having an Ion Exchange capacity in the range of 0.2 to 4.0 mmol per gram midblock sulfonated styrenic block copolymer.

11. The coating composition of claim 1 , wherein the solids content is in the range of 10 to 50 wt. %.

12. The coating composition of claim 1 , wherein the poly(vinyl alcohol) is a mixture of poly(vinyl alcohol)s.

13. The coating composition of claim 1 , wherein the poly(vinyl alcohol) used in the coating composition is a hydrolyzed or partially hydrolyzed poly(vinyl alcohol).

14. The coating composition of claim 13 , wherein the poly(vinyl alcohol) used is hydrolyzed to a degree of 99+%.

15. The coating composition of claim 1 , wherein the poly(vinyl alcohol) has a weight average molecular weight in the range of 9,000 to 205,000 g/mol.

16. The coating composition of claim 15 , wherein the poly(vinyl alcohol) is a hydrolyzed poly(vinyl alcohol) with a weight average molecular weight in the range of 89,000 to 98,000 g/mol and hydrolyzed to >99%.

17. The coating composition of claim 1 , wherein the ratio of the poly(vinyl alcohol) versus the midblock sulfonated styrenic block copolymer by weight is in the range of 1:1.5 to 1:150.

18. A method for preparing the textile coating composition of claim 1 , which comprises: forming an aqueous emulsion of a midblock sulfonated styrenic block copolymer in water, bringing the aqueous emulsion to a temperature in the range of 50 to 100° C., and dissolving the poly(vinyl alcohol) into the emulsion.

19. A method for preparing a fabric with enhanced evaporative cooling effect, which comprises: applying the textile coating composition of claim 1 onto a fabric, and applying heat and optionally pressure.

20. The method of claim 19 , which comprises drying the coating composition at a temperature in the range of 50-80° C., for less than a minute in an oven.

21. The method of claim 20 , which comprises applying heat to a temperature in the range of 40-180° C. and pressure in the range of 5 to 1100 kPa.

22. A fabric having enhanced evaporative cooling properties having the coating of any one of claims 1 - 17 applied thereon.

23. An airtight fabric having one or more layers of coating according to any one of claims 1 - 17 applied as film thereon.

24. A textile coating composition comprising an aqueous emulsion of a midblock sulfonated styrenic block copolymer and a poly(vinyl alcohol);

wherein the midblock sulfonated styrenic block copolymer comprises at least two non-sulfonated styrenic polymer end blocks A and at least one interior styrenic polymer block B carrying sulfonyl groups and/or derivates thereof;

wherein the poly(vinyl alcohol) used in the coating composition is a hydrolyzed or partially hydrolyzed poly(vinyl alcohol) having a weight average molecular weight in the range of 9,000 to 205,000 g/mol;

wherein the coating composition has a solids content, defined by the amount of midblock sulfonated styrenic block copolymer and poly(vinyl alcohol) in the coating composition by weight, in the range of 5 to 70 wt. %;

wherein the coating composition comprises greater than or equal to 0.8 wt % of the poly(vinyl alcohol) based on the total weight of the coating composition; and

wherein a ratio of the poly(vinyl alcohol) versus the midblock sulfonated styrenic block copolymer by weight is in the range of 1:1 to 1:200.

Assignments (10)