Coating composition for packaging articles
A coating composition is provided that includes a polymer, which is preferably a polyester polymer. The polyester polymer preferably includes one or more heterocyclic groups that preferably include at least one nitrogen atom and at least one carbonyl group. In one embodiment, the binder polymer is made using ingredients including tris(2-hydroxyethyl) isocyanurate. The coating composition is useful in a variety of packaging coating applications, including as a coating for aluminum monobloc containers.
1. An article, comprising:
an aluminum monobloc container or a portion thereof; and
a coating formed from a spray-applied coating composition that does not include n-methyl-2-pyrrolidone (NMP), comprises an adhesion promoter and is substantially free of bisphenol A, the coating disposed on at least a portion of an interior surface of the aluminum monobloc container or a portion thereof, wherein the coating composition includes at least 15 weight percent of a polyester polymer that includes one or more heterocyclic groups having a ring that includes one or more nitrogen atoms and one or more carbon atoms of carbonyl groups, based on the total nonvolatile weight of the coating composition;
wherein the coating exhibits no corrosion or adhesion loss after storage for one week at 55° C. while contacting a mixture comprising, by volume, ⅓ dimethyl ether, ⅓ water, and ⅓ ethanol.
2. The article of claim 1 , wherein the coating composition further comprises at least 0.5 weight percent of titanium-containing catalyst, based on the total non- volatile weight of the coating composition.
3. The article of claim 2 , wherein the titanium-containing catalyst comprises a titanium-containing organometallic catalyst, and wherein the coating composition includes at least 4 weight percent of titanium-containing organometallic catalyst, based on the total non-volatile weight of the coating composition.
4. The article of claim 2 , wherein the coating composition includes at least 2 weight percent of titanium-containing organometallic catalyst, based on the total non-volatile weight of the coating composition, and wherein the titanium-containing catalyst comprises a tetraalkyltitanate.
5. The article of claim 1 , wherein the adhesion promoter comprises an acid-functional adhesion promoter.
6. The article of claim 5 , wherein the coating composition comprises at least 2 weight percent of the acid-functional adhesion promoter, based on the total non-volatile weight of the coating composition.
7. The article of claim 1 , wherein the adhesion promoter has an acid value of about 50 mg KOH/g resin or higher.
8. The article of claim 1 , wherein the adhesion promoter comprises a hydroxyl-and/or carboxyl-functional phosphate ester, a carboxy-modified ester resin, or a mixture thereof.
9. The article of claim 1 , wherein the coating composition exhibits no corrosion or adhesion loss after storage at 40° C. for an additional four weeks while contacting the mixture comprising, by volume, ⅓ dimethyl ether, ⅓ water, and ⅓ ethanol; and wherein the polyester polymer is formed from ingredients including tris (2-hydroxyethyl) isocyanurate or a derivative thereof.
10. The article of claim 1 , wherein the polyester polymer is hydroxyl-functional, and wherein the coating composition includes an amino crosslinker, a phenolic crosslinker, a blocked isocyanate crosslinker, or a combination thereof.
11. The article of claim 10 , wherein the polyester polymer is formed from ingredients including tris (2-hydroxyethyl) isocyanurate or a derivative thereof, and wherein the polyester polymer comprises a polyester-imide polymer.
12. The article of claim 1 , wherein the aluminum monobloc container contains a pressurized packaged product including dimethyl ether.
13. An article, comprising:
an aluminum monobloc pressurized container or a portion thereof formed from an aluminum slug via an impact extrusion process that uses a lubricant to facilitate the fabrication process; and
a thermoset coating having a thickness of, an average, from as low as about 4 microns thick to as high as about 20 microns thick; wherein the coating is formed from a spray-applied coating composition disposed on at least a portion of an interior surface of the aluminum monobloc container or a portion thereof; and wherein the coating composition does not include n-methyl-2-pyrrolidone (NMP), is substantially free of bisphenol A, comprises an adhesion promoter and includes at least about 50 weight percent of a hydroxy-functional polyester-imide polymer that includes one or more heterocyclic groups having a ring that includes one or more nitrogen atoms and one or more carbon atoms of carbonyl groups, based on the total nonvolatile weight of the coating composition, and wherein the polyester polymer comprises a reaction product of ingredients including tris (2-hydroxyethyl) isocyanurate; and wherein the pressurized container further includes a packaged product including dimethyl ether; and wherein the coating exhibits no corrosion or adhesion loss, while contacting the packaging product, after storage for one week at 55° C. and then 40° C. for an additional four weeks.
14. The article of claim 13 , wherein the coating composition includes xylenes.
15. The article of claim 13 , wherein the coating composition is substantially epoxy-free.
16. The article of claim 13 , wherein the adhesion promoter comprises an acid-functional adhesion promoter.
17. The article of claim 16 , wherein the hydroxy-functional polyester-imide polymer has an acid number of less than about 10.
18. The article of claim 17 , wherein the hydroxy-functional polyester-imide polymer is hydroxyl-terminated.
19. An inside spray coating composition that does not include n-methyl-2-pyrrolidone (NMP) and is substantially free of bisphenol A, the coating composition having a viscosity of from 25 to 200 seconds, when measured using a DIN cup at 23° C. and comprising:
at least 50 weight percent, based on the total non-volatile weight of the coating composition, of a hydroxyl-functional polyester polymer having an acid number of less than about 10 and formed from ingredients including tris (2-hydroxyethyl) isocyanurate or a derivative thereof;
at least 0.5 weight percent of titanium-containing organometallic catalyst, based on the total non-volatile weight of the coating composition;
at least 0.2 weight percent of an adhesion promoter, based on the total non- volatile weight of the coating composition;
an amino crosslinker, a phenolic crosslinker, a blocked isocyanate crosslinker, or a combination thereof; and
an organic solvent having a boiling point of 110° C. to 190° C.;
wherein the coating composition is suitable for use in forming a spray-applied thermoset coating on an interior of an aluminum monobloc container or a portion thereof formed from an aluminum slug using an impact extrusion process that uses a lubricant to facilitate the fabrication process.