IP Library Granted Patent US 9,114,372
Granted Patent B1
US 9,114,372 · App. 14/278,938 · Granted Aug 25, 2015

Electrocoagulation removal of hydrate inhibitors in produced water

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Quick Facts
Patent No.
US 9,114,372
App. No.
14/278,938
Granted
Aug 25, 2015
Kind
B1
Abstract

Electrocoagulation may be used to reduce the concentration of hydrate inhibitors in produced water. For example, a method may include producing a fluid from a subterranean formation, the fluid comprising petroleum hydrocarbons and water, the water having an organic material that includes hydrate inhibitors dispersed therein, wherein the hydrate inhibitors are at a concentration of about 30 ppm or greater in the water; separating the petroleum hydrocarbons from the water and the organic material; and separating at least some of the organic material from the water via electrocoagulation to yield an effluent water and a coagulated organic material.

Claims (12)

1. A method comprising:

producing a fluid from a subterranean formation, the fluid comprising petroleum hydrocarbons and water, the water having an organic material that includes hydrate inhibitors dispersed therein, wherein the hydrate inhibitors are at a concentration of about 30 ppm or greater in the water;

separating the petroleum hydrocarbons from the water and the organic material; and

separating at least some of the organic material from the water via a first electrocoagulation to yield a first effluent water and a coagulated organic material, wherein the first effluent water has a concentration of the organic material of greater than about 25 ppm; and

retreating the first effluent water via a second electrocoagulation to yield a second effluent water, wherein a concentration of the organic material in the second effluent water has been reduced by about 95% or more as compared to the water before electrocoagulation.

2. The method of claim 1 , wherein a concentration of the organic material in the second effluent water has been reduced by about 98% or more as compared to the water before electrocoagulation.

3. The method of claim 1 , wherein a concentration of the organic material in the water before the first electrocoagulation is about 500 ppm to about 30,000 ppm.

4. The method of claim 1 , wherein a concentration of the organic material in the water before the first electrocoagulation is up to about 75% by volume of the water.

5. The method of claim 1 further comprising:

adjusting the pH of the water before or during the first electrocoagulation to between about 3 and about 12.

6. The method of claim 1 further comprising:

adjusting the pH of the water before or during the second electrocoagulation to between about 3 and about 12.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 15, 2014
From: LORD, PAUL DAVID; WEAVER, JIMMIE D.; SHANNON, DANIEL EDWARD
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 032905/0907 →