IP Library Granted Patent US 9,042,057
Granted Patent B1
US 9,042,057 · App. 14/290,961 · Granted May 26, 2015

Methods for providing magnetic storage elements with high magneto-resistance using Heusler alloys

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Quick Facts
Patent No.
US 9,042,057
App. No.
14/290,961
Granted
May 26, 2015
Kind
B1
Abstract

Methods for providing magnetic storage elements with high magneto-resistance using Heusler alloys are provided. One such method includes depositing a substrate including NiFe, depositing a seed layer on the substrate, depositing a buffer layer on the seed layer, and growing, epitaxially, an upper layer on the buffer layer, the upper layer including a Heusler alloy.

Claims (62)

1. A method for manufacturing a magnetic storage element, the method comprising:

depositing a substrate comprising NiFe;

depositing a seed layer on the substrate;

depositing a buffer layer on the seed layer; and

growing, epitaxially, an upper layer on the buffer layer, the upper layer comprising a Heusler alloy.

2. The method of claim 1 :

wherein the substrate comprises a first crystalline structure; and

wherein the seed layer is configured to substantially obstruct a transfer of the first crystalline structure to the buffer layer and the upper layer.

3. The method of claim 1 :

wherein the substrate comprises a first crystalline structure;

wherein the seed layer is configured to substantially obstruct a transfer of the first crystalline structure to the buffer layer and the upper layer;

wherein the seed layer is configured to provide a second crystalline structure different from the first crystalline structure;

wherein the buffer layer is configured to substantially maintain the second crystalline structure; and

wherein a structure of the buffer layer substantially matches a crystalline structure of the upper layer.

4. The method of claim 3 , wherein the first crystalline structure comprises a face-centered cubic structure, and the second crystalline structure comprises a structure that is about body-centered cubic.

5. The method of claim 3 :

wherein the seed layer comprises a first magnetic sub-layer with an amorphous structure and a second magnetic sub-layer with the second crystalline structure that is about body-centered cubic; and

wherein the second crystalline structure is developed through a process for changing the amorphous structure of the first magnetic sub-layer, the process selected from the group consisting of an annealing process, a phase change process, a re-crystallization process, and combinations thereof.

6. The method of claim 1 :

wherein the substrate comprises a first crystalline structure; and

wherein the seed layer and the buffer layer are configured to provide a foundation structure for the Heusler alloy of the upper layer that is different from the first crystalline structure.

7. The method of claim 1 :

wherein the Heusler alloy comprises a L21/B2 ordering; and

wherein the Heusler alloy comprises a CFMS alloy.

8. The method of claim 1 :

wherein the seed layer comprises substantially magnetic characteristics; and

wherein the buffer layer comprises substantially non-magnetic characteristics.

9. The method of claim 1 :

wherein the upper layer comprises a free layer comprising the Heusler alloy; and

wherein the method further comprises:

depositing a spacer on the free layer;

depositing a reference layer on the spacer, the reference layer comprising a Heusler alloy; and

depositing a capping layer on the reference layer.

10. The method of claim 9 :

wherein the Heusler alloy of the free layer comprises a L21/B2 ordering;

wherein the Heusler alloy of the reference layer comprises a L21/B2 ordering;

wherein the depositing the capping layer on the reference layer comprises:

depositing a non-magnetic coupling layer on the reference layer;

depositing an anti-ferromagnetically coupled pinned layer on the non-magnetic coupling layer, wherein the reference layer is anti-ferromagnetically coupled via the non-magnetic coupling layer;

depositing an anti-ferromagnetic pinning layer on the anti-ferromagnetically coupled pinned layer; and

depositing the capping layer on the anti-ferromagnetic pinning layer; and

wherein the depositing the reference layer on the spacer comprises growing, epitaxially, the Heusler alloy of the reference layer.

11. The method of claim 1 :

wherein the upper layer comprises a reference layer, the reference layer comprising the Heusler alloy; and

wherein the method further comprises:

depositing a spacer on the reference layer;

depositing a free layer on the spacer, the free layer comprising a Heusler alloy; and

depositing a capping layer on the free layer.

12. The method of claim 11 :

wherein the Heusler alloy of the reference layer comprises a L21/B2 ordering;

wherein the Heusler alloy of the free layer comprises a L21/B2 ordering; and

wherein the depositing the free layer on the spacer comprises growing, epitaxially, the Heusler alloy of the free layer.

13. The method of claim 1 :

wherein the seed layer comprises a multi-layer structure with one or more materials selected from the group consisting of NiFe, Ta, Ti, amorphous CoFeB, CoFe, a material comprising a magnetic CFMS Heusler alloy, and combinations thereof; and

wherein the buffer layer comprises one or more materials selected from the group consisting of Ta, Ti, Cr, Ru, Cu, Ag, Al, W, a Ta alloy, a Cr alloy, a Ru alloy, a Cu alloy, a Ag alloy, a W alloy, a NiAl alloy, and combinations thereof.

14. The method of claim 1 :

wherein the seed layer comprises a multi-layer structure with one or more materials selected from the group consisting of NiFe, Ta, Ti, amorphous CoFeB, CoFe, a material comprising a magnetic CFMS Heusler alloy, and combinations thereof; and

wherein the buffer layer comprises one or more materials selected from the group consisting of Cu2CrAl, Cu2AlSi, a material comprising a non-magnetic Heusler alloy, and combinations thereof.

15. The method of claim 1 :

wherein the magnetic storage element is a current perpendicular to plane giant magneto-resistance (GMR) reader;

wherein a shield layer is selected from the group consisting of the substrate, the seed layer, and combinations thereof; and

wherein the shield layer acts as a shield for the GMR reader.

Assignments (9)
PATENT COLLATERAL AGREEMENT - DDTL LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 067045/0156 →
PATENT COLLATERAL AGREEMENT - A&R LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 064715/0001 →
RELEASE OF SECURITY INTEREST AT REEL 038710 FRAME 0845 Recorded Feb 8, 2022
From: JPMORGAN CHASE BANK, N.A.
To: WESTERN DIGITAL (FREMONT), LLC; WESTERN DIGITAL TECHNOLOGIES, INC.
Reel/Frame 058965/0445 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 19, 2019
From: WESTERN DIGITAL (FREMONT), LLC
To: WESTERN DIGITAL TECHNOLOGIES, INC.
Reel/Frame 050450/0582 →
RELEASE OF SECURITY INTEREST Recorded Mar 5, 2018
From: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: WESTERN DIGITAL (FREMONT), LLC
Reel/Frame 045501/0158 →
SECURITY AGREEMENT Recorded May 16, 2016
From: WESTERN DIGITAL (FREMONT), LLC
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 038744/0675 →
SECURITY AGREEMENT Recorded May 16, 2016
From: WESTERN DIGITAL (FREMONT), LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038710/0845 →
SECURITY AGREEMENT Recorded May 16, 2016
From: WESTERN DIGITAL (FREMONT), LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038744/0755 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 15, 2014
From: DIAO, ZHITAO; LENG, QUNWEN
To: WESTERN DIGITAL (FREMONT), LLC
Reel/Frame 034505/0872 →