Method for preparing lactames, comprising a photonitrosation step, followed by a Beckmann transposition step
View Patent ↗The invention relates to a method for preparing lactames, according to which a photonitrosation of a cycloalkane is carried out using nitrosyl chloride (NOCI). According to the invention, said photonitrosation is carried out by means of LEDs emitting a monochromatic light. The method according to the invention can also include a step comprising Beckmann transposition/dechlorination of the oxime hydrochloride generated during said phonitrosation, preferably carried out in a glass microreactor.
1. In a process for preparing lauryllactam or caprolactam from oximes, comprising photonitrosating of a cycloalkane using nitrosyl chloride (NOCI), the improvement wherein said photonitrosating is carried out by exposing the cycloalkane to LEDs emitting a monochromatic light.
2. The process as claimed in claim 1 , in which the cycloalkane is cyclododecane.
3. The process as claimed in claim 1 , wherein the monochromatic light emitted by the LEDs has an average wavelength value included in a range from 550 to 650 nm.
4. The process as claimed in claim 3 , wherein the monochromatic light emitted by the LEDs has an average wavelength value of from 585 to 595 nm.
5. The process as claimed in claim 1 , wherein a microreactor is used to carry out the photonitrosation of the cycloalkane.
6. The process as claimed in claim 5 , wherein the body of the microreactor is made of glass.
7. The process as claimed in claim 1 , wherein the lactam is prepared from the oxime by Beckmann rearrangement/dechlorination of the oxime hydrochloride generated during photonitrosation, and a microreactor is used to carry out a Beckmann rearrangement/dechlorination step.
8. The process as claimed in claim 7 , wherein the body of the microreactor comprises tantalum, a fluoropolymer, a glass steel or glass.
9. A process for preparing lauryllactam or caprolactam, comprising preparing an oxime by photonitrosation of a cycloalkane using nitrosyl chloride in the presence of LEDs emitting monochromatic light, and subjecting oxime hydrochloride generated during photonitrosation to Beckman rearrangement/dechlorination to produce lauryllactam or caprolactam.
10. The process as claimed in claim 9 , in which the cycloalkane is cyclododecane.
11. The process as claimed in claim 9 , wherein the body of the microreactor is made of glass.