Cathode active material for lithium secondary battery
View Patent ↗Disclosed is a lithium secondary battery, which is low in capacity loss after overdischarge, having excellent capacity restorability after overdischarge and shows an effect of preventing a battery from swelling at a high temperature.
1. A lithium secondary battery comprising a cathode, an anode, a separator and a non-aqueous electrolyte containing a lithium salt and an electrolyte compound,
wherein the cathode comprises the cathode active material containing a lithium transition metal oxide capable of lithium ion intercalation/deintercalation, which further comprises a lithium nickel oxide represented by Li 2 Ni 0.97 Al 0.03 O 2 or Li 2 Ni 0.97 B 0.03 O 2 , as an additive in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the total cathode active material,
wherein the lithium transition metal oxide is at least one selected from the group consisting of LiCoO 2 , LiNiO 2 , LiMnO 2 , LiMn 2 O 4 , Li(Ni a Co b Mn c )O 2 , LiNi 1−d Co d O 2 , LiCo 1−d Mn d O 2 , LiNi 1−d Mn d O 2 , Li(Ni x Co y Mn z )O 4 , LiMn 2−n Ni n O 4 , LiMn 2−n Co n O 4 , LiCoPO 4 and LiFePO 4 , wherein 0<a<1, 0<b<1, 0<c<1, a+b+c=1, 0≦d<1, 0<x<2, 0<y<2, 0<z<2, x+y+z=2, and 0<n<2, and
wherein a capacity restorability after overdischarge of the lithium secondary battery is more than 90% and less than or equal to 94.2%.
2. The lithium secondary battery according to claim 1 , wherein the lithium nickel oxide belongs to a space group Immm.
3. The lithium secondary battery according to claim 2 wherein the lithium nickel oxide forms a tetra-coordinated planar structure, and two tetra-coordinated planar structures facing to each other share one side formed by O—O so as to form a primary chain.
4. The lithium secondary battery according to claim 2 , wherein the lithium nickel oxide has the following lattice constants: a=3.7±0.5 Å, b=2.8±0.5 Å, c=9.2±0.5 Å, a=90°, β=90° and γ=90.
5. The lithium secondary battery according to claim 1 , wherein the lithium salt is at least one selected from the group consisting of LiClO 4 , LiCF 3 SO 3 , LiPF 6 , LiBF 4 , LiAsF 6 and LiN(CF 3 SO 2 ) 2 , and the electrolyte compound is at least one carbonate selected from the group consisting of ethylene carbonate, propylene carbonate, gamma-butyrolactone, diethyl carbonate, dimethyl carbonate, ethylmethyl carbonate and methylpropyl carbonate.
6. The lithium secondary battery according to claim 1 , wherein the additive is present in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of the total cathode active material.
7. The lithium secondary according to claim 1 , wherein the capacity restorability after overdischarge of the lithium secondary battery is more than 92.3%.
8. The lithium secondary battery according to claim 1 , wherein the capacity restorability after overdischarge of the lithium secondary battery is more than 92.3% and less than or equal to 94.2%.
9. The lithium secondary battery according to claim 1 , wherein the lithium transition metal oxide is LiCoO 2 .