Method for selecting lubricants for heat pumps
View Patent ↗Provided is a method for selecting a lubricant and a refrigerant for use in a vapor-compression refrigeration device such that the combination of the lubricant and refrigerant produces a fluid system having a lubricant-rich phase and a refrigerant-rich phase, yet exhibits miscible-type properties.
1. A vapor compression system comprising:
a condenser having an inlet side and an outlet side;
a compressor having an inlet side and an outlet side;
an evaporator having an inlet side and an outlet side;
an expansion valve having an inlet side and an outlet side;
a circulation loop placing each of the condenser, compressor, evaporator, and expansion valve into fluid communication; and
a heat transfer fluid comprising a refrigerant-rich portion and a lubricant-rich portion, wherein a relative difference between the densities of the portions is less than 20%, and wherein at a temperature below a phase inversion temperature of the heat transfer fluid the refrigerant-rich portion and the lubricant-rich portion are immiscible and one of the refrigerant-rich portion and lubricant-rich portion is more dense and at a temperature above the phase inversion temperature the refrigerant-rich portion and the lubricant-rich portion are immiscible and the other of the refrigerant-rich portion and the lubricant-rich portion is more dense.
2. The system of claim 1 wherein at a temperature below the phase inversion temperature the refrigerant-rich portion is more dense than the lubricant-rich portion and at a temperature above the phase inversion temperature the lubricant-rich portion is more dense than the refrigerant-rich portion.
3. The system of claim 1 wherein the refrigerant-rich portion comprises at least one C 2 to C 5 fluoroalkene.
4. The system of claim 3 wherein the fluoroalkene is a C 3 or C 4 fluoroalkene.
5. The system of claim 3 wherein the fluoroalkene has a formula XCF z R 3-z wherein X is a substituted or unsubstituted vinyl or allyl radical, R is independently Cl, Br, I or H, and z is 1 to 3.
6. The system of claim 5 wherein z is 3.
7. The system of claim 3 wherein the fluoroalkene is selected from the group consisting of trifluorpropene, tetrafluoropropene, and pentafluoropropene.
8. The system of claim 7 wherein the fluoroalkene is selected from the group consisting of cis-1,3,3,3-tetrafluoropropene; trans-1,3,3,3-tetrafluoropropene; 1,1,1,2-tetrafluoropropene; 1,1,1-trifluoro-3-chloro-2-propene; 3,3,3-trifluoropropene; and combinations thereof.
9. The system of claim 1 wherein the lubricant-rich portion comprises a lubricant selected from the group consisting of at least one of a one polyol ester, a polyalkylene glycol, a polyalkylene glycol ester, mineral oils, alkylbenzenes, polyalpha-olefins, alkylated naphthalenes, and polyalkylene glycol esters.
10. The system of claim 1 wherein the lubricant-rich portion comprises a lubricant selected from the group consisting of at least one of a one polyol ester, a polyalkylene glycol, and a polyalkylene glycol ester.
11. The system of claim 10 wherein said polyalkylene glycol is a branched or straight chain polymer having from about 5 to about 50 units of oxyethylene, oxypropylene, oxybutylene, oxypentylene, or combinations thereof.
12. The system of claim 11 wherein said polymer comprises at least 50 weight percent oxypropylene units.
13. The system of claim 10 wherein said polyol ester has a structure according to formulae I or II:
RO(R 1 O) n C(O)R 2 (I)
R 3 (O)C(O)R 2 (II)
wherein R is a hydrocarbyl group having at least 2 carbon atoms,
R 1 is a hydrocarbylene group,
R 2 is H, hydrocarbyl, —CF 3 , —R 4 CN, —R 4 NO 2 or R 5 OCH(R 6 )—,
R 3 is a —R 4 CF 3 , —R 4 CN or —R 4 NO 2 group, provided that R 3 may be a hydrocarbyl group when
R 2 is —R 4 CN,
n is an integer from 1 to about 50,
R 4 is a hydrocarbylene group,
R 5 is H, a lower hydrocarbyl group or R 7 C(O)— where R 7 is a hydrocarbyl group, and
R 6 is H or a lower hydrocarbyl group.
14. The system of claim 1 wherein the relative difference between the densities of the portions is less than 10%.
15. The system of claim 1 wherein the relative difference between the densities of the portions is less than 5%.
16. The system of claim 1 wherein said temperature above said phase inversion temperature is between about +30° C. to about +75° C.
17. The system of claim 1 wherein said temperature below said phase inversion temperature is between about −40° C. to about +25° C.
18. The system of claim 1 wherein the composition comprises from about 60 to about 90 weight percent of the refrigerant-rich portion and from about 10 to about 40 weight percent of the lubricant-rich portion, wherein weight percents are relative to the total weight of said composition.
19. The system of claim 1 wherein the composition comprises from about 70 to about 99 weight percent of the refrigerant-rich portion and from about 1 to about 30 weight percent of the lubricant-rich portion, wherein weight percents are relative to the total weight of said composition.
20. The system of claim 1 wherein said composition further comprises one or more of extreme pressure additives, anti-wear additives, oxidation stabilizers, thermal stabilizers, pour and floc point depressants, anti-foaming agents, lubricants soluble in fluoroolefins, surfactants, compatibilizers, and solubilizing agents.