IP Library Granted Patent US 9,404,025
Granted Patent B1
US 9,404,025 · App. 14/256,950 · Granted Aug 2, 2016

Wood adhesive

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Quick Facts
Patent No.
US 9,404,025
App. No.
14/256,950
Granted
Aug 2, 2016
Kind
B1
Abstract

An adhesive composition for manufacturing a composite wood product comprising an aqueous network of a formaldehyde condensation resin, wheat flour, and wheat gluten, said adhesive composition having a density less than water and is non-thixotropic. The composition is prepared by subjecting an aqueous formaldehyde condensation resin, wheat flour and wheat gluten to an intense high shear.

Claims (32)

1. A blended adhesive composition for manufacturing a composite wood product comprising an aqueous network of:

a formaldehyde condensation resin,

wheat flour, and

wheat gluten, said adhesive composition having a density less than water, wherein the wheat flour comprises a pre-extracted gluten content from 7.5 wt. % to 15 wt. %, and wherein the wheat flour has been exposed to a shear extraction process in the presence of the formaldehyde condensation resin in the absence of additional water.

2. The adhesive composition of claim 1 wherein said formaldehyde condensation resin is urea-formaldehyde.

3. The adhesive composition of claim 2 wherein said composite wood product is hardwood plywood.

4. The adhesive composition of claim 1 wherein said wheat gluten was shear extracted from said wheat flour during manufacture of said adhesive composition.

5. The adhesive composition of claim 1 wherein the wheat gluten comprises shear extracted wheat gluten from said wheat flour and wheat gluten isolates.

6. The adhesive composition of claim 1 wherein said adhesive composition is non-thixotopic.

7. The adhesive composition of claim 1 wherein said adhesive composition has a density of between about 7.90 and about 8.00 pounds per US gallon.

8. The adhesive composition of claim 7 wherein said adhesive composition has a density of about 7.98 pounds per US gallon.

9. A blended adhesive composition for manufacturing hardwood plywood comprising an aqueous network of a urea-formaldehyde condensation resin, wheat flour, and wheat gluten, said adhesive composition having a density of between about 7.90 and 8.00 pounds per US gallon and a thixotropic index of substantially 1.0, wherein the wheat flour comprises a gluten content from 7.5 wt % to 15 wt. %, and wherein the wheat flour has been exposed to a shear extraction process in the presence of the formaldehyde condensation resin in the absence of additional water.

10. The process of preparing an adhesive for composite wood products comprising:

providing an aqueous formaldehyde condensation resin;

subjecting said resin to an intensely high shear;

adding wheat flour having a pre-extracted gluten content of 7.5 wt. % to 15 wt. % to said resin under said intense high shear in the absence of additional water, said intense high shear being sufficient to extract wheat gluten from said wheat flour;

adding water to said resin, wheat flour and wheat gluten under said intense high shear in an amount sufficient to provide an adhesive composition having a viscosity suitable for preparing a selected composite wood product; and

subjecting said resin, wheat flour, wheat gluten and water to said intense high shear for a time sufficient to form an adhesive composition having a density less than water.

11. The process of claim 10 wherein wheat gluten isolates are added prior to water addition in an amount that raises the total wheat gluten content to a level that allows the composition to achieve said density less than water.

12. The process of claim 10 wherein said resin is a urea-formaldehyde resin.

13. The process of claim 12 wherein said aqueous urea-formaldehyde resin has a solids content of about 60%.

14. The process of claim 12 wherein said composite wood product is hardwood plywood.

15. The process of claim 10 wherein the amount of water added to the adhesive composition does not exceed about 25% by weight of the final adhesive composition.

16. The process of claim 10 wherein said adhesive composition has a density of between about 7.90 and about 8.00 pounds per US gallon.

17. The process of claim 16 wherein said adhesive composition has a density of about 7.98 pounds per US gallon.

18. The process of preparing an adhesive composition for composite wood products comprising:

providing an aqueous urea-formaldehyde condensation resin;

subjecting said resin to an intense high shear;

adding wheat flour having a pre-extracted gluten content of 7.5 wt. % to 15 wt. % to said resin under said intense high shear in the absence of additional water, said intense high shear being sufficient to extract wheat gluten from said wheat flour;

adding water to said resin, wheat flour and wheat gluten under said high shear in an amount up to about 25% by weight of said adhesive composition; and

subjecting said resin, wheat flour, wheat gluten and water to said intense high shear for a time sufficient to form an adhesive composition having a density less than water and is non-thixotropic.

19. The process of claim 18 wherein said aqueous urea-formaldehyde resin has a solids content of about 60% by weight.

Assignments (12)
RELEASE OF SECURITY INTEREST IN PATENTS (ABL) RECORDED AT REEL/FRAME 049740/0770 Recorded Mar 18, 2022
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: HEXION INC.
Reel/Frame 059435/0490 →
RELEASE OF SECURITY INTEREST IN PATENTS (TERM LOAN) RECORDED AT REEL/FRAME 049741/0425 Recorded Mar 18, 2022
From: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
To: HEXION INC.
Reel/Frame 059435/0473 →
SECURITY INTEREST Recorded Mar 18, 2022
From: HEXION INC.; HEXION INVESTMENTS INC.
To: GOLDMAN SACHS BANK USA, AS ADMINISTRATIVE AGENT
Reel/Frame 059436/0748 →
SECURITY INTEREST Recorded Mar 18, 2022
From: HEXION INC.; HEXION INVESTMENTS INC.
To: GOLDMAN SACHS BANK USA, AS ADMINISTRATIVE AGENT
Reel/Frame 059436/0823 →
SECURITY INTEREST Recorded Mar 18, 2022
From: HEXION INC.; HEXION INVESTMENTS INC.
To: ROYAL BANK OF CANADA, AS ADMINISTRATIVE AGENT
Reel/Frame 059436/0842 →
PATENT SECURITY INTEREST (TERM LOAN) Recorded Jul 12, 2019
From: HEXION INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 049741/0425 →
PATENT SECURITY INTEREST (ABL) Recorded Jul 12, 2019
From: HEXION INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 049740/0770 →
PATENT SECURITY INTEREST ASSIGNMENT AGREEMENT Recorded Apr 3, 2019
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS THE PRIOR COLLATERAL AGENT
To: WILMINGTON SAVINGS FUND SOCIETY, FSB, AS THE CURRENT COLLATERAL AGENT
Reel/Frame 048788/0617 →
SECURITY INTEREST Recorded Feb 13, 2017
From: HEXION INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 041693/0888 →
SECURITY INTEREST Recorded Feb 16, 2015
From: MOMENTIVE SPECIALTY CHEMICALS INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 034967/0872 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 6, 2015
From: HOLTE, IVAN E
To: MOMENTIVE SPECIALTY CHEMICALS INC.
Reel/Frame 034906/0367 →
CHANGE OF NAME Recorded Feb 3, 2015
From: MOMENTIVE SPECIALTY CHEMICALS INC.
To: HEXION INC.
Reel/Frame 034882/0127 →