Dual core golf ball having positive-hardness-gradient thermoplastic inner core and positive-hardness-gradient thermoset outer core layer
View Patent ↗A golf ball includes a core including a thermoplastic inner core and a thermoset outer core layer. The inner core has a surface hardness of about 40 to 80 Shore C and a center hardness of about 30 to 75 Shore C. The center hardness is less than the surface hardness to define a positive hardness gradient. A cover is formed over the core and includes an inner cover layer and an outer cover layer. The thermoplastic inner core includes a highly-neutralized ionomer formed from a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater. The outer core layer comprises a polybutadiene rubber and has a positive hardness gradient of less than 25 Shore C.
1. A golf ball comprising:
a core comprising a thermoplastic inner core and a thermoset outer core layer, the inner core having a surface hardness of about 40 to 80 Shore C and a center hardness of about 30 to 75 Shore C and is less than the surface hardness to define a first positive hardness gradient; and
a cover comprising an inner cover layer and an outer cover layer;
wherein the thermoplastic inner core comprises a highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater, and the outer core layer comprises a polybutadiene rubber and has a surface hardness greater than an interior hardness to define a second positive hardness gradient of less than 25 Shore C.
2. The golf ball of claim 1 , wherein the thermoplastic inner core further comprises an ethylene/acid copolymer or ionomer.
3. The golf ball of claim 1 , wherein the second positive hardness gradient is 1 to 15 Shore C.
4. The golf ball of claim 1 , wherein the acid groups of the copolymer are neutralized by 90% or greater.
5. The golf ball of claim 1 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.
6. The golf ball of claim 5 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.
7. The golf ball of claim 5 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.
8. The golf ball of claim 1 , wherein the acid copolymer further comprises a softening comonomer.
9. The golf ball of claim 1 , wherein the highly-neutralized ionomer further comprises a second polymer component.
10. The golf ball of claim 9 , wherein the second polymer component comprises ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, polyamides, polycarbonates, polyesters, polyurethanes, polyureas, thermoplastic elastomers, polybutadiene rubber, balata, grafted- or non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers, or cationic ionomers.
11. A golf ball comprising:
a core comprising a thermoplastic inner core and a thermoset outer core layer, the inner core having a surface hardness of about 65 to 95 Shore C and a center hardness of about 60 to 90 Shore C and is less than the surface hardness to define a first positive hardness gradient; and
a cover comprising an inner cover layer and an outer cover layer;
wherein the thermoplastic inner core comprises a highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater, and the outer core layer comprises a polybutadiene rubber and has a surface hardness greater than an interior hardness to define a second positive hardness gradient of less than 25 Shore C.
12. The golf ball of claim 11 , wherein the thermoplastic inner core further comprises an ethylene/acid copolymer or ionomer.
13. The golf ball of claim 11 , wherein the second positive hardness gradient is 1 to 15 Shore C.
14. The golf ball of claim 11 , wherein the acid groups of the copolymer are neutralized by 90% or greater.
15. The golf ball of claim 11 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.
16. The golf ball of claim 15 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.
17. The golf ball of claim 15 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.
18. The golf ball of claim 11 , wherein the acid copolymer further comprises a softening comonomer.
19. The golf ball of claim 11 , wherein the highly-neutralized ionomer further comprises a second polymer component.
20. The golf ball of claim 19 , wherein the second polymer component comprises ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, polyamides, polycarbonates, polyesters, polyurethanes, polyureas, thermoplastic elastomers, polybutadiene rubber, balata, grafted- or non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers, or cationic ionomers.