IP Library Granted Patent US 9,834,718
Granted Patent B2
US 9,834,718 · App. 14/270,815 · Granted Dec 5, 2017

Ecofriendly lubricating additives for water-based wellbore drilling fluids

Inventors: Md Amanullah (Dhahran, SA); Abdulaziz S. Bubshait (Dhahran, SA); Omar A. Fuwaires (Dhahran, SA)
Assignee: Saudi Arabian Oil Company
C09K8/16C09K8/035C09K8/18C10M129/70C11C3/003E21B7/00E21B21/068C09K2208/34C10M2207/281C10M2207/283C10M2207/40C10N2230/06C10N2270/00
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Quick Facts
Patent No.
US 9,834,718
App. No.
14/270,815
Granted
Dec 5, 2017
Kind
B2
Abstract

Some examples of producing water-based drilling fluids including ecofriendly lubricating additives are described. A raw material oil including fatty acids with a short chain alcohol is esterified in the presence of a catalyst to produce alkyl ester products and triglycerides. The alkyl ester products are washed and heated to remove any residual water or the short chain alcohol. A first quantity of the alkyl ester products is mixed with a second quantity of a water-based wellbore drilling fluid.

Claims (16)

1. A method for producing water-based wellbore drilling fluids, the method comprising:

esterifying a raw material oil comprising fatty acids with a short chain alcohol in the presence of a catalyst to produce alkyl ester products and triglycerides;

washing the alkyl ester products;

heating the alkyl ester products to remove any residual water or the short chain alcohol; and

mixing a first quantity of the alkyl ester products with a second quantity of a water-based wellbore drilling fluid, wherein the first quantity is substantially between 1.5% and 3.4% by volume of a sum of the first quantity and the second quantity.

2. The method of claim 1 , wherein the first quantity is substantially between 6 cc and 12 cc, and the second quantity is 350 cc.

3. The method of claim 1 , further comprising separating the alkyl ester products and the triglycerides before washing the alkyl ester products.

4. The method of claim 1 , further comprising removing impurities from the raw material oil prior to esterifying the raw material oil.

5. The method of claim 1 , wherein removing the impurities from the raw material oil comprises filtering the raw material oil at a pressure ranging substantially between 5 psi and 10 psi.

6. The method of claim 1 , wherein the raw material oil comprises processed vegetable oil.

7. The method of claim 1 , wherein the fatty acids comprise molecules averaging substantially from 16 carbon atoms to less than 20 carbon atoms.

8. The method of claim 1 , wherein the short chain alcohol comprises at least one or more of methanol, ethanol, propanol, or butanol.

9. The method of claim 1 , wherein a plastic viscosity of the raw material oil is greater than substantially 50 cP.

10. The method of claim 1 , wherein the catalyst comprises at least one of sodium hydroxide, potassium hydroxide, sodium alkoxides, or potassium alkoxides.

11. The method of claim 1 , further comprising, before washing the alkyl ester products, breaking emulsions formed in the alkyl ester products and triglycerides in response to the esterifying.

12. The method of claim 11 , breaking the emulsions formed in the alkyl ester products and triglycerides in response to the esterifying comprises adding a quantity of acetic acid to the alkyl ester products and triglycerides.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2014
From: AMANULLAH, MD; BUBSHAIT, ABDULAZIZ S.; FUWAIRES, OMAR A.
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 032833/0770 →
Continuity (1)
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