Polyoxymethylene compositions
View Patent ↗Compositions comprising polyoxymethylene polymers and at least one organopolysiloxane polymer. Adding organopolysiloxane polymers to polyoxymethylene polymers provides compositions that exhibit at least a 50 percent reduction in melt viscosity compared to the melt viscosity of an identical, melted composition lacking the organopolysiloxane polymer, and promote easier molding of the compositions into complex article shapes.
1. A composition comprising:
(a) at least one polyoxymethylene polymer; and
(b) at least one organopolysiloxane polymer selected from the group consisting of:
(i) one or more polysiloxane homopolymers having as silicon atom substituents at least one C 2 to C 20 alkyl group, or at least one aryl group, or any combination of these;
(ii) one or more polysiloxane copolymers having as silicon atom substituents at least one C 1 to C 20 alkyl group, or at least one aryl group, or any combination of these;
(iii) one or more polyhydroxylsiloxane polymers; and
(iv) mixtures of any two or more of these;
wherein, when the composition is melted, the composition exhibits at least 50 percent reduction in melt viscosity compared to the melt viscosity of an identical, melted composition lacking component (b), with melt viscosity measured according to ASTM D-3835-08 at 220° C. and 500 sec −1 shear rate.
2. The composition of claim 1 , comprising 0.5 to 5 weight percent of the organopolysiloxane polymer.
3. The composition of claim 1 , comprising 1.5 to 2.5 weight percent of the organopolysiloxane polymer.
4. The composition of claim 1 , comprising 60 to 99.5 wt. % of the polyoxymethylene polymer.
5. The composition of claim 1 , wherein, when the composition comprises component (b)(i), number average molecular weight (Mn) of component (b)(i) ranges from about 1500 to about 25,000.
6. The composition of claim 1 , wherein, when the composition comprises component (b)(i), carbon atom to silicon atom ratio (C/Si) of component (b)(i) ranges from about 4 to 20.
7. The composition of claim 1 , wherein when the composition comprises component (b)(i), the reduction in melt viscosity ranges from at least 50% to about 60%, when compared to the melt viscosity of an identical, melted composition lacking component (b).
8. The composition of claim 1 , wherein, when the composition comprises component (b)(ii), number average molecular weight (Mn) of component (b)(ii) ranges from about 1200 to about 38,000.
9. The composition of claim 1 , wherein, when the composition comprises component (b)(ii), the carbon atom to silicon atom ratio (C/Si) of component (b)(ii) ranges from about 2 to 20.
10. The thermoplastic composition of claim 1 , wherein, when the composition comprises component (b)(ii), the reduction in melt viscosity ranges from at least 50% to about 65%, when compared to the melt viscosity of an identical, melted composition lacking component (b).
11. The thermoplastic composition of claim 1 , wherein, when the composition comprises component (b)(iii), number average molecular weight (Mn) of component (b)(iii) ranges from about 800 to about 38,000.
12. The thermoplastic composition of claim 1 , wherein, when the composition comprises component (b)(iii), carbon atom to silicon atom ratio (C to Si) of component (b)(iii) ranges from about 2 to 6.
13. The composition of claim 1 , wherein, when the composition comprises component (b)(iii), the reduction in melt viscosity ranges from at least 50% to about 65%, when compared to the melt viscosity of an identical, melted composition lacking component (b).
14. An article comprising a composition comprising:
(a) at least one polyoxymethylene polymer; and
(b) at least one organopolysiloxane polymer selected from the group consisting of:
(i) one or more polysiloxane homopolymers having as silicon atom substituents at least one C 2 to C 20 alkyl group, or at least one aryl group, or any combination of these;
(ii) one or more polysiloxane copolymers having as silicon atom substituents at least one C 1 to C 20 alkyl group, or at least one aryl group, or any combination of these;
(iii) one or more polyhydroxylsiloxane polymers; and
(iv) mixtures of any two or more of these;
wherein, the composition is melted, reduction in melt viscosity of the composition is at least 50 percent compared to the melt viscosity of an identical, melted composition lacking component (b), with melt viscosity measured according to ASTM D-3835-08 at 220° C. and 500 sec −1 shear rate.