IP Library Granted Patent US 9,681,833
Granted Patent B2
US 9,681,833 · App. 14/256,342 · Granted Jun 20, 2017

Coextruded plastic capillary tube

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Quick Facts
Patent No.
US 9,681,833
App. No.
14/256,342
Granted
Jun 20, 2017
Kind
B2
Abstract

Coextruded plastic capillary tube and method of manufacturing a coextruded tube for collecting a volume of liquid. The tube is disposable, inexpensive to manufacture and can reliably draw blood and other aqueous based fluids into the tube by capillary action, at a fluid uptake level comparable to glass and other commercially pre-treated plastic tubes, without requiring further interior coating.

Claims (56)

1. A capillary tube comprising:

a coextruded plastic multilayer capillary tube having a tubular sidewall defining a central channel and comprising at least two coextruded polymer layers coaxially disposed along an axial length of the tube between open proximal and distal ends of the tube, the tubular sidewall having an inner diameter sized to permit an aqueous or aqueous based fluid to flow into the central channel by capillary action through an open end of the tube,

the at least two coaxial coextruded polymer layers comprising:

an innermost layer defining the surface of the central channel comprising a polyether block polyamide (PEBA) polymer material; and

an outer layer of a material having a flexural modulus of at least about 250,000 pounds per square inch (psi).

2. The capillary tube of claim 1 wherein the material comprising the innermost layer has a flexural modulus of at least about 11,000 psi.

3. The capillary tube of claim 1 wherein:

the innermost layer material comprises a blend of PEBA and a base resin.

4. The capillary tube of claim 3 wherein:

the base resin is selected from the group consisting of polyesters, acrylic resins, styrenic resins, acetal resins, polyamides, polyolefins and polyolefin copolymers, and all combinations and blends thereof.

5. The capillary tube of claim 1 wherein

the central channel has a diameter in a range of from about 0.01 inches to about 0.10 inches;

the tubular sidewall has a thickness in a range of form about 0.003 inches to about 0.060 inches; and

the innermost layer has a thickness in a range of from about 0.001 inches to about 0.059 inches.

6. The capillary tube of claim 1 wherein:

the tubular sidewall has two layers, including the outer layer of semi-crystalline or amorphous polyester polymer material, and the innermost layer comprising PEBA or a blend of PEBA and a base resin.

7. The capillary tube of claim 6 wherein:

the central channel has a diameter in a range of from about 0.01 inches to about 0.10 inches;

the tubular sidewall has a thickness in a range of from about 0.003 inches to about 0.060 inches; and

the innermost layer has a thickness in a range of from about 0.001 inches to about 0.059 inches.

8. The capillary tube of claim 1 wherein:

the tubular sidewall has three layers, the outer layer being an outermost layer comprising semi-crystalline or amorphous polyester polymer material, an intermediate layer comprising semi-crystalline or amorphous polyester polymer material, and the innermost layer comprising PEBA or a blend of PEBA and a base resin.

9. The capillary tube of claim 8 wherein:

the outermost layer has a thickness in a range of from about 0.0005 inches to about 0.058 inches, the intermediate layer has a thickness in a range of from about 0.0005 inches to about 0.058 inches, the innermost layer has a thickness in a range of from about 0.001 inches to about 0.059 inches, and the central channel has a diameter in a range of from about 0.01 inches to about 0.100 inches.

10. The capillary tube of claim 1 wherein the sidewall outer layer is an outermost layer of semi-crystalline polyester polymer material.

11. The capillary tube of claim 1 wherein the capillary tube comprises a medical tube for collecting a sample of blood or other aqueous based fluid.

12. A medical device for collecting a sample of blood or other aqueous based fluid including the capillary tube of claim 1 .

13. A method of collecting a fluid sample comprising inserting an open end of the capillary tube of claim 1 into a fluid specimen and drawing fluid from the specimen into the channel via capillary action.

14. The capillary tube of claim 1 , wherein the capillary tube is sized for collecting a sample of at least 0.5 microliters.

15. The capillary tube of claim 1 , wherein the capillary tube is sized for collecting a sample from about 0.5 to about 2 microliters.

16. A method of making a coextruded plastic multilayer capillary tube comprising:

coextruding a tubular sidewall of a coextruded plastic multilayer capillary tube, the tubular sidewall comprising at least two coextruded polymer layers coaxially disposed along an axial length of the tube between open proximal and distal ends of the tube, the tubular sidewall defining a central channel for receiving a fluid,

the tubular sidewall having an inner diameter sized to permit an aqueous or aqueous based fluid to flow into the central channel by capillary action through an open end of the tube,

the at least two coaxial coextruded polymer layers comprising: an innermost layer defining the surface of the central channel comprising a polyether block polyamide (PEBA) polymer material, and an outermost layer of a material having a flexural modulus of at least about 250,000 pounds per square inch (psi).

