Corrosion resistant barrier layer for a solid oxide fuel cell stack and method of making thereof
View Patent ↗A method of forming diffusion barrier layer includes providing an interconnect for a fuel cell stack, forming a glass barrier precursor layer over a Mn and/or Co containing electrically conductive contact layer on the interconnect, and heating the barrier precursor layer to precipitate crystals in the barrier precursor layer to convert the barrier precursor layer to a glass ceramic barrier layer.
1. A solid oxide fuel cell (SOFC) stack, comprising:
a plurality of SOFCs;
a plurality of interconnects, wherein each of the plurality of the interconnects is located between two adjacent SOFCs; and
at least one glass or glass ceramic seal located between each of the plurality of interconnects and a cathode side of one of the adjacent SOFCs;
wherein each of the plurality of interconnects comprises:
an electrically conductive contact layer located on a cathode side of the interconnect, the electrically conductive contact layer containing at least one of Co and Mn; and
a glass ceramic barrier layer located over the electrically conductive contact layer, the glass ceramic barrier layer comprising all of zirconium silicate (ZrSiO 4 ) crystals, barium aluminum silicate (BaAlSiO 4 ) crystals and potassium feldspar (KAlSi 3 O 8 ) crystals located in a glassy matrix.
2. The SOFC stack of claim 1 , wherein the at least one glass or glass ceramic seal is located between the glass ceramic barrier layer of one of the plurality of interconnects and the cathode side of one of the adjacent SOFCs.
3. The SOFC stack of claim 2 , wherein the at least one glass or glass ceramic seal comprises a ring seal located over the glass ceramic barrier layer in at least one fuel riser region around a fuel riser opening through the one of the plurality of interconnects.
4. The SOFC stack of claim 3 , wherein:
the electrically conductive contact layer comprises lanthanum strontium manganite (LSM), manganese cobalt oxide spinel (MCO) or a mixture thereof;
each of the plurality of interconnects comprises a chromium-iron alloy interconnect having gas flow channels and ribs;
the glass ceramic barrier layer prevents or reduces at least one of Mn and Co diffusion from the electrically conductive contact layer to at least one of the seal and an adjacent SOFC in the SOFC stack; and
the glass ceramic barrier layer is formed from a glass barrier precursor layer that comprises:
45-55 wt. % silica (SiO 2 );
5-10 wt. % potassium oxide (K 2 O);
2-5 wt. % calcium oxide (CaO);
2-5 wt. % barium oxide (BaO);
0-1 wt. % boron trioxide (B 2 O 3 );
15-25 wt. % alumina (Al 2 O 3 ); and
20-30 wt. % zirconia (ZrO 2 ) on an oxide weight basis.
5. The SOFC stack of claim 4 , wherein:
the glass ceramic barrier layer further comprises alumina crystals located in the glassy matrix; and
the glass ceramic barrier layer is formed from a glass barrier precursor layer that comprises:
44.6 wt. % silica;
6.3 wt. % potassium oxide;
2.4 wt. % calcium oxide;
2.4 wt. % barium oxide;
19.1 wt. % alumina;
0.1 wt. % boron trioxide; and
25.1 wt. % zirconia on an oxide weight basis.
6. A solid oxide fuel cell (SOFC) stack, comprising:
a plurality of SOFCs;
a plurality of interconnects, wherein each of the plurality of the interconnects is located between two adjacent SOFCs; and
at least one glass or glass ceramic seal located between each of the plurality of interconnects and a cathode side of one of the adjacent SOFCs
wherein each of the plurality of interconnects comprises:
an electrically conductive contact layer located on a cathode side of the interconnect, the electrically conductive contact layer containing at least one of Co and Mn; and
a glass ceramic barrier layer located over the electrically conductive contact layer, the glass ceramic barrier layer comprising all of zirconium silicate crystals, alkali earth metal aluminum silicate crystals and potassium feldspar crystals located in a glassy matrix.
7. The SOFC stack of claim 6 , wherein the at least one glass or glass ceramic seal is located between the glass ceramic barrier layer of one of the plurality of interconnects and the cathode side of one of the adjacent SOFCs.
8. The SOFC stack of claim 7 , wherein the at least one glass or glass ceramic seal comprises a ring seal located over the glass ceramic barrier layer in at least one fuel riser region around a fuel riser opening through the one of the plurality of interconnects.
9. The SOFC stack of claim 8 , wherein:
the alkali earth metal aluminum silicate crystals comprise barium aluminum silicate crystals;
the electrically conductive contact layer comprises lanthanum strontium manganite (LSM), manganese cobalt oxide spinel (MCO) or a mixture thereof;
each of the plurality of interconnects comprises a chromium-iron alloy interconnect having gas flow channels and ribs;
the glass ceramic barrier layer prevents or reduces at least one of Mn and Co diffusion from the electrically conductive contact layer to at least one of the seal and an adjacent SOFC in the SOFC stack; and
the glass ceramic barrier layer is formed from a glass barrier precursor layer that comprises:
45-55 wt. % silica (SiO 2 );
5-10 wt. % potassium oxide (K 2 O);
2-5 wt. % calcium oxide (CaO);
2-5 wt. % barium oxide (BaO);
0-1 wt. % boron trioxide (B 2 O 3 );
15-25 wt. % alumina (Al 2 O 3 ); and
20-30 wt. % zirconia (ZrO 2 ) on an oxide weight basis.
10. The SOFC stack of claim 9 , wherein:
the glass ceramic barrier layer further comprises alumina crystals located in the glassy matrix; and
the glass ceramic barrier layer is formed from a glass barrier precursor layer that comprises:
44.6 wt. % silica;
6.3 wt. % potassium oxide;
2.4 wt. % calcium oxide;
2.4 wt. % barium oxide;
19.1 wt. % alumina;
0.1 wt. % boron trioxide; and
25.1 wt. % zirconia on an oxide weight basis.