BACK JUNCTION SOLAR CELL WITH TUNNEL OXIDE
One embodiment of the present invention provides a back junction solar cell. The solar cell includes a base layer, a quantum-tunneling-barrier (QTB) layer situated below the base layer facing away from incident light, an emitter layer situated below the QTB layer, a front surface field (FSF) layer situated above the base layer, a front-side electrode situated above the FSF layer, and a back-side electrode situated below the emitter layer.
1 . A method for fabricating a tunneling-junction based solar cell, comprising:
obtaining a base layer for the solar cell;
simultaneously forming a front-side quantum-tunneling-barrier (QTB) layer on a front surface of the base layer and a back-side QTB layer on a back surface of the base layer;
forming an emitter;
forming a surface field layer;
forming a front-side electrode; and
forming a back-side electrode.
2 . The method of claim 1 , wherein the base layer comprises at least one of:
a mono-crystalline silicon wafer; and
an epitaxially grown crystalline-Si (c-Si) thin film.
3 . The method of claim 2 , wherein the epitaxially grown c-Si thin film's doping profile is modulated.
4 . The method of claim 1 , wherein the QTB layers comprise at least one of:
silicon oxide (SiO x );
hydrogenated SiO x ;
silicon nitride (SiN x );
hydrogenated SiN x ;
aluminum oxide (AlO x );
silicon oxynitride (SiON); and
hydrogenated SiON.
5 . The method of claim 1 , wherein the QTB layers have a thickness between 1 and 50 angstroms.
6 . The method of claim 1 , wherein forming the QTB layers involves at least one of the following techniques:
thermal oxidation;
atomic layer deposition;
wet or steam oxidation;
low-pressure radical oxidation; and
plasma-enhanced chemical-vapor deposition (PECVD).
7 . The method of claim 1 , further comprising forming a transparent conductive oxide (TCO) layer on the emitter, the surface field layer, or both.
8 . The method of claim 1 , wherein the emitter and/or the surface field layer comprise amorphous-Si (a-Si).
9 . The method of claim 8 , wherein the emitter comprises carbon-doped a-Si.
10 . The method of claim 8 , wherein the emitter and the surface field layer comprise undoped a-Si.
11 . The method of claim 8 , wherein the emitter and/or the surface field layer comprise graded-doped amorphous-Si (a-Si).
12 . The method of claim 11 , wherein the graded-doped a-Si has a doping concentration ranging between 1×10 15 /cm 3 and 5×10 20 /cm 3 .
13 . The method of claim 11 , wherein when an n-type dopant is used for the graded-doped a-Si the n-type dopant comprises phosphorus, and wherein when a p-type dopant is used for the graded-doped a-Si the p-type dopant comprises boron.
14 . The method of claim 1 , wherein the base layer has a donor (n-type) or acceptor (p-type) doping concentration ranging between 1×10 14 /cm 3 and 1×10 18 /cm 3 .
15 . The method of claim 14 , wherein the emitter has an opposite doping type as that of the base layer, and wherein the surface field layer has a same doping type as that of the base layer.
16 . The method of claim 15 , wherein the emitter is formed on the front-side QTB layer, facing incident light, and wherein the surface field layer is formed on the back-side QTB layer to act as a back surface field (BSF).
17 . The method of claim 15 , wherein the emitter is formed on the back-side QTB layer, facing away from incident light, and wherein the surface field layer is formed on the front-side QTB layer to act as a front surface field (FSF).
18 . The method of claim 1 , wherein forming the QTB layers involves using a wet oxidation technique to form a SiO x layer with x less than 2.
19 . A tunneling-junction based solar cell, comprising:
a base layer;
a front quantum-tunneling-barrier (QTB) layer situated on a front surface of the base layer;
a back QTB layer situated on a back surface of the base layer;
an emitter;
a surface field layer;
a front-side electrode; and
a back-side electrode.
20 . The solar cell of claim 19 , wherein the base layer comprises at least one of:
a mono-crystalline silicon wafer; and
an epitaxially grown crystalline-Si (c-Si) thin film.
21 . The solar cell of claim 20 , wherein the epitaxially grown c-Si thin film's doping profile is modulated.
22 . The solar cell of claim 19 , wherein the QTB layers comprise at least one of:
silicon oxide (SiO x );
hydrogenated SiO x ;
silicon nitride (SiN x );
hydrogenated SiN x ;
aluminum oxide (AlO x );
silicon oxynitride (SiON); and
hydrogenated SiON.
23 . The solar cell of claim 19 , wherein the QTB layers have a thickness between 1 and 50 angstroms.
24 . The solar cell of claim 19 , wherein the QTB layers are formed using at least one of the following techniques:
thermal oxidation;
atomic layer deposition;
wet or steam oxidation;
low-pressure radical oxidation; and
plasma-enhanced chemical-vapor deposition (PECVD).
25 . The solar cell of claim 19 , further comprising a transparent conductive oxide (TCO) layer situated above the emitter, the surface field layer, or both.
26 . The solar cell of claim 19 , wherein the emitter and/or the surface field layer comprise amorphous-Si (a-Si).
27 . The solar cell of claim 26 , wherein the emitter comprises carbon-doped a-Si.
28 . The solar cell of claim 26 , wherein the emitter and/or the surface field layer comprise undoped a-Si.
29 . The solar cell of claim 26 , wherein the emitter and/or the surface field layer comprise graded-doped amorphous-Si (a-Si).
30 . The solar cell of claim 29 , wherein the graded-doped a-Si has a doping concentration ranging between 1×10 15 /cm 3 and 5×10 20 /cm 3 .
31 . The solar cell of claim 29 , wherein when an n-type dopant is used for the graded-doped a-Si the n-type dopant comprises phosphorus, and wherein when a p-type dopant is used for the graded-doped a-Si the p-type dopant comprises boron.
32 . The solar cell of claim 19 , wherein the base layer has a donor (n-type) or acceptor (p-type) doping concentration ranging between 1×10 14 /cm 3 and 1×10 18 /cm 3 .
33 . The solar cell of claim 32 , wherein the emitter has an opposite doping type as that of the base layer, and wherein the surface field layer has a same doping type as that of the base layer.
34 . The solar cell of claim 33 , wherein the emitter is situated above the base layer facing incident light, and wherein the surface field layer is situated beneath the base layer to act as a back surface field (BSF).
35 . The solar cell of claim 33 , wherein the emitter is situated beneath the base layer facing away from incident light, and wherein the surface field layer is situated above the base layer to act as a front surface field (FSF).
36 . The solar cell of claim 19 , wherein the QTB layers comprise a SiO x layer with x less than 2, wherein the SiO x layer is formed using a wet oxidation technique.
37 . A solar cell, comprising:
a base layer;
a quantum-tunneling-barrier (QTB) layer situated adjacent to the base layer, wherein the QTB layer comprises SiO x with x less than two;
an emitter;
a surface field layer;
a front-side electrode; and
a back-side electrode.