17. A capillary tube comprising:

a coextruded plastic multilayer capillary tube having a tubular sidewall defining a central channel and comprising three coextruded polymer layers coaxially disposed along an axial length of the tube between open proximal and distal ends of the tube, the tubular sidewall having an inner diameter sized to permit an aqueous or aqueous based fluid to flow into the central channel by capillary action through an open end of the tube, the three coaxial coextruded polymer layers comprising:

an innermost layer defining the surface of the central channel comprising a polyether block polyamide (PEBA) or a blend of PEBA and a base resin polymer material;

an intermediate layer comprising semi-crystalline or amorphous polyester polymer material; and

an outermost layer comprising semi-crystalline or amorphous polyester polymer material having a flexural modulus of at least about 250,000 pounds per square inch (psi).

18. The capillary tube of claim 17 wherein:

the outermost layer has a thickness in a range of from about 0.0005 inches to about 0.058 inches, the intermediate layer has a thickness in a range of from about 0.0005 inches to about 0.058 inches, the innermost layer has a thickness in a range of from about 0.001 inches to about 0.059 inches, and the central channel has a diameter in a range of from about 0.01 inches to about 0.100 inches.

19. The capillary tube of claim 17 , wherein the material comprising the innermost layer has a flexural modulus of at least about 11,000 psi.

20. The capillary tube of claim 17 wherein:

the innermost layer material comprises the blend of PEBA and base resin polymer material.

21. The capillary tube of claim 17 wherein:

the base resin polymer material is selected from the group consisting of polyesters, acrylic resins, styrenic resins, acetal resins, polyamides, polyolefins and polyolefin copolymers, and all combinations and blends thereof.

22. The capillary tube of claim 17 wherein

the central channel has a diameter in a range of from about 0.01 inches to about 0.10 inches;

the tubular sidewall has a thickness in a range of form about 0.003 inches to about 0.060 inches; and

the innermost layer has a thickness in a range of from about 0.001 inches to about 0.059 inches.

23. The capillary tube of claim 17 wherein the outermost layer is semi-crystalline polyester polymer material.

24. The capillary tube of claim 17 wherein the capillary tube comprises a medical tube for collecting a sample of blood or other aqueous based fluid.

25. A medical device for collecting a sample of blood or other aqueous based fluid including the capillary tube of claim 17 .

26. A method of collecting a fluid sample comprising inserting an open end of the capillary tube of claim 17 into a fluid specimen and drawing fluid from the specimen into the channel via capillary action.

27. The capillary tube of claim 17 , wherein the capillary tube is sized for collecting a sample of at least 0.5 microliters.

28. The capillary tube of claim 17 , wherein the capillary tube is sized for collecting a sample from about 0.5 to about 2 microliters.

Assignments (9)
SECURITY INTEREST Recorded Nov 15, 2017
From: TEKNI-PLEX, INC.; NATVAR HOLDINGS, LLC; PLASTIC SPECIALTIES AND TECHNOLOGIES, INC.; TRI-SEAL HOLDINGS, INC.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
Reel/Frame 044763/0001 →
SECURITY INTEREST Recorded Nov 15, 2017
From: TEKNI-PLEX, INC.; NATVAR HOLDINGS, LLC; PLASTIC SPECIALTIES AND TECHNOLOGIES, INC.; TRI-SEAL HOLDINGS, INC.
To: BMO HARRIS BANK, N.A.
Reel/Frame 044763/0339 →
RELEASE OF SECURITY INTEREST Recorded Oct 18, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: TEKNI-PLEX, INC.; NATVAR HOLDINGS, LLC; PLASTIC SPECIALTIES AND TECHNOLOGIES, INC.; TRI-SEAL HOLDINGS, INC.
Reel/Frame 044342/0928 →
RELEASE OF SECURITY INTEREST Recorded Oct 18, 2017
From: BANK OF AMERICA, N.A.
To: TEKNI-PLEX, INC.; NATVAR HOLDINGS, LLC; PLASTIC SPECIALTIES AND TECHNOLOGIES, INC.; TRI-SEAL HOLDINGS, INC.
Reel/Frame 044225/0079 →
RELEASE OF SECURITY INTEREST Recorded Oct 18, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: TEKNI-PLEX, INC.; NATVAR HOLDINGS, LLC; PLASTIC SPECIALTIES AND TECHNOLOGIES, INC.; TRI-SEAL HOLDINGS, INC.
Reel/Frame 044342/0866 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Jun 2, 2015
From: TEKNI-PLEX, INC.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 035813/0164 →
ABL PATENT SECURITY AGREEMENT Recorded Jun 2, 2015
From: TEKNI-PLEX, INC.
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 035814/0314 →
SECOND LIEN PATENT SECURITY AGREEMENT Recorded Jun 2, 2015
From: TEKNI-PLEX, INC.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 035814/0362 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 23, 2014
From: OLSAVSKY, JOSEPH E.; SCHLATER, STEVE
To: TEKNI-PLEX, INC.
Reel/Frame 032734/0887 →