Adhesive compositions containing a block copolymer with polymyrcene
View Patent ↗The invention relates to a novel block copolymer comprising at least one polymeric monoalkenyl arene block and at least one polymeric myrcene block having a low and stable viscosity and having good adhesive properties when used in an adhesive composition or as a damping material. An adhesive composition is also described, preferably containing an SMS triblock optionally mixed with an SM diblock. The adhesive composition comprises: 1) a block copolymer having at least one polymeric monoalkenyl arene block and at least one polymeric myrcene block; 2) a tackifier; 3) optional plasticizer; and 4) optionally a stabilizer. Compared with adhesive compositions comprising SIS block copolymers, those comprising SMS block copolymers have lower and more stable viscosity.
1. A block copolymer composition comprising at least one polymeric block of monoalkenyl arene and at least one polymeric block of myrcene, said composition having 50 wt. % or less monoalkenyl arene and a melt flow rate of greater than about 50 grams/10 min. at 200° C. and 5 kg weight according to ASTM D1238, said at least one block of monoalkenyl arene having a molecular weight of 10-20 kg/mol., and said at least one block of myrcene having a molecular weight of 40-220 kg/mol., said block copolymer composition has the general structure (S-M-S′) n X or (S-M) n X where S and S′ are polymeric blocks of monoalkenyl arene, M is a polymeric block of myrcene, and n is an integer from 1 to about 5, and X is the residue of a coupling agent, said at least one polymeric block of monoalkenyl arene contains at least 95 wt. % styrene with up to 5 wt. % of alpha-methylstyrene, methylstyrene, p-tertbutylstyrene, dimethylstyrene, or mixtures of these, based on the total weight of the monoalkenyl arene in said block copolymer, wherein said block copolymer composition has a viscosity retention greater than 80% for 24 hours, at 160° C. and a vinyl content ranging from about 5 mol. % to 50 mol. %.
2. An adhesive composition comprising 100 parts by weight of a block copolymer of two end blocks of monoalkenyl arene and a mid-block of myrcene having a vinyl content ranging from about 5 mol. % to 50 mol. %; from about 30 to 250 parts by weight of a tackifier, based on 100 parts of said block copolymer; from about 0.1 to 80 parts by weight of a plasticizer, based on 100 parts of said block copolymer; and from about 0.1 to 3 parts by weight of a stabilizer, based on 100 parts of said block copolymer, the molecular weight of each monoalkenyl arene block is from about 10 to 20 kg/mol., the molecular weight of said polymyrcene block is from 40 to 220 kg/mol., said tackifier is selected from the group of C 5 hydrocarbon resins, hydrogenated C 5 hydrocarbon resins, styrenated C 5 resins, C 9 hydrocarbon resins, hydrogenated C 9 hydrocarbon resins, styrenated C 9 resins, C 5 /C 9 hydrocarbon resins, a modified C 5 , C 9 , or C 5 /C 9 resin, terpenes, rosin ester, rosin derivatives or a mixture of two or more of these, said plasticizer is selected from the group of mineral or naphthenic oil, said block copolymer contains at least 50 wt. % of said myrcene, and said monoalkenyl arene is at least 10 wt. %, based on the total weight of said block copolymer.
3. A process for producing a coupled block copolymer of monoalkenyl arene and myrcene, comprising introducing into a reactor styrene and an organolithium initiator; polymerizing said monoalkenyl arene to form a polymeric block of monoalkenyl arene; introducing myrcene into said reactor; continuing polymerization of said myrcene to form a polymeric diblock of styrene and myrcene or introducing additional styrene to the polymeric diblock of styrene and myrcene to form a triblock of styrene and myrcene; introducing a coupling agent into said reactor and coupling said diblock or triblock copolymer of styrene and myrcene, forming (S-M-S) n X or (S-M) n X where S is polymeric blocks of styrene, M is a polymeric block of myrcene, and n is an integer from 1 to about 5, and X is the residue of a coupling agent, wherein said polystyrene content is 50 wt. % or less, and the molecular weight of a styrene block is 10-20 kg/mol. and the molecular weight of said myrcene block is 40-220 kg/mol., further comprising the step of introducing an amount of butadiene sufficient to introduce at least one molecule of butadiene per myrcene block between the steps of polymerizing said myrcene and introducing a coupling agent, and wherein the block copolymer has a vinyl content of about 5 mol. % to about 50 mol. %.
4. The process of claim 3 , wherein the amount of butadiene is up to 3 wt. %, based on the total weight of the coupled block copolymer.