Polyester-carbamate polymer and coating compositions thereof
A polyester-carbamate polymer and coating compositions containing the polymer are provided. The polyester-carbamate polymer preferably includes a polyester-carbamate backbone and one or more blocked isocyanate groups. A coating composition is provided that preferably includes the polyester-carbamate polymer and a thermoplastic dispersion. In a preferred embodiment, the coating composition is an organosol.
1. A packaging article comprising a food or beverage container or a portion thereof having a coating adhered on at least a portion of a surface thereof, wherein the coating includes a layer formed form a coating composition that comprises: (i) a polyester-carbamate polymer having a backbone that includes both ester and carbamate linkages and (ii) a thermoplastic dispersion including a halogenated polyolefin material.
2. The packaging article of claim 1 , wherein the polyester-carbamate polymer has at least one pendant group that includes an oxirane group.
3. The packaging article of claim 1 , wherein the coating composition comprises:
at least about 15 weight percent of the polyester-carbamate polymer, by weight nonvolatile material in the coating composition, and
at least about 10 weight percent of thermoplastic particles comprising the halogenated polyolefin material, by weight nonvolatile material in the coating composition.
4. The packaging article of claim 1 , wherein the thermoplastic dispersion includes a substantially non-aqueous liquid carrier and the halogenated polyolefin material comprises polyvinylchloride particles.
5. The packaging article of claim 1 , wherein the polyester-carbamate polymer includes at least one blocked isocyanate group.
6. The packaging article of claim 5 , wherein the at least one blocked isocyanate groups is deblockable.
7. The packaging article of claim 6 , wherein the at least one blocked isocyanate group comprises a reaction product of an isocyanate group and one or more of glycidol, ε-caprolactam, methyl ethyl ketoxime (MEKO), or diisopropylamine (DIPA).
8. The packaging article of claim 1 , wherein the coating is a mono-layer coating.
9. The packaging article of claim 8 , wherein the packaging article comprises a three-piece food can, a shallow drawn food can, or a bottle crown having the coating adhered thereon.
10. The packaging article of claim 1 , wherein the coating is a multilayer coating that includes an additional size layer adhered directly to the surface.
11. The packaging article of claim 10 , wherein the layer formed from the coating composition including (i) and (ii) is a topcoat layer.
12. The packaging article of claim 11 , wherein the size layer is a polyester size coat.
13. The packaging article of claim 12 , wherein the polyester size coat includes about 60% to 80% by weight of nonvolatiles of one or more polyesters and about 20 to 40% by weight nonvolatiles of one or more phenolic resins.
14. The packaging article of claim 12 , wherein the polyester size coat includes a polyester-carbamate polymer.
15. The packaging article of claim 14 , wherein the polyester size coat includes, based on total nonvolatile weight, from about 15 to about 70% by weight of polyester-carbamate polymer and 0.5 to 30% by weight of one or more crosslinkers.
16. The packaging article of claim 15 , wherein the polyester-carbamate polymer includes one or more pendant blocked isocyanate groups.
17. The packaging article of claim 15 , wherein the polyester size coat includes at least some resole phenolic crosslinker and is substantially free of BPA and BADGE.
18. The packaging article of claim 11 , wherein the size layer is an epoxy-phenolic size coat.
19. The packaging article of claim 18 , wherein the epoxy-phenolic size coat includes from about 60 to about 90 wt-% of epoxy resin and from about 10 to about 40 wt-% of phenolic resin, by weight of nonvolatiles in the coating composition.
20. A packaging article comprising a food or beverage container or a portion thereof having a multilayer coating adhered on at least a portion of an interior metal surface thereof, wherein the multilayer coating is substantially free of bound BPA and aromatic glycidyl ether compounds, and wherein the multilayer coating includes:
a polyester size coat; and
a topcoat formed from a coating composition that comprises: (i) a polyester-carbamate polymer having a backbone that includes both ester and carbamate linkages and (ii) a thermoplastic dispersion including polyvinylchloride particles dispersed in a substantially non-aqueous liquid carrier.