Adhesive having insulative properties

1. A method of preparing a corrugated product having improved insulative properties, comprising the steps of:

a. providing a first paper liner that is substantially planar and has a first side and second side;

b. providing a second paper liner having a plurality of flutes each having a peak and a trough;

c. preparing an adhesive composition having improved insulative properties, comprising the steps of:

i. combining a high amylose starch component that has an amylose content greater than 50%, an alkaline component, sodium tetraborate, water, and about 0.5 to about 5 wet basis weight percent of a plurality of expandable microspheres to form a starch mixture;

ii. cooking said high amylose starch mixture to form a cooked starch mixture;

iii. adding unmodified starch component to said cooked starch mixture; and

iv. adding a plurality of expandable microspheres to said cooked starch mixture;

d. applying said adhesive composition to the peaks of each of said flutes;

e. mating the peaks of said flutes with a surface of said first side of said planar paper liner to form a composite structure wherein the first paper liner and the second paper liner contact each other at said peaks of said flutes; and

f. curing said adhesive composition in said composite structure by heating to a first temperature, which is from about 138° F. to about 156° F., and to a second temperature, wherein said first temperature and said second temperature differ by about 20° F. to about 40° F.

2. The method of claim 1 , wherein said step of placing said tips of said flutes to said first side of said substantially flat paper liner comprises using pressure to secure said tips to said first side.

3. The method of claim 1 , wherein said second temperature is about 178° F. to about 196° F.