Biobased carbodiimides, a process for preparation thereof and use thereof

1. A process for stabilizing a compound containing ester groups, against hydrolytic degradation, the process comprising:

contacting a compound containing ester groups with a biobased carbodiimide produces by reacting at least one carbodiimide and at least one carbon acid compound at a temperature of 20° C. to 200° C.,

wherein the carbodiimide comprises:

a compound of formulae (II),

where x =1 to 50 ;

a compound of formulae (III),

where y=1 to 20, and /or

dicyclohexylmethane 4,4′-diisocyanate (H 12-MDI=hydrogerated MDI); and

wherein the at least one carbon acid compound has a functionality greater than 1, comprises greater than 4 carbon atoms, and is from a renewable source selected from the group consisting of castor oil, rapeseed oil, soy oil, tall oil, and combinations thereof.

2. The process according to claim 1 , wherein the ratio of the carbodiimide to the carbon acid compound is 5:95 to 95:5.

3. The process according to claim 1 , wherein the biobased carbodiimide further comprises a non-biobased polyol based on polyether, polyester and/or polyetherester.

4. A process for stabilizing compounds containing ester groups from hydrolytic degradation with a biobased stabilizing agent, the process comprising:

contacting the compounds containing ester groups with a biobased, green stabilizing agent produced by a process comprising:

contacting at least one carbon acid compound having a functionality>1and more than 4 carbon atoms from renewable raw materials selected from a group that includes castor oil, rapeseed oil, soy oil, tall oil, and mixtures of these, with at least one carbodiimide selected from:

dicyclohexylmethane 4,4′-diisocyanate,

compounds of formulae (II)

where x =1 to 50, and/or

compounds of formula (III)

where y =1 to 20,

in solution and/or in the absence of a solvent in the presence or absence of a catalyst to produce the biobased carbodiimide stabilizing agent,

to stabilize the compound containing ester groups against hydrolytic degradation.

5. The process according to claim 4 , wherein the contacting is done at a temperature of 20° C. and 200° C. at a ratio of the carbodiimide to the carbon acid compound of 5:95 to 95:5.

6. The process according to claim 5 , wherein the contacting of the at least one carbon acid compound with the at least one carbodiimide comprises reacting the at least one carbon acid compound with the at least one carbodiimide at temperatures of 80° C. to 120° C. in the presence of a solvent selected from the group consisting of toluene, xylene, ethyl acetate, butyl acetate and/or methyl ethyl ketone.

7. The process according to claim 5 , wherein the contacting of the at least one carbon acid compound with the at least one carbodiimide comprises reacting the at least one carbon acid compound with the at least one carbodiimide in the presence of a catalyst selected from the group consisting of tertiary amines, matrix-soluble tin compounds, titanium compounds, lead, bismuth, and zinc compounds.

8. The process according to claim 4 , wherein:

the ratio of the carbodiimide to the carbon add compound is 5:95to 95:5;

the contacting of the at least one carbon add compound with the at least one carbodiimide comprises reacting the at least one carbon acid compound with the at least one carbodiimide at a temperature of 80° C. to 120′ C.;

the reacting is done in the presence of a solvent selected from the group consisting of toluene, xylene, ethyl acetate, butyl acetate and/or methyl ethyl ketone; and

the reacting is done in the presence of a catalyst selected from the group consisting of tertiary amines, matrix-soluble tin compounds, titanium compounds, lead, bismuth, and zinc compounds